Citation: ZHENG Zhuo, GUO Xiao-Dong, WU Zhen-Guo, XIANG Wei, HUA Wei-Bo, ZHONG Ben-He, YANG Xiu-Shan. Preparation of Carbon-Coated LiNi_1/3Co_1/3Mn_1/3O₂ Cathode for High-Rate Lithium Ion Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(1): 106-114. doi: 10.11862/CJIC.2017.020 shu

Preparation of Carbon-Coated LiNi_1/3Co_1/3Mn_1/3O₂ Cathode for High-Rate Lithium Ion Batteries

1.
Polymer Research Institute, Sichuan University, Chengdu 610065, China
2.
School of Chemical Engineering, Sichuan University, Chengdu 610065, China
3.
College of Materials and Chemistry & Chemical Engineering, Chengdu University of Technology, Chengdu 610059, China

Corresponding author: YANG Xiu-Shan, yangxs@scu.edu.cn
Received Date: 23 August 2016
Revised Date: 18 November 2016

Figures(9)

A series of carbon-coated LiNi_1/3Co_1/3Mn_1/3O₂ cathodes (w=1.0%, 2.0%, 3.0%) have been prepared by the carbonate co-precipitation, high temperature solid state method. Powder X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), electrochemical impedance spectroscopy (EIS) and galvanostatic charge-discharge tests were employed to analyze the crystal structure, micromorphology and electrochemical properties of the as-prepared materials. The results indicate that carbon was successfully coated on the particle surface, and the carbon-coated LiNi_1/3Co_1/3Mn_1/3O₂ cathodes have well-ordered α-NaFeO₂ structure (Space group:R3m). The average primary particle sizes were gradually increased (from 177 to 209 nm) with the increased carbon coating. The amorphous carbon layer on the surface could enhance the electronic conductivity and decrease the side reactions between electrolyte and electrodes, thus improving the electrochemical performance. The 2.0% carbon-coated sample has the best high rate and long-term cycling stability. After 100 cycles at 1C between 2.7 and 4.3 V, the material retained 93% of its initial capacity. At 0.1C, 0.2C, 0.5C, 1C, 3C, 5C, 10C and 20C, the specific capacities of the material were 155, 148, 145, 138, 127, 116, 104 and 96 mAh·g^-1, respectively. This sample exhibits an excellent ultra-high rate performance with a high discharge capacity of 62 mAh·g^-1 (the pristine LiNi_1/3Co_1/3Mn_1/3O₂ barely delivers 30 mAh·g^-1) even at the ultra-high rate 50C (9 A·g^-1).
- carbonate co-precipitation,
- carbon-coated,
- high rate performance,
- LiNi_1/3Co_1/3Mn_1/3O₂,
- lithium-ion battery
1. [1]
  Dunn B, Kamath H, Tarascon J M. Science, 2011,334(6058): 928-935 doi: 10.1126/science.1212741
2. [2]
  Tarascon J M, Armand M. Nature, 2001,414(6861):359-367 doi: 10.1038/35104644
3. [3]
  Manthiram A, Murugan A V, Sarkar A, et al. Energy Environ. Sci., 2008,1:621-638 doi: 10.1039/b811802g
4. [4]
  Hua W B, Guo X D, Zheng Z, et al. J. Power Sources, 2015, 275:200-206 doi: 10.1016/j.jpowsour.2014.09.178
5. [5]
  Ahn W, Lim S N, Jung K N, et al. J. Alloys Compd., 2014, 609(9):143-149
6. [6]
  Cho T H, Park S M, Yoshio M, et al. J. Power Sources, 2005, 142(1/2):306-312
7. [7]
  Lee M H, Kang Y J, Myung S T, et al. Electrochim. Acta, 2004,50(4):939-948 doi: 10.1016/j.electacta.2004.07.038
8. [8]
