Citation: ZHENG Zhuo, HUA Wei-Bo, WU Zhen-Guo, XIANG Wei, ZHONG Ben-He, GUO Xiao-Dong. Controllable Preparation of Ultra-High Rate LiNi_1/3Co_1/3Mn_1/3O₂ Cathode Through Carbonate Co-precipitation Method for Li-Ion Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(2): 307-314. doi: 10.11862/CJIC.2017.010 shu

Controllable Preparation of Ultra-High Rate LiNi_1/3Co_1/3Mn_1/3O₂ Cathode Through Carbonate Co-precipitation Method for Li-Ion Batteries

1.
Polymer Research Institute, Sichuan University, Chengdu 610065, China
2.
School of Chemical Engineering, Sichuan University, Chengdu 610065, China
3.
College of Materials and Chemistry & Chemical Engineering, Chengdu University of Technology, Chengdu 610065, China
4.
Institute for Superconducting and Electronic Materials, University of Wollongong, Wollongong NSW 2522, Australia

Corresponding author: GUO Xiao-Dong, xiaodong2009@scu.edu.cn
Received Date: 12 August 2016
Revised Date: 15 October 2016

Figures(6)

The ultra-high rate nanostructured LiNi_1/3Co_1/3Mn_1/3O₂ cathode is controllably prepared by the carbonate co-precipitation method through tailoring the amount of the NH₃·H₂O. The NH₃·H₂O has a great effect on morphology, particle size, crystal structure and electrochemical performance. Powder X-ray diffraction (XRD)and scanning electron microscopy (SEM)results indicate that the morphology of primary particle is changed from nano-plate to nano-sphere with the decreasing of the NH₃·H₂O, and the sample with ratio n_NH₃·H₂O: (n_Ni+n_Co+n_Mn)=1:2 has the well-ordered-NaFeO₂ structure and the lowest cation mixing (Li⁺/Ni²⁺). Electrochemical results also confirm that the sample with ratio n_NH₃·H₂O: (n_Ni+n_Co+n_Mn)=1:2 has the best cycling stability and ultra-high rate capability. Specifically, it delivers a discharge capacity of 119 mAh·g^-1 between 2.7 and 4.3 V at 1C after 300 cycles with outstanding capacity retention of 81%, and the mid-point potential retention is 97%. This sample can still deliver a high discharge capacity of 56 mAh·g^-1 even at the ultra-high rate 100C (18 mAh·g^-1), which has the prospect to be applied in high power lithium ion battery. This nNH₃·H₂O ratio could provide some valuable reference for synthesizing other high-rate and high-capacity anode/cathode oxides.
- lithium-ion battery,
- cathode material,
- carbonate co-precipitation method,
- ultra-high rate performance
1. [1]
  Tarascon J M, Armand M. Nature, 2001, 414(6861):359-367 doi: 10.1038/35104644
2. [2]
  Manthiram A, Murugan A V, Sarkar A, et al. Energy Environ. Sci., 2008, 1:621-638 doi: 10.1039/b811802g
3. [3]
  Dunn B, Kamath H, Tarascon J M. Science, 2011, 334(6058):928-935 doi: 10.1126/science.1212741
4. [4]
  HUA Wei-Bo, ZHENG Zhuo, LI Long-Yan, et al. Acta Phys.-Chim. Sin., 2014, 30(8):1481-1486 doi: 10.3866/PKU.WHXB201405303
5. [5]
  Choi N S, Chen Z, Freunberger S A, et al. Angew. Chem. Int. Ed., 2012, 51(40):9994-10024 doi: 10.1002/anie.201201429
6. [6]
  WANG Hai-Yan, TANG Ai-Dong, HUANG Ke-Long, et al. Chinese J. Inorg. Chem., 2008, 24(4):593-599
