Citation: GU Wen-Jun, GU Jin-Zhong. Syntheses, Crystal Structures and Magnetic Properties of 1D and 2D Cobalt(Ⅱ) Coordination Polymers Constructed from Semir-igid Tricarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(2): 227-236. doi: 10.11862/CJIC.2017.035 shu

Syntheses, Crystal Structures and Magnetic Properties of 1D and 2D Cobalt(Ⅱ) Coordination Polymers Constructed from Semir-igid Tricarboxylic Acid

GU Wen-Jun ¹ ,
GU Jin-Zhong ^2,,

1.
College of Animal Science and Technology, Southwest University, Chongqing 400715, China
2.
College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China

Corresponding author: GU Jin-Zhong, gujzh@lzu.edu.cn
Received Date: 30 September 2016
Revised Date: 2 December 2016

Figures(14)

Two 1D and 2D cobalt (Ⅱ)coordination polymers, namely[Co (μ2-Hcpta) (phen) (H₂O)]_n (1)and[Co₃ (μ5-cpta)₂ (2, 2'-bipy)₂]_n (2), have been constructed hydrothermally using H₃cpta (H₃cpta=2-(2-carboxyphenoxy)terephthalic acid), phen (phen=phenanthroline)or 2, 2'-bipy (2, 2'-bipy=2, 2'-bipyridine), and cobalt chloride. Single-crystal X-ray diffraction analyses revealed that the two compounds crystallize in the monoclinic system, space group P2_1/c. In compound 1, the carboxylate groups of Hcpta^2- ligands bridge alternately neighboring metal ions to form a chain. Adjacent chains are assembled to a 2D supramolecular network through C-H…O hydrogen bond. Compound 2 shows a 2D sheet based on Co₃ units. Magnetic studies for compounds 1 and 2 demonstrate an antiferromagnetic coupling between the adjacent Co (Ⅱ)centers. CCDC:1507502, 1; 1507503, 2.
- coordination polymer,
- hydrogen bonding,
- tricarboxylic acid,
- magnetic properties
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