Citation: WANG Yue, ZOU Xiao-Chuan, WANG Cun, SHI Yong-Fang. Thermolysis Synthesis and Growth Mechanism of Metastable MInS₂ (M=Ag, Cu) Flowerlike Microsphere[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(12): 2151-2157. doi: 10.11862/CJIC.2016.233 shu

Thermolysis Synthesis and Growth Mechanism of Metastable MInS₂ (M=Ag, Cu) Flowerlike Microsphere

1.
1 School of Biological and Chemical Engineering, Chongqing University of Education, Chongqing 400067, China;
2.
2 Key Laboratory of Research on Chemistry and Physics of Optoelectronic Materials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: WANG Yue, SHI Yong-Fang,
Received Date: 19 July 2016
Available Online: 17 September 2016
Fund Project:

3D metastable orthorhombic AgInS₂ and hexagonal CuInS₂ flowerlike microsphere were synthesized by the thermolysis method. The obtained products were characterized by X-ray diffraction (XRD), field-emission scanning electron microscope (FESEM), and the photocatalytic activity of AgInS₂ were investigated. Furthermore, the possible growth mechanism of metastable orthorhombic AgInS₂ and hexagonal CuInS₂ flowerlike microsphere was also proposed by means of thermogravimetric thermogravimetric and differential thermal analysis (TG-DTA). The results indicated that both the reaction temperature and feed ratio of metallic ion (n_M/n_In) had an influence on the formation of pure-phase MInS₂, and the prepared AgInS₂ flowerlike microsphere could well degrade methylene blue (MB) under visible light irradiation.
- metastable MInS₂;flowerlike microsphere;thermolysis method;growth mechanism
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Thermolysis Synthesis and Growth Mechanism of Metastable MInS2 (M=Ag, Cu) Flowerlike Microsphere

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Thermolysis Synthesis and Growth Mechanism of Metastable MInS₂ (M=Ag, Cu) Flowerlike Microsphere