Citation: LU Chan, WU Ke-Qi, FU Lin-Feng, GUO Xi-Shan, ZHU Song-Ming. Reduced Graphene Oxide Modified Y-Branched TiO₂ Nanotubes Photoelectrode:Preparation and Photoelectrocatalytic Oxidation of Ammonia[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(2): 262-268. doi: 10.11862/CJIC.2017.024 shu

Reduced Graphene Oxide Modified Y-Branched TiO₂ Nanotubes Photoelectrode:Preparation and Photoelectrocatalytic Oxidation of Ammonia

College of Biosystems Engineering and Food Science, Zhejiang University, Hangzhou 310058, China

Corresponding author: GUO Xi-Shan, guoxs@zju.edu.cn
Received Date: 16 June 2016
Revised Date: 31 October 2016

Figures(9)

The rGO/Y-TiO₂ nanotubes (rGO/Y-TiO₂NTs)electrodes with different rGO loading were fabricated by a three-step anodic oxidation, followed by a one-step cyclic voltammetric electrodeposition technique. Field emission scanning electron microscopy (FESEM), X-ray energy dispersive spectrometry (EDS), X-ray diffraction (XRD), UV-Vis diffuse reflection spectrum (UV-Vis DRS)and Raman spectrum were used to characterize the morphology, element composition and crystal form of the samples. Photocurrent responses and the performance of photoelectrocatalytic (PEC)oxidation of ammonia were investigated under 1.0 V bias potential using rGO/Y-TiO₂NTs electrodes prepared under different cyclic voltammetric cycle numbers. The results indicated that the highly ordered Y-TiO₂NTs possessed the crystal form of anatase phases with high surface area. The smooth and transparent rGO film was electrodeposited on the surface of Y-TiO₂NTs. The photoelectrocatalytic efficiency of ammonia using rGO/Y-TiO₂NTs electrode was improved by the modification of rGO film, and reached 95.9% in 30 min when the electrodeposition cycle number was 30, which was 1.3 time higher than that of the pristine Y-TiO₂NTs electrodes.
- Y-branched TiO₂ nanotubes,
- reduced graphene oxide,
- photoelectrocatalytic oxidation,
- ammonia
1. [1]
  Nemoto J, Gokan N, Ueno H, et al. J. Photochem. Photobiol., A, 2007, 185(2):295-300
2. [2]
  Wang N, Li X, Wang Y, et al. Chem. Eng. J., 2009, 146(1):30-35 doi: 10.1016/j.cej.2008.05.025
3. [3]
  da Rocha O R S, Pinheiro R B, Duarte M M M B, et al. Desalin. Water Treat., 2013, 51(37/38/39):7269-7275
4. [4]
  Kondalkar V V, Mali S S, Mane R M, et al. Ind. Eng. Chem. Res., 2014, 53(47):18152-18162 doi: 10.1021/ie501821a
5. [5]
  Xin Y, Gao M, Wang Y, et al. Chem. Eng. J., 2014, 242:162-169 doi: 10.1016/j.cej.2013.12.068
6. [6]
  Liu Z, Zhang X, Nishimoto S, et al. J. Phys. Chem. C, 2008, 112(1):253-259 doi: 10.1021/jp0772732
7. [7]
  Michailowski A, AlMawlawi D, Cheng G, et al. Chem. Phys. Lett., 2001, 349(1):1-5
8. [8]
  Bavykin D V, Parmon V N, Lapkin A A, et al. J. Mater. Chem., 2004, 14(22):3370-3377 doi: 10.1039/b406378c
9. [9]
  Gong D, Grimes C A, Varghese O K, et al. J. Mater. Res., 2001, 16(12):3331-3334 doi: 10.1557/JMR.2001.0457
10. [10]
  Chen D, Zhang H, Li X, et al. J. Anal. Chem., 2010, 82(6):2253-2261 doi: 10.1021/ac9021055
11. [11]
  Mohapatra S K, Misra M, Mahajan V K, et al. Mater. Lett., 2008, 62(12):1772-1774
12. [12]
  Rambabu Y, Jaiswal M, Roy S C. J. Phys. D, 2015, 48(29):295302 doi: 10.1088/0022-3727/48/29/295302
13. [13]
  YANG Xu, QU Yi, FAN Yi, et al. Chinese J. Lumin., 2012, 33(3):269-274
14. [14]
