Citation: WANG Ye-Chen, FENG Jian-Tao, WANG Xi-Ya, LI Liang-Chao. Preparation of Zinc Ferrite/Expanded Graphite Composites and Decontamination Performance on Humic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(9): 1526-1534. doi: 10.11862/CJIC.2016.208 shu

Preparation of Zinc Ferrite/Expanded Graphite Composites and Decontamination Performance on Humic Acid

College of Chemistry and Life Science, Zhejiang Normal University, Jinhua, Zhejiang 321004, China

Corresponding author: LI Liang-Chao, sky52@zjnu.cn
Received Date: 27 February 2016
Revised Date: 10 August 2016

Figures(14)

Zinc ferrite/expanded graphite (ZF/EG) composites were prepared using a simple chemical co-precipitation method. The composition, microstructure, magnetic property, adsorption and photocatalytic activity of the samples were characterized by means of modern analytical techniques. And the results showed that the magnetic composite not only held the original special structure and good adsorption properties of EG, but also had suitable magnetic property and photocatalytic activity. The removal rate of the samples on humic acid depends on the mass ratio of ZF to EG (m_ZF/m_E), adsorption time and pH of the solution, and so on. Removal rate of 0.1 g ZF/EG composite with m_EG/m_ZF=1 on humic acid (15 mg·L^-1, 100 mL, pH=7) was up to 95% under UV irradiation. After repeated use 4 times, removal rate of the composite on the humic acid declined only 4%. In addition, the samples can be recovered conveniently, activated easily and had good performance for recycling, and were thought to be a promising green and high-efficiency material in dealing with wastewater.
- expanded graphite,
- zinc ferrite,
- humic acid,
- aadsorption,
- photocatalysis
1. [1]
  Qin X P, Liu F, Wang G C, et al. Environ. Earth Sci., 2015, 73:4011-4017 doi: 10.1007/s12665-014-3686-7
2. [2]
  An J, Jho E H, Nam K. J. Hazard. Mater., 2015, 286:236-141 doi: 10.1016/j.jhazmat.2014.12.016
3. [3]
  Pinhedo L, Pelegrini R, Bertazzoli R, et al. Appl. Catal. B Environ., 2005, 57:75-81 doi: 10.1016/j.apcatb.2004.10.006
4. [4]
  Wang T C, Qu C Z, Ren J Y, et al. Water Res., 2016, 89:28-38 doi: 10.1016/j.watres.2015.11.039
5. [5]
  HAN Zhi-Dong, ZHANG Da-Wei, DONG Li-Min, et al. Chinese J. Inorg. Chem., 2007, 23:286-290 doi: 10.3321/j.issn:1001-4861.2007.02.017
6. [6]
  Toyoda M, Inagaki M. Carbon, 2000, 38:199-210 doi: 10.1016/S0008-6223(99)00174-8
7. [7]
  Zhou Y Y, Wang S W, Kim K N, et al. Talanta, 2006, 69: 970-975 doi: 10.1016/j.talanta.2005.11.048
8. [8]
  Bourlinos A B, Steriotis T A, Karakassides M, et al. Carbon, 2007, 45:852-857 doi: 10.1016/j.carbon.2006.11.008
9. [9]
  Li J B, Xiao Q S, Li L C, et al. Appl. Surf. Sci., 2015, 331: 108-144 doi: 10.1016/j.apsusc.2015.01.001
10. [10]
  Kobayashi M, Shirai H, Nunokawa M. Ind. Eng. Chem. Res., 2002, 41:2903-2909 doi: 10.1021/ie010846r
11. [11]
  Vermisoglou E C, Giannakopoulou T, Romanos G E, et al. Appl. Surf. Sci., 2015, 358:110-121 doi: 10.1016/j.apsusc.2015.08.123
12. [12]
  Zhao Y, Ma C L, Li Y, et al. Carbon, 2015, 95:494-496 doi: 10.1016/j.carbon.2015.08.053
13. [13]
  Yan Y, Ben L, Zhan Y, et al. Electrochim. Acta, 2016, 187: 186-192 doi: 10.1016/j.electacta.2015.11.015
14. [14]
  Lee J H, Kim S. Energy Build., 2012, 46:56-61 doi: 10.1016/j.enbuild.2011.10.046
15. [15]
  Jin H Y, Ji Z J, Yuan J, et al. J. Alloy. Compd., 2015, 620: 361-367 doi: 10.1016/j.jallcom.2014.09.143
16. [16]
  Zhang J, Wang X, Wang X, et al. RSC Adv., 2015, 5:71922 -71931 doi: 10.1039/C5RA12783A
17. [17]
  FENG Jian-Tao, CHEN Hai-feng, LI Liang-Chao. Sci. Sin. Chim., 2015, 45:1075-1088
18. [18]
  Li S, Tian S H, Feng Y F, et al. J. Hazard. Mater., 2010, 183:506-511 doi: 10.1016/j.jhazmat.2010.07.052
19. [19]
  Jiang L, Zhang J, Xu X, et al. Appl. Surf. Sci., 2015, 357: 2355-2363 doi: 10.1016/j.apsusc.2015.09.241
20. [20]
  Yu X Z, Shen Z A. J. Magn. Magn. Mater., 2009, 321:2890-2895 doi: 10.1016/j.jmmm.2009.04.040
21. [21]
  Wang X, Wu Z, Wang Y, et al. J. Hazar. Mater., 2013, 262: 16-24 doi: 10.1016/j.jhazmat.2013.08.037
22. [22]
  CHEN Hai-Feng, MA Ge, LI Liang-Chao, et al. Chinese J. Inorg. Chem., 2013, 29:479-485 doi: 10.3969/j.issn.1001-4861.2013.00.057
23. [23]
  Pang X Y, Ren H L, Gong F, et al. J. Environ. Sci. Eng., 2008, 2:18-23
24. [24]
  LIANG Xiao-Xi, CHEN Ke-Yu, LI Liang-Chao, et al. Sci. Sin. Chim., 2013, 43: 840-847
25. [25]
  Su M H, He C, Sharma V K, et al. J. