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Citation: ZHANG Ying-Xia, MI Chang-Huan, LI Hong-Sen. Electrochemical Properties of Fe(Ⅲ)-Doped Nb2O5 Micro/nano Spheres via Hydrothermal Synthesis[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(11): 1905-1910. doi: 10.11862/CJIC.2016.247 shu

Electrochemical Properties of Fe(Ⅲ)-Doped Nb2O5 Micro/nano Spheres via Hydrothermal Synthesis

  • 1.

    Jiangsu Key Laboratory of Materials and Technology for Energy Conversion, College of Matrials Sciense Engineering, Nanjing University of Aeronautics and Astroautics, Nanjing 210016, China

  • Corresponding author: MI Chang-Huan, 
  • Received Date: 28 March 2016
    Available Online: 19 August 2016

    Fund Project:

  • Fe(Ⅲ)-doped niobium oxide (Fe-Nb2O5) and Nb2O5 were prepared by the one-step hydrothermal route. Both samples were characterized by X-ray diffraction (XRD), electron microscopy(SEM), Transmission electron microscope(TEM) and so on. The results showed that Fe-Nb2O5 and Nb2O5 were orthorhombic phase. Nb2O5 was irregular particle with the wider size distribution of 50~300 nm, and Fe-Nb2O5 was homogeneous micro/nano sphere with the diameter of 1 μm, which assembled from 50 nm sized nano-particles The porous multistage structure could increase the contact interface between electrode materials and electrolyte. Electrochemical analyses showed that Fe-Nb2O5 has the better rate performance and cycle stability with a discharge capacity of 193.2 mAh·g-1 retained up to 100 cycles at 50 and 108.4 mAh·g-1 at 5 A·g-1, and the possible reasons were analyzed.
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