  WANG Hai-Yan, TANG Ai-Dong, HUANG Ke-Long, et al. Chinese. J. Inorg. Chem., 2008,24(4):593-599
9. [9]
  Aurbach D, Gamolsky K, Markovsky B, et al. J. Electrochem. Soc., 2000,147(4):1322-1331 doi: 10.1149/1.1393357
10. [10]
  Huang Y, Chen J, Cheng F, et al. J. Power Sources, 2010, 195(24):8267-8274 doi: 10.1016/j.jpowsour.2010.07.021
11. [11]
  Hashem A M A, Abdel-Ghany A E, Eid A E, et al. J. Power Sources, 2011,196(20):8632-8637 doi: 10.1016/j.jpowsour.2011.06.039
12. [12]
  Riley L A, Atta S V, Cavanagh A S, et al. J. Power Sources, 2011,196(6):3317-3324 doi: 10.1016/j.jpowsour.2010.11.124
13. [13]
  Lu J, Peng Q, Wang W, et al. J. Am. Chem. Soc., 2013,135(5):1649-1652 doi: 10.1021/ja308717z
14. [14]
  Wu Z Z, Han X G, Zheng J X, et al. Nano Lett., 2014,14(8): 4700-4706 doi: 10.1021/nl5018139
15. [15]
  Mei T, Zhu Y C, Tang K B, et al. RSC Adv., 2012,2(33): 12886-12891 doi: 10.1039/c2ra21392c
16. [16]
  Hsieh C T, Mo C Y, Chen Y F, et al. Electrochim. Acta, 2013,106(9):525-533
17. [17]
  Hu Y Y, Zhou Y K, Wang J, et al. Mater. Chem. Phys., 2011, 129(1/2):296-300
18. [18]
  Kim H S, Kong M Z, Kim K, et al. J. Power Sources, 2007, 171(2):917-921 doi: 10.1016/j.jpowsour.2007.06.028
19. [19]
  Guo R, Shi P F, Cheng X Q, et al. J. Alloys Compd., 2009, 473(1/2):53-59
20. [20]
  Han Y M, Zhang Z F, Zhang L B, et al. Trans. Nonferrous Met. Soc. China, 2013,23(10):2971-2976 doi: 10.1016/S1003-6326(13)62822-8
21. [21]
  Cao Q, Zhang H P, Wang G J, et al. Electrochem. Commun., 2007,9(5):1228-1232 doi: 10.1016/j.elecom.2007.01.017
22. [22]
  Li J F, Xiong S L, Liu Y R, et al. Nano Energy, 2013,2(6): 1249-1260 doi: 10.1016/j.nanoen.2013.06.003
23. [23]
  Zhang X Y, Jiang W J, Mauger A, et al. J. Power Sources, 2010,195(5):1292-1301 doi: 10.1016/j.jpowsour.2009.09.029
24. [24]
  ZHANG Ji-Bin, HUA Wei-Bo, ZHENG Zhuo, et al. Acta Phys.-Chim. Sin., 2015,31(5):905-912
25. [25]
  Zheng Z, Hua W B, Liao S X, et al. RSC Adv., 2015,5(72): 58528-58535 doi: 10.1039/C5RA06419H
26. [26]
  Gabrisch H, Yi T, Yazami R. Electrochem. Solid-State Lett., 2008,11(7):A119-A124 doi: 10.1149/1.2919713
27. [27]
  HUA Wei-Bo, GUO Xiao-dong, ZHENG Zhuo, et al. Chem. Res. Appl., 2014,26(3):441-444
28. [28]
  Huang Z D, Liu X M, Zhang B, et al. Scripta Mater., 2011, 64(2):122-125 doi: 10.1016/j.scriptamat.2010.09.018
29. [29]
  Sa Q, Gratz E, He M, et al. J. Power Sources, 2015,282:140-145 doi: 10.1016/j.jpowsour.2015.02.046
30. [30]
  Wu F, Li N, Su Y F, et al. Adv. Mater., 2013,25(27):3722-3726 doi: 10.1002/adma.v25.27
31. [31]
  Zheng Z, Guo X D, Zhong Y J, et al. Electrochim. Acta, 2016,188:336-343 doi: 10.1016/j.electacta.2015.12.021
32. [32]
  Aurbach D, Levi M D, Gamulski K, et al. J. Power Sources, 1999,81-82(9):472-479
33. [33]
  Striebel K A, Sakai E, Cairns E J. J. Electrochem. Soc., 2002,149(1):A61-A68 doi: 10.1149/1.1427075
34. [34]
  Mai L, Li S, Dong Y, et al. Nanoscale, 2013,5(11):4864-4869 doi: 10.1039/c3nr01490h
35. [35]
  Li B, Han C, He Y B, et al. Energy Environ. Sci., 2012,5(11):9595-9602 doi: 10.1039/c2ee22591c
1. [1]
