Citation: YANG Rong, LIU Xu-Wang, PENG Lu-Ming. Synthesis and Electrochemical Properties of Manganese Oxides/Carbon-Nitrogen Three-Dimensional Networks Composite as an Anode Material for Lithium Ion Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(2): 210-218. doi: 10.11862/CJIC.2017.025 shu

Synthesis and Electrochemical Properties of Manganese Oxides/Carbon-Nitrogen Three-Dimensional Networks Composite as an Anode Material for Lithium Ion Batteries

1.
China Academy of Engineering Physics, Institute of Chemical Materials, Mianyang, Sichuan 621000, China
2.
Department of Chemistry, Nanjing University, Key Laboratory of Mesoscopic Chemistry of MOE, Nanjing 210093, China

Corresponding author: YANG Rong, yangrong@caep.cn PENG Lu-Ming, luming@nju.edu.cn
Received Date: 17 August 2016
Revised Date: 21 October 2016

Figures(9)

Sesquioxide coated on melamine foams (MF)were prepared by hydrothermal method using manganese nitrate and ethanol. After calcinating the resulting material at different temperatures in N₂ atmosphere, manganese oxides loaded on C-N three-dimensional networks were obtained. Due to the presence of C-N networks, the structure stability and conductivity of the materials have been increased. The pores and channels generated during the calcination processes facilitate the lithium ions transportation. The composites present excellent charge/discharge ability and cycling stability as anode materials for lithium ion batteries. Therefore, the specific capacity and cycling stability have been greatly enhanced. MnO/CNnws-500 can maintain a specific capacity of 590 mAh·g^-1 after 160 cycles which accounts for 78% of theoretical capacity (755 mAh·g^-1)of manganese monoxide (MnO).
- manganese oxide,
- melamine foams,
- C-N three-dimensional networks,
- lithium ion batteries,
- anode materials
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沈阳化工大学材料科学与工程学院沈阳 110142