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Citation: WANG Yue, ZOU Xiao-Chuan, WANG Cun, SHI Yong-Fang. Thermolysis Synthesis and Growth Mechanism of Metastable MInS2 (M=Ag, Cu) Flowerlike Microsphere[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(12): 2151-2157. doi: 10.11862/CJIC.2016.233 shu

Thermolysis Synthesis and Growth Mechanism of Metastable MInS2 (M=Ag, Cu) Flowerlike Microsphere

  • 1.

    1 School of Biological and Chemical Engineering, Chongqing University of Education, Chongqing 400067, China;

  • 2.

    2 Key Laboratory of Research on Chemistry and Physics of Optoelectronic Materials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

  • Corresponding author: WANG Yue,  SHI Yong-Fang, 
  • Received Date: 19 July 2016
    Available Online: 17 September 2016

    Fund Project:

  • 3D metastable orthorhombic AgInS2 and hexagonal CuInS2 flowerlike microsphere were synthesized by the thermolysis method. The obtained products were characterized by X-ray diffraction (XRD), field-emission scanning electron microscope (FESEM), and the photocatalytic activity of AgInS2 were investigated. Furthermore, the possible growth mechanism of metastable orthorhombic AgInS2 and hexagonal CuInS2 flowerlike microsphere was also proposed by means of thermogravimetric thermogravimetric and differential thermal analysis (TG-DTA). The results indicated that both the reaction temperature and feed ratio of metallic ion (nM/nIn) had an influence on the formation of pure-phase MInS2, and the prepared AgInS2 flowerlike microsphere could well degrade methylene blue (MB) under visible light irradiation.
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