  Zhicheng JU , Wenxuan FU , Baoyan WANG , Ao LUO , Jiangmin JIANG , Yueli SHI , Yongli CUI . MOF-derived nickel-cobalt bimetallic sulfide microspheres coated by carbon: Preparation and long cycling performance for sodium storage. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 661-674. doi: 10.11862/CJIC.20240363
2. [2]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
3. [3]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
4. [4]
  Bowen Yang , Rui Wang , Benjian Xin , Lili Liu , Zhiqiang Niu . C-SnO₂/MWCNTs Composite with Stable Conductive Network for Lithium-based Semi-Solid Flow Batteries. Acta Physico-Chimica Sinica, 2025, 41(2): 100015-. doi: 10.3866/PKU.WHXB202310024
5. [5]
  Yuting ZHANG , Zunyi LIU , Ning LI , Dongqiang ZHANG , Shiling ZHAO , Yu ZHAO . Nickel vanadate anode material with high specific surface area through improved co-precipitation method: Preparation and electrochemical properties. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2163-2174. doi: 10.11862/CJIC.20240204
6. [6]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
7. [7]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
8. [8]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
9. [9]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100037-. doi: 10.3866/PKU.WHXB202408007
10. [10]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
11. [11]
  Xueyu Lin , Ruiqi Wang , Wujie Dong , Fuqiang Huang . 高性能双金属氧化物负极的理性设计及储锂特性. Acta Physico-Chimica Sinica, 2025, 41(3): 2311005-. doi: 10.3866/PKU.WHXB202311005
12. [12]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
13. [13]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
14. [14]
  Jiaxuan Zuo , Kun Zhang , Jing Wang , Xifei Li . 锂离子电池Ni-Co-Mn基正极材料前驱体的形核调控及机制. Acta Physico-Chimica Sinica, 2025, 41(1): 2404042-. doi: 10.3866/PKU.WHXB202404042
15. [15]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
16. [16]
  Hengyi ZHU , Liyun JU , Haoyue ZHANG , Jiaxin DU , Yutong XIE , Li SONG , Yachao JIN , Mingdao ZHANG . Efficient regeneration of waste LiNi_0.5Co_0.2Mn_0.3O₂ cathode toward high-performance Li-ion battery. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 625-638. doi: 10.11862/CJIC.20240358
17. [17]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
18. [18]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
19. [19]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Corrosion inhibition of nickel-cobalt-phosphide in water by coating TiO₂ layer. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 365-384. doi: 10.11862/CJIC.20240063
20. [20]
  Pengyang FAN , Shan FAN , Qinjin DAI , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Xiaoxiao HUANG , Yong ZHANG . Preparation and performance of rich 1T-MoS₂ nanosheets for high-performance aqueous zinc ion battery cathode materials. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 675-682. doi: 10.11862/CJIC.20240339

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(1017)
HTML views(237)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of Carbon-Coated LiNi1/3Co1/3Mn1/3O2 Cathode for High-Rate Lithium Ion Batteries

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation of Carbon-Coated LiNi_1/3Co_1/3Mn_1/3O₂ Cathode for High-Rate Lithium Ion Batteries