Citation: LI Zhi-Hua, LIU Hong, SONG Ling-Yong, HUANG Tian-Hui. Synthesis of Dual-Metal Functionalized MOF-74 and its Adsorption Properties[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(2): 237-242. doi: 10.11862/CJIC.2017.042 shu

Synthesis of Dual-Metal Functionalized MOF-74 and its Adsorption Properties

Technology Center, China Tobacco Guangxi Industrial Co., Ltd., Nanning 530001, China

Corresponding author: HUANG Tian-Hui, thhuang_guangxi@163.com
Received Date: 10 August 2016
Revised Date: 3 December 2016

Figures(4)

Dual-metal incorporated MOF-74 network structure was prepared by one-pot synthesis with Mn (Ⅱ)and Co (Ⅱ)uniformly distributed in the metal sites of the inorganic building blocks. The resulting frameworks functionalized by two kinds of metal ions with various ratios retain the same structure and channel compared to the single-metal MOF-74. Co (Ⅱ)coordinates with the linker and crystallizes faster than Mn (Ⅱ), resulting in higher ratio of Co (Ⅱ)in the crystals compared to the precursor solutions. Furthermore, incorporating two metals with distinct ion sizes have introduced more local defects in the single crystals, contributing to the porosity enhancement of 10% compared to the single-metal MOF-74.
- metal-organic framework,
- gas adsorption,
- crystal engineering,
- dual-metal structure,
- functionalization
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