Citation: WU Jin-Xiu, LI Mei, CUI Shong-Shong, LIU Zhao-Gang, HU Yan-Hong, WANG Mi-Tang. Controllable Morphology and Luminescence Properties of SrMoO₄:Sm³⁺, Na⁺ Red Emitting Phosphors[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(2): 219-226. doi: 10.11862/CJIC.2017.036 shu

Controllable Morphology and Luminescence Properties of SrMoO₄:Sm³⁺, Na⁺ Red Emitting Phosphors

WU Jin-Xiu ^1,2,3,, ,
LI Mei ^1,2,3,, ,
CUI Shong-Shong ² ,
LIU Zhao-Gang ^2,3 ,
HU Yan-Hong ^2,3 ,
WANG Mi-Tang ^2,3

1.
Metallurgical and Ecological Engineering School, University of Science and Technology Beijing, Beijing 100083, China
2.
College of Materials and Metallurgy, Inner Mongolia University of Science and Technology, Baotou, Inner Mongolia 014010, China
3.
Key Laboratory of Inner Mongolia Autonomous University on New Technologies of Modern Metallurgy and Application of Rare Earth, Baotou, Inner Mongolia 014010, China

Corresponding author: WU Jin-Xiu, wujinxiu888@126.com LI Mei, limei@163.com
Received Date: 16 July 2016
Revised Date: 22 November 2016

Figures(12)

With Sm³⁺ as activator, Na⁺ as doping charge compensatory, citric acid as complexing agent, ethylene glycol as auxiliary complexing agent by sol-gel method red phosphors precursor was synthesized, then a series of SrMoO₄:Sm³⁺, Na⁺ red phosphor samples were sintered at 800℃. The crystalline phase, morphology and luminescence properties and quantum efficiency of the samples were characterized by X-ray diffraction, scanning electron microscopy, fluorescence spectrophotometry and fourier transform infrared spectroscopy, respectively. The results show that the synthesized NaSrMoO₄:Sm³⁺ crystallines are a tetragonal structure. The doped ions have little impact on the matrix crystal structure. The emission spectra of the samples are composed of four peaks, 563, 600, 647 and 707 nm belonging to the ⁵G_5/2→⁶H_J (J=5/2, 7/2, 9/2, 11/2)under the near UV excitation of 403 nm, the relative luminous intensity at 647 nm main emission peak is maximum. When the doping molar fraction of Sm³⁺ is 1%~3%, the emission intensity is the maximum, luminescence concentration quenching could be observed when the doping molar fraction of Sm³⁺ ions was more than 1%~3%. The energy transfer type between Sm³⁺ ions was determined to be the exchange interaction and the critical energy transfer distance (D_c)was calculated to be 1.77~2.56 nm. In addition, Influences of ethylene glycol on the performance of SrMoO₄:Sm³⁺, Na⁺ phosphors were investigated in detail. The research result shows that when ethylene glycol addition amount was 5 mL, the sample grains show spherical or elliptical and the structure is uniform and loose and the fluorescence intensity is optimal.
- strontium molybdate,
- Sm³⁺,
- sol-gel method,
- phosphor
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沈阳化工大学材料科学与工程学院沈阳 110142

Controllable Morphology and Luminescence Properties of SrMoO4:Sm3+, Na+ Red Emitting Phosphors

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Controllable Morphology and Luminescence Properties of SrMoO₄:Sm³⁺, Na⁺ Red Emitting Phosphors