Citation: NI Bang-Qing, LIU Hui, FAN Ming-Ming, ZHANG Ping-Bo. Construction and Properties of SO₄^2-/ZrO₂-SiO₂ Immobilized Ionic Liquid Catalysts with Double-Acid Active Sites[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(1): 97-105. doi: 10.11862/CJIC.2017.009 shu

Construction and Properties of SO₄^2-/ZrO₂-SiO₂ Immobilized Ionic Liquid Catalysts with Double-Acid Active Sites

School of Chemical and Material Engineering, Jiangnan University, Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, Wuxi, Jiangsu 214122, China

Corresponding author: FAN Ming-Ming, fanmm2000@126.com ZHANG Ping-Bo, pingbozhang@126.com
Received Date: 9 August 2016
Revised Date: 1 November 2016

Figures(10)

The immobilized catalyst SO₄^2-/ZrO₂-SiO₂-IL with double-acid active sites, namely Brönsted and Lewis acid sites, was synthesized by immobilization of acid ionic liquid sulfonic acid functionalized imidazolium hydrogen sulfate([Ps-im]HSO₄) onto the surface of the acidic mesoporous material SO₄^2-/ZrO₂-SiO₂ which was prepared by a one-step co-condensation technique combined with hydrothermal treatment. The structure of the catalyst was characterized by XRD, FT-IR, N2 absorption-desorption measurement, XPS, thermogravimetric analysis and TEM. The results showed that zirconium and acid structure (SO₄^2-) were incorporated into the framework of pure silicon, bringing a certain acidity; and it also demonstrated that the ionic liquid was successfully immobilized onto the acidic mesoporous materials SO₄^2-/ZrO₂-SiO₂ and the structure of the catalyst remained intact. The activity of SO₄^2-/ZrO₂-SiO₂-IL was investigated by the transesterification of soybean oil with methanol for biodiesel production as the probe reaction. The yield of biodiesel was more than 92% when the reaction was carried out under the following condition:reaction temperature, 150℃; reaction time, 4 h; amount of catalyst, 5%(w/w); methanol to soybean oil, 24:1. And the catalyst still yielded about 86% after five cycles.
- double-acid active sites,
- biodiesel,
- acidic mesoporous material,
- ionic liquid,
- immobilize
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通讯作者: 陈斌, bchen63@163.com

Construction and Properties of SO₄^2-/ZrO₂-SiO₂ Immobilized Ionic Liquid Catalysts with Double-Acid Active Sites