7. [7]
  WEI Xuan-Ni, LAI Qiong-Jie, GAO Yuan, et al. Chinese J. Inorg. Chem., 2005, 21(7):999-1003
8. [8]
  Yabuuchi N, Ohzuku T. J. Power Sources, 2003, 119-121(6):171-174
9. [9]
  Gao P, Yang G, Liu H, et al. Solid State Ionics, 2012, 207(2):50-56
10. [10]
  Lee M H, Kang Y J, Myung S T, et al. Electrochim. Acta, 2004, 50(4):939-948 doi: 10.1016/j.electacta.2004.07.038
11. [11]
  Wang D, Belharouak I, Gary M K, et al. J. Mater. Chem., 2011, 21(25):9290-9295 doi: 10.1039/c1jm11077b
12. [12]
  Myung S T, Lee M H, Komaba S, et al. Electrochim. Acta, 2005, 50(24):4800-4806 doi: 10.1016/j.electacta.2005.02.034
13. [13]
  Park S H, Oh S, Sun Y K. J. Power Sources, 2005, 146(1/2):622-625
14. [14]
  Zheng Z, Guo X D, Chou S L, et al. Electrochim. Acta, 2016, 191:401-410 doi: 10.1016/j.electacta.2016.01.092
15. [15]
  Liu Zhi-Min. Thesis for the Doctorate of Central South University. 2009.
16. [16]
  Yec C C, Zeng H C. J. Mater. Chem. A, 2014, 14(14):4843-4851
17. [17]
  Huang Z D, Liu X M, Oh S W, et al. J. Mater. Chem., 2011, 21(29):10777-10784 doi: 10.1039/c1jm00059d
18. [18]
  Cho Y, Oh P, Cho J. Nano Lett., 2013, 13(3):1145-1152 doi: 10.1021/nl304558t
19. [19]
  Conry T E, Mehta A, Cabana J, et al. Chem. Mater., 2012, 24(17):3307-3317 doi: 10.1021/cm3011937
20. [20]
  Tan Xin-Xin. Thesis for the Master of Central South University. 2010.
21. [21]
  Wang F X, Xiao S Y, Chang Z, et al. Chem. Commun., 2013, 49(80):9209-9211 doi: 10.1039/c3cc44360d
22. [22]
  Zhang X J, Shi W H, Zhu J X, et al. Nano Res., 2010, 3(9):643-652 doi: 10.1007/s12274-010-0024-6
23. [23]
  Zheng Z, Wu Z G, Zhong Y J, et al. RSC Adv., 2015, 5(47):37330-37339 doi: 10.1039/C5RA03289J
24. [24]
  Jung S K, Gwon H, Hong J, et al. Adv. Energy Mater., 2014, 4(1):94-98
25. [25]
  ZHANG Ji-Bin, HUA Wei-Bo, ZHENG Zhuo, et al. Acta Phys.-Chim. Sin., 2015, 31(5):905-912 doi: 10.3866/PKU.WHXB201503091
26. [26]
  Huang Z D, Liu X M, Zhang B, et al. Scripta Mater., 2011, 64(2):122-125 doi: 10.1016/j.scriptamat.2010.09.018
27. [27]
  HUA Wei-Bo, GUO Xiao-dong, ZHENG Zhuo, et al. Chem. Res. Appl., 2014, 26(3):441-444
28. [28]
  Li J F, Xiong S L, Liu Y R, et al. Nano Energy, 2013, 2(6):1249-1260 doi: 10.1016/j.nanoen.2013.06.003
29. [29]
  Zhang T, Fu L J, Gao J, et al. J. Power Sources, 2007, 174(2):770-773 doi: 10.1016/j.jpowsour.2007.06.231
30. [30]
  Cui L, Shen J, Cheng F, et al. J. Power Sources, 2011, 196(4):2195-2201 doi: 10.1016/j.jpowsour.2010.09.075
31. [31]
  Wang L, Zhao J S, He X M, et al. Int. J. Electrochem. Sci., 2012, 7(1):345-353
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沈阳化工大学材料科学与工程学院沈阳 110142

Controllable Preparation of Ultra-High Rate LiNi1/3Co1/3Mn1/3O2 Cathode Through Carbonate Co-precipitation Method for Li-Ion Batteries

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通讯作者: 陈斌, bchen63@163.com

Controllable Preparation of Ultra-High Rate LiNi_1/3Co_1/3Mn_1/3O₂ Cathode Through Carbonate Co-precipitation Method for Li-Ion Batteries