  Wang Y, Li Y, Tang L, et al. Electrochem. Commun., 2009, 11(4):889-892 doi: 10.1016/j.elecom.2009.02.013
15. [15]
  LI Guo-Wong, ZHONG Jing-Ming, WANG Li-Hui, et al. Adv. New Renewable Energy, 2015, 3(5):336-339
16. [16]
  KUANG Da, HU Wen-Bin. J. Inorg. Mater., 2013, 28(3):235-246
17. [17]
  Chen D, Zhang H, Liu Y, et al. Energy Environ. Sci., 2013, 6(5):1362-1387 doi: 10.1039/c3ee23586f
18. [18]
  Chen D, Feng H, Li J. Chem. Rev., 2012, 112(11):6027-6053 doi: 10.1021/cr300115g
19. [19]
  Liu C, Teng Y, Liu R, et al. Carbon, 2011, 49(15):5312-5320 doi: 10.1016/j.carbon.2011.07.051
20. [20]
  Zhang X, Tang Y, Li Y, et al. Appl. Catal. A, 2013, 457:78-84 doi: 10.1016/j.apcata.2013.03.011
21. [21]
  Zhang H, Lü X, Li Y, et al. ACS Nano, 2010, 4(1):380-386 doi: 10.1021/nn901221k
22. [22]
  Tang Y, Luo S, Teng Y, et al. J. Hazard. Mater., 2012, 241:323-330
23. [23]
24. [24]
  CHENG Xiu-Wen, LIU Hui-Ling, WANG Pu, et al. J. Harbin Inst. Technol., 2014, 46(6):30-33
25. [25]
  Zhai C, Zhu M, Lu Y, et al. Phys. Chem. Chem. Phys., 2014, 16(28):14800-14807 doi: 10.1039/C4CP01401D
26. [26]
  LIU Jing-Jing, SONG Cun-Yi, TONG Zhen -Song. Chinese J. Environ. Eng., 2015, 9(10):4890-4896 doi: 10.12030/j.cjee.20151043
27. [27]
  CHEN Shu-Hai, XU Yao, LÜBao-Liang, et al. Acta Phys.-Chim. Sin., 2011, 27(12):2933-2938 doi: 10.3866/PKU.WHXB20112933
28. [28]
  SU Ming-Xing, WANG Wei, NI Ya-Ru, et al. New Chem. Mater., 2013, 41(10):86-88 doi: 10.3969/j.issn.1006-3536.2013.10.028
29. [29]
  Tang Y B, Lee C S, Xu J, et al. Acs Nano, 2010, 4(6):3482-3488 doi: 10.1021/nn100449w
30. [30]
  Wang X, Zhi L, Müllen K. Nano Lett., 2008, 8(1):323-327 doi: 10.1021/nl072838r
31. [31]
  Lu M D, Yang S M. J. Colloid Interface Sci., 2009, 333(1):128-134 doi: 10.1016/j.jcis.2009.01.073
32. [32]
  LI Dan-Dan, LIU Zhong-Qing, YAN Xin, et al. Chinese J. Inorg. Chem., 2011, 27(7):1358-1362
33. [33]
  Wang H, Zhang X, Su Y, et al. Appl. Surf. Sci., 2014, 311:851-857 doi: 10.1016/j.apsusc.2014.05.195
1. [1]
  Ruolin CHENG , Yue WANG , Xiyao NIU , Huagen LIANG , Ling LIU , Shijian LU . Efficient photothermal catalytic CO₂ cycloaddition over W₁₈O₄₉/rGO composites. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1276-1284. doi: 10.11862/CJIC.20240424
2. [2]
  Yang ZHOU , Lili YAN , Wenjuan ZHANG , Pinhua RAO . Thermal regeneration of biogas residue biochar and the ammonia nitrogen adsorption properties. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1574-1588. doi: 10.11862/CJIC.20250032
3. [3]
  Jingyu Cai , Xiaoyu Miao , Yulai Zhao , Longqiang Xiao . Exploratory Teaching Experiment Design of FeOOH-RGO Aerogel for Photocatalytic Benzene to Phenol. University Chemistry, 2024, 39(4): 169-177. doi: 10.3866/PKU.DXHX202311028
4. [4]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
5. [5]
  Yunting Shang , Yue Dai , Jianxin Zhang , Nan Zhu , Yan Su . Something about RGO (Reduced Graphene Oxide). University Chemistry, 2024, 39(9): 273-278. doi: 10.3866/PKU.DXHX202306050
6. [6]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
7. [7]
  Yue Zhang , Bao Li , Lixin Wu . GO-Assisted Supramolecular Framework Membrane for High-Performance Separation of Nanosized Oil-in-Water Emulsions. Acta Physico-Chimica Sinica, 2024, 40(5): 2305038-0. doi: 10.3866/PKU.WHXB202305038
8. [8]
