Citation: WANG Hui, DENG Huang-Xiu, HAO Shi-You. Efffect of Heating Model and Raw Material Ratios on the Structure and Photocatalytic Properties of Mesoporous CeO₂[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(2): 285-291. doi: 10.11862/CJIC.2017.040 shu

Efffect of Heating Model and Raw Material Ratios on the Structure and Photocatalytic Properties of Mesoporous CeO₂

1.
Xingzhi College, , Zhejiang Normal University, Jinhua, Zhejiang 321004, China
2.
College of Chemistry and Life Sciences, Zhejiang Normal University, Jinhua, Zhejiang 321004, China

Corresponding author: HAO Shi-You, sky54@zjnu.cn
Received Date: 24 July 2016
Revised Date: 12 December 2016

Figures(10)

Mesoporous CeO₂ materials with good structural properties and high loading of surface hydroxyl groups were synthesized using P123 as template and Ce (NO₃)₃ as raw material via investigating the heating models, heating temperature and the ratios of raw material. The synthesized materials were characterized by XRD, N₂ adsorption-desorption, TEM, Raman, and FT-IR technologies and the results showed that the structural properties of mesoporous CeO₂ prepared using the molar ratio of P123 to Ce (NO₃)₃ of 1:10 as reactants at the temperature of 110℃ hydrothermal heating is the best. The photocatalytic performance of mesoporous CeO₂ was evaluated by the degradation of acid orange 7 (AO7)from aqueous solution. The photocatalytic results presented that AO7 can be thoroughly degraded by the resulted mesoporous CeO₂ under the irradiation of visible light due to the high loading of hydroxyl groups and the formation of mesopores and oxygen vacancies.
- synthetic factors,
- mesoporous CeO₂,
- adsorption,
- photocatalysis,
- acid orange 7
1. [1]
  Forgacs E, Cserhati T, Oros G. Environ. Int., 2004, 30:953-971 doi: 10.1016/j.envint.2004.02.001
2. [2]
  Li J, Ng D H L, Song P, et al. J. Ind. Eng. Chem., 2015, 23:290-298 doi: 10.1016/j.jiec.2014.08.031
3. [3]
  HAO Shi-You, DENG Huang-Xiu, ZHANG Guo-Dong. Chinese J. Inorg. Chem., 2016, 32:233-240
4. [4]
  Mao J, Lu H B, Habibi D, et al. Clean-Soil Air Water, 2015, 43:1037-1043 doi: 10.1002/clen.v43.7
5. [5]
  Dávila-Jiméneza M M, Elizalde-Gonzálezb M P, Díazb E G, et al. Appl. Catal. B:Environ., 2015, 166-167:241-250 doi: 10.1016/j.apcatb.2014.11.034
6. [6]
  Muthirulann P, Nirmala Devi C, MeenakshiSundaram M. Ceram. Int., 2014, 40:5945-5957 doi: 10.1016/j.ceramint.2013.11.042
7. [7]
  Silva A M T, Silva C G, Drazic G, et al. Catal. Today, 2009, 144:13-18 doi: 10.1016/j.cattod.2009.02.022
8. [8]
  Fallah J E, Hilaire L, Romeo M, et al. J. Electron. Spectrosc. Relat. Phenom., 1995, 73:89-103 doi: 10.1016/0368-2048(94)02266-6
9. [9]
  Ji P, Zhang J, Chen F, et al. Appl. Catal. B:Environ, 2009, 85:148-154 doi: 10.1016/j.apcatb.2008.07.004
10. [10]
  Ji P, Wang L, Chen F. ChemCatChem, 2010, 2:1552-1554 doi: 10.1002/cctc.v2.12
11. [11]
  Chen F, Shen X, Wang Y, et al. Appl. Catal. B:Environ., 2012, 121-122:223-229 doi: 10.1016/j.apcatb.2012.04.014
12. [12]
  Hu S, Zhou F, Wang L, et al. Catal. Commun., 2011, 12:794-797 doi: 10.1016/j.catcom.2011.01.027
13. [13]
  Ji P, Zhang J, Chen F, et al. J. Phys. Chem. C, 2008, 112:17809-17813 doi: 10.1021/jp8054087
14. [14]
  Hao S, Hou J, Aprea P, et al. Ind. Eng. Chem. Res., 2014, 53:14617-14622 doi: 10.1021/ie501585z
15. [15]
  Kim S N, Son W J, Choi J S, et al. Microporous Mesoporous Mater., 2008, 115:497-503 doi: 10.1016/j.micromeso.2008.02.025
16. [16]
  Yu J C, Wang X C, Fu X Z. Chem. Mater., 2004, 16:1523-1530 doi: 10.1021/cm049955x
17. [17]
  Yoon M, Seo M, Jeong C, et al. Chem. Mater., 2005, 17:6069-6079 doi: 10.1021/cm0515855
18. [18]
  Keramidas V G, White W B. J. Chem. Phys., 1973, 59:1561-1562 doi: 10.1063/1.1680227
19. [19]
  Hao S, Hou J, Aprea P, et al. Ceram. Int., 2016, 42:7440-7446 doi: 10.1016/j.ceramint.2016.01.148
20. [20]
  Hao S, Hou J, Aprea P, et al. Appl. Catal. B:Environ., 2014, 160-161:566-573 doi: 10.1016/j.apcatb.2014.06.013
21. [21]
  Pan D, Yuan P, Zhao L, et al. Chem. Mater., 2009, 21:5413-5425 doi: 10.1021/cm901999n
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Efffect of Heating Model and Raw Material Ratios on the Structure and Photocatalytic Properties of Mesoporous CeO2

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通讯作者: 陈斌, bchen63@163.com

Efffect of Heating Model and Raw Material Ratios on the Structure and Photocatalytic Properties of Mesoporous CeO₂