Citation: LU Chan, WU Ke-Qi, FU Lin-Feng, GUO Xi-Shan, ZHU Song-Ming. Reduced Graphene Oxide Modified Y-Branched TiO₂ Nanotubes Photoelectrode:Preparation and Photoelectrocatalytic Oxidation of Ammonia[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(2): 262-268. doi: 10.11862/CJIC.2017.024 shu

Reduced Graphene Oxide Modified Y-Branched TiO₂ Nanotubes Photoelectrode:Preparation and Photoelectrocatalytic Oxidation of Ammonia

College of Biosystems Engineering and Food Science, Zhejiang University, Hangzhou 310058, China

Corresponding author: GUO Xi-Shan, guoxs@zju.edu.cn
Received Date: 16 June 2016
Revised Date: 31 October 2016

Figures(9)

The rGO/Y-TiO₂ nanotubes (rGO/Y-TiO₂NTs)electrodes with different rGO loading were fabricated by a three-step anodic oxidation, followed by a one-step cyclic voltammetric electrodeposition technique. Field emission scanning electron microscopy (FESEM), X-ray energy dispersive spectrometry (EDS), X-ray diffraction (XRD), UV-Vis diffuse reflection spectrum (UV-Vis DRS)and Raman spectrum were used to characterize the morphology, element composition and crystal form of the samples. Photocurrent responses and the performance of photoelectrocatalytic (PEC)oxidation of ammonia were investigated under 1.0 V bias potential using rGO/Y-TiO₂NTs electrodes prepared under different cyclic voltammetric cycle numbers. The results indicated that the highly ordered Y-TiO₂NTs possessed the crystal form of anatase phases with high surface area. The smooth and transparent rGO film was electrodeposited on the surface of Y-TiO₂NTs. The photoelectrocatalytic efficiency of ammonia using rGO/Y-TiO₂NTs electrode was improved by the modification of rGO film, and reached 95.9% in 30 min when the electrodeposition cycle number was 30, which was 1.3 time higher than that of the pristine Y-TiO₂NTs electrodes.
- Y-branched TiO₂ nanotubes,
- reduced graphene oxide,
- photoelectrocatalytic oxidation,
- ammonia
1. [1]
  Nemoto J, Gokan N, Ueno H, et al. J. Photochem. Photobiol., A, 2007, 185(2):295-300
2. [2]
  Wang N, Li X, Wang Y, et al. Chem. Eng. J., 2009, 146(1):30-35 doi: 10.1016/j.cej.2008.05.025
3. [3]
  da Rocha O R S, Pinheiro R B, Duarte M M M B, et al. Desalin. Water Treat., 2013, 51(37/38/39):7269-7275
4. [4]
  Kondalkar V V, Mali S S, Mane R M, et al. Ind. Eng. Chem. Res., 2014, 53(47):18152-18162 doi: 10.1021/ie501821a
5. [5]
  Xin Y, Gao M, Wang Y, et al. Chem. Eng. J., 2014, 242:162-169 doi: 10.1016/j.cej.2013.12.068
6. [6]
  Liu Z, Zhang X, Nishimoto S, et al. J. Phys. Chem. C, 2008, 112(1):253-259 doi: 10.1021/jp0772732
7. [7]
  Michailowski A, AlMawlawi D, Cheng G, et al. Chem. Phys. Lett., 2001, 349(1):1-5
8. [8]
  Bavykin D V, Parmon V N, Lapkin A A, et al. J. Mater. Chem., 2004, 14(22):3370-3377 doi: 10.1039/b406378c
9. [9]
  Gong D, Grimes C A, Varghese O K, et al. J. Mater. Res., 2001, 16(12):3331-3334 doi: 10.1557/JMR.2001.0457
10. [10]
  Chen D, Zhang H, Li X, et al. J. Anal. Chem., 2010, 82(6):2253-2261 doi: 10.1021/ac9021055
11. [11]
  Mohapatra S K, Misra M, Mahajan V K, et al. Mater. Lett., 2008, 62(12):1772-1774
12. [12]
  Rambabu Y, Jaiswal M, Roy S C. J. Phys. D, 2015, 48(29):295302 doi: 10.1088/0022-3727/48/29/295302
13. [13]
  YANG Xu, QU Yi, FAN Yi, et al. Chinese J. Lumin., 2012, 33(3):269-274
14. [14]
  Wang Y, Li Y, Tang L, et al. Electrochem. Commun., 2009, 11(4):889-892 doi: 10.1016/j.elecom.2009.02.013
15. [15]
  LI Guo-Wong, ZHONG Jing-Ming, WANG Li-Hui, et al. Adv. New Renewable Energy, 2015, 3(5):336-339
16. [16]
  KUANG Da, HU Wen-Bin. J. Inorg. Mater., 2013, 28(3):235-246
17. [17]
  Chen D, Zhang H, Liu Y, et al. Energy Environ. Sci., 2013, 6(5):1362-1387 doi: 10.1039/c3ee23586f
18. [18]
  Chen D, Feng H, Li J. Chem. Rev., 2012, 112(11):6027-6053 doi: 10.1021/cr300115g
19. [19]
  Liu C, Teng Y, Liu R, et al. Carbon, 2011, 49(15):5312-5320 doi: 10.1016/j.carbon.2011.07.051
20. [20]
  Zhang X, Tang Y, Li Y, et al. Appl. Catal. A, 2013, 457:78-84 doi: 10.1016/j.apcata.2013.03.011
21. [21]
  Zhang H, Lü X, Li Y, et al. ACS Nano, 2010, 4(1):380-386 doi: 10.1021/nn901221k
22. [22]
  Tang Y, Luo S, Teng Y, et al. J. Hazard. Mater., 2012, 241:323-330
23. [23]
24. [24]
  CHENG Xiu-Wen, LIU Hui-Ling, WANG Pu, et al. J. Harbin Inst. Technol., 2014, 46(6):30-33
25. [25]
  Zhai C, Zhu M, Lu Y, et al. Phys. Chem. Chem. Phys., 2014, 16(28):14800-14807 doi: 10.1039/C4CP01401D
