Citation: ZHANG Chang-Wei, DING Yan-Hua, ZHANG Na, ZHANG Jian-Yong, FANG Yong-Zheng, ZHANG Cheng. Eu²⁺, Mn²⁺, Sr²⁺ Tri-doped BaMgAl₁₀O₁₇ Phosphor: Solution Combustion Synthesis and Photoluminescence Properties[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(12): 2075-2081. doi: 10.11862/CJIC.2016.237 shu

Eu²⁺, Mn²⁺, Sr²⁺ Tri-doped BaMgAl₁₀O₁₇ Phosphor: Solution Combustion Synthesis and Photoluminescence Properties

1.
1 School of Materials Science and Engineering, Shanghai Institute of Technology, Shanghai 201418, China;
2.
2 School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418, China

Corresponding author: ZHANG Na, ZHANG Jian-Yong,
Received Date: 1 April 2016
Available Online: 20 September 2016
Fund Project:

Sr²⁺, Eu²⁺ and Mn²⁺ tri-doped BaMgAl₁₀O₁₇ (BAM) phosphors that emitting the blue-green light are prepared by solution combustion synthesis at 600℃. X-ray diffraction (XRD), scanning electron microscopy (SEM) and photoluminescence (PL) are employed to measure the powders crystallinity, morphology and luminescent properties, respectively. The results show that the formation temperature of the BAM phase by the solution combustion synthesis (SCS) method is significantly lower than that of a high temperature solid state (HTS) reaction. The nanorods of SBAM:Eu²⁺, Mn²⁺ without aggregation and well distribution are synthesized successfully. The well-dispersed morphology of the SCS-derived phosphors is beneficial to the improvement of PL property. While Sr²⁺ ions are introduced, the PL property have been further enhanced, and the PL intensity can up to 1.8 times as high of that BAM specimen obtained by the HTS method. The xy CIE chromaticity coordinates of SBAM:0.1Eu²⁺, 0.04Mn²⁺ phosphor is presented at (0.146, 0.250), located at the blue-green reign.
- solution combustion synthesis;BAM:Eu²⁺, Mn²⁺;optical material;blue-green phosphor
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Eu²⁺, Mn²⁺, Sr²⁺ Tri-doped BaMgAl₁₀O₁₇ Phosphor: Solution Combustion Synthesis and Photoluminescence Properties