  Huasen Lu , Shixu Song , Qisen Jia , Guangbo Liu , Luhua Jiang . Advances in Cu₂O-based Photocathodes for Photoelectrochemical Water Splitting. Acta Physico-Chimica Sinica, 2024, 40(2): 2304035-0. doi: 10.3866/PKU.WHXB202304035
9. [9]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
10. [10]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
11. [11]
  Shiqian WEI , Xinyu TIAN , Hong LIU , Maoxia CHEN , Fan TANG , Qiang FAN , Weifeng FAN , Yu HU . Oxygen reduction reaction/oxygen evolution reaction catalytic performances of different active sites on nitrogen-doped graphene loaded with iron single atoms. Chinese Journal of Inorganic Chemistry, 2025, 41(9): 1776-1788. doi: 10.11862/CJIC.20250102
12. [12]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
13. [13]
  Hailang JIA , Yujie LU , Pengcheng JI . Preparation and properties of nitrogen and phosphorus co-doped graphene carbon aerogel supported ruthenium electrocatalyst for hydrogen evolution reaction. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2327-2336. doi: 10.11862/CJIC.20250021
14. [14]
  Jiali Lei , Juan Wang , Wenhui Zhang , Guohong Wang , Zihui Liang , Jinmao Li . TiO₂/CdIn₂S₄ S-scheme heterojunction photocatalyst promotes photocatalytic hydrogen evolution coupled vanillyl alcohol oxidation. Acta Physico-Chimica Sinica, 2025, 41(12): 100174-0. doi: 10.1016/j.actphy.2025.100174
15. [15]
  Lisha LEI , Wei YONG , Yiting CHENG , Yibo WANG , Wenchao HUANG , Junhuan ZHAO , Zhongjie ZHAI , Yangbin DING . Application of regenerated cellulose and reduced graphene oxide film in synergistic power generation from moisture electricity generation and Mg-air batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1151-1161. doi: 10.11862/CJIC.20240202
16. [16]
  Yinjie Xu , Suiqin Li , Lihao Liu , Jiahui He , Kai Li , Mengxin Wang , Shuying Zhao , Chun Li , Zhengbin Zhang , Xing Zhong , Jianguo Wang . Enhanced Electrocatalytic Oxidation of Sterols using the Synergistic Effect of NiFe-MOF and Aminoxyl Radicals. Acta Physico-Chimica Sinica, 2024, 40(3): 2305012-0. doi: 10.3866/PKU.WHXB202305012
17. [17]
  Zhuoyan Lv , Yangming Ding , Leilei Kang , Lin Li , Xiao Yan Liu , Aiqin Wang , Tao Zhang . Light-Enhanced Direct Epoxidation of Propylene by Molecular Oxygen over CuO_x/TiO₂ Catalyst. Acta Physico-Chimica Sinica, 2025, 41(4): 100038-0. doi: 10.3866/PKU.WHXB202408015
18. [18]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
19. [19]
  Bizhu Shao , Huijun Dong , Yunnan Gong , Jianhua Mei , Fengshi Cai , Jinbiao Liu , Dichang Zhong , Tongbu Lu . Metal-Organic Framework-Derived Nickel Nanoparticles for Efficient CO₂ Electroreduction in Wide Potential Windows. Acta Physico-Chimica Sinica, 2024, 40(4): 2305026-0. doi: 10.3866/PKU.WHXB202305026
20. [20]
  Xudong Lv , Tao Shao , Junyan Liu , Meng Ye , Shengwei Liu . Paired Electrochemical CO₂ Reduction and HCHO Oxidation for the Cost-Effective Production of Value-Added Chemicals. Acta Physico-Chimica Sinica, 2024, 40(5): 2305028-0. doi: 10.3866/PKU.WHXB202305028

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(890)
HTML views(104)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Reduced Graphene Oxide Modified Y-Branched TiO2 Nanotubes Photoelectrode:Preparation and Photoelectrocatalytic Oxidation of Ammonia

Metrics

通讯作者: 陈斌, bchen63@163.com

Reduced Graphene Oxide Modified Y-Branched TiO₂ Nanotubes Photoelectrode:Preparation and Photoelectrocatalytic Oxidation of Ammonia