26. [26]
  LIU Jing-Jing, SONG Cun-Yi, TONG Zhen -Song. Chinese J. Environ. Eng., 2015, 9(10):4890-4896 doi: 10.12030/j.cjee.20151043
27. [27]
  CHEN Shu-Hai, XU Yao, LÜBao-Liang, et al. Acta Phys.-Chim. Sin., 2011, 27(12):2933-2938 doi: 10.3866/PKU.WHXB20112933
28. [28]
  SU Ming-Xing, WANG Wei, NI Ya-Ru, et al. New Chem. Mater., 2013, 41(10):86-88 doi: 10.3969/j.issn.1006-3536.2013.10.028
29. [29]
  Tang Y B, Lee C S, Xu J, et al. Acs Nano, 2010, 4(6):3482-3488 doi: 10.1021/nn100449w
30. [30]
  Wang X, Zhi L, Müllen K. Nano Lett., 2008, 8(1):323-327 doi: 10.1021/nl072838r
31. [31]
  Lu M D, Yang S M. J. Colloid Interface Sci., 2009, 333(1):128-134 doi: 10.1016/j.jcis.2009.01.073
32. [32]
  LI Dan-Dan, LIU Zhong-Qing, YAN Xin, et al. Chinese J. Inorg. Chem., 2011, 27(7):1358-1362
33. [33]
  Wang H, Zhang X, Su Y, et al. Appl. Surf. Sci., 2014, 311:851-857 doi: 10.1016/j.apsusc.2014.05.195
1. [1]
  Jingyu Cai , Xiaoyu Miao , Yulai Zhao , Longqiang Xiao . Exploratory Teaching Experiment Design of FeOOH-RGO Aerogel for Photocatalytic Benzene to Phenol. University Chemistry, 2024, 39(4): 169-177. doi: 10.3866/PKU.DXHX202311028
2. [2]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
3. [3]
  Yunting Shang , Yue Dai , Jianxin Zhang , Nan Zhu , Yan Su . Something about RGO (Reduced Graphene Oxide). University Chemistry, 2024, 39(9): 273-278. doi: 10.3866/PKU.DXHX202306050
4. [4]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
5. [5]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
6. [6]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
7. [7]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
8. [8]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
9. [9]
  Zhuoyan Lv , Yangming Ding , Leilei Kang , Lin Li , Xiao Yan Liu , Aiqin Wang , Tao Zhang . Light-Enhanced Direct Epoxidation of Propylene by Molecular Oxygen over CuO_x/TiO₂ Catalyst. Acta Physico-Chimica Sinica, 2025, 41(4): 100038-. doi: 10.3866/PKU.WHXB202408015
10. [10]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
11. [11]
  Kaihui Huang , Dejun Chen , Xin Zhang , Rongchen Shen , Peng Zhang , Difa Xu , Xin Li . Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(12): 2407020-. doi: 10.3866/PKU.WHXB202407020
12. [12]
  Jiapei Zou , Junyang Zhang , Xuming Wu , Cong Wei , Simin Fang , Yuxi Wang . A Comprehensive Experiment Based on Electrocatalytic Nitrate Reduction into Ammonia: Synthesis, Characterization, Performance Exploration, and Applicable Design of Copper-based Catalysts. University Chemistry, 2024, 39(6): 373-382. doi: 10.3866/PKU.DXHX202312081
13. [13]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
14. [14]
  Xianghai Song , Xiaoying Liu , Zhixiang Ren , Xiang Liu , Mei Wang , Yuanfeng Wu , Weiqiang Zhou , Zhi Zhu , Pengwei Huo . 氮掺杂显著提升BiOBr光催化还原CO₂性能研究. Acta Physico-Chimica Sinica, 2025, 41(6): 100055-. doi: 10.1016/j.actphy.2025.100055
15. [15]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
16. [16]
  .
  CCS Chemistry 综述推荐│绿色氧化新思路：光/电催化助力有机物高效升级
  . CCS Chemistry, 2025, 7(10.31635/ccschem.024.202405369): -.
17. [17]
  Jianyu Qin , Yuejiao An , Yanfeng Zhang . In Situ Assembled ZnWO₄/g-C₃N₄ S-Scheme Heterojunction with Nitrogen Defect for CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408002-. doi: 10.3866/PKU.WHXB202408002
18. [18]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Fei Liu . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 100036-. doi: 10.3866/PKU.WHXB202408004
19. [19]
  Runhua Chen , Qiong Wu , Jingchen Luo , Xiaolong Zu , Shan Zhu , Yongfu Sun . 缺陷态二维超薄材料用于光/电催化CO₂还原的基础与展望. Acta Physico-Chimica Sinica, 2025, 41(3): 2308052-. doi: 10.3866/PKU.WHXB202308052
20. [20]
  Fangfang WANG , Jiaqi CHEN , Weiyin SUN . CuBi@Cu-MOF composite catalysts for electrocatalytic CO₂ reduction to HCOOH. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 97-104. doi: 10.11862/CJIC.20240350

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(628)
HTML views(78)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Reduced Graphene Oxide Modified Y-Branched TiO2 Nanotubes Photoelectrode:Preparation and Photoelectrocatalytic Oxidation of Ammonia

Metrics

通讯作者: 陈斌, bchen63@163.com

Reduced Graphene Oxide Modified Y-Branched TiO₂ Nanotubes Photoelectrode:Preparation and Photoelectrocatalytic Oxidation of Ammonia