Citation: ZHANG Yi-Qing, LIU Jia-Xiang. Hexagonal-Type ITO Nanopowders:Coprecipitation Synthesis and Photoelectric Property[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(2): 249-254. doi: 10.11862/CJIC.2017.041 shu

Hexagonal-Type ITO Nanopowders:Coprecipitation Synthesis and Photoelectric Property

ZHANG Yi-Qing ,
LIU Jia-Xiang ^,

Beijing Key Laboratory of Electrochemical Process and Technology for Materials, State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China

Corresponding author: LIU Jia-Xiang, ljxpost@263.net
Received Date: 11 July 2016
Revised Date: 26 November 2016

Figures(6)

Hexagonal-type ITO powders were prepared by coprecipitation method, In and SnCl₄·5H₂O as raw materials, urea as precipitant and added (NH₄)₂SO₄ for dispersing. The powders' crystal shape, particle morphology, electronic and optical properties were characterized by XRD, TEM, four point probe resistance meter, optical spectral luminous apparatus and XPS. The experimental results show that with the increase amount of (NH₄)₂SO₄, powders' morphology and phase structure are changed, the morphology changes from octahedral with spherical ball to spherical ball; Without adding (NH₄)₂SO₄, ITO crystal type is cubic phase. When the molar ratios of (NH₄)₂SO₄ to In are 1:3.45 and 1:1.73, the ITO crystal type turns into hexagonal phase.Continue to add (NH₄)₂SO₄, the crystal type transforms into cubic phase structure. Cubic phase ITO shows a better electrical performance with low resistivity of 0.64 Ω·cm. Under the same excitation wavelength, hexagonal phase ITO emission light intensity is higher.
- h-ITO,
- (NH₄)₂SO₄,
- coprecipitation method,
- nanopowders,
- photoelectric property
1. [1]
  Ayeshamariam A, Kashif M, Bououdina M, et al. Ceram. Int., 2014, 40(1):1321-1328 doi: 10.1016/j.ceramint.2013.07.012
2. [2]
  Ahn M H, Cho E S, Kwon S J. Vacuum, 2014, 101:221-227 doi: 10.1016/j.vacuum.2013.08.018
3. [3]
  Solieman A, Zayed M K, Alamri S N, et al. Mater. Chem. Phys., 2012, 134(1):127-132 doi: 10.1016/j.matchemphys.2012.02.040
4. [4]
  Song P, Han D, Zhang H H, et al. Sens. Actuators B, 2014, 196:434-439 doi: 10.1016/j.snb.2014.01.114
5. [5]
  Chen L Y, Wang Z X, Zhang Z D. New J. Chem., 2009, 33(5):1109-1115 doi: 10.1039/b817588h
6. [6]
  Solieman A, Zayed M K, Alamri S N, et al. Mater. Chem. Phys., 2012, 134(1):127-132 doi: 10.1016/j.matchemphys.2012.02.040
7. [7]
  Feng X, Yang W W, Tang Q L, et al. Powder Technol., 2012, 221:164-167 doi: 10.1016/j.powtec.2011.12.059
8. [8]
  Gao L P, Ren F M, Cheng Z X, et al. CrystEngComm, 2015, 17:3268-3276 doi: 10.1039/C5CE00279F
9. [9]
  Tao B L, Zhang Y, Han D Z, et al. J. Mater. Chem. A, 2014, 2:5455-5461 doi: 10.1039/C4TA00139G
10. [10]
  Liu G D, Chen D R, Jiao X L. CrystEngComm, 2009, 11:1828-1830 doi: 10.1039/b904595n
11. [11]
  Kim B C, Kim S M, Lee J H, et al. J. Am. Ceram. Soc., 2002, 85(8):2083-2088 doi: 10.1111/jace.2002.85.issue-8
12. [12]
  LIU Lang-Ming, GONG Mingming, WEI Wen-Wu. Nonferrous Metallurgy, 1999, 28(6):32-36
13. [13]
  Gurlo A, Barsan N, Weimar U. J. Am. Chem. Soc., 2004, 126(13):4078-4079 doi: 10.1021/ja0318075
14. [14]
  ZHONG Wei-Zhuo, WANG Bu-Guo, SHI Er-Wei, et al. J. Inorg. Mater., 1997, 12(1):11-16
15. [15]
  Guptake R K, Ghosh K, Patel R, et al. J. Cryst. Growth, 2008, 310(19):4336-4339 doi: 10.1016/j.jcrysgro.2008.07.043
16. [16]
  Zhang D H, Ma H L. Appl Phys. A, 1996, 62(5):487-492 doi: 10.1007/BF01567122
17. [17]
  Yang H X, Liu L, Liang H. CrystEngComm, 2011, 13:5011-5016 doi: 10.1039/c1ce05274h
18. [18]
  Wu X C, Hong J M, Han Z J, et al. Chem. Phys. Lett., 2003, 373(1/2):28-32
19. [19]
  Chang H C, Seung Y H, Yu W S, et al. J. Mater. Chem. C, 2015, 3:854-860 doi: 10.1039/C4TC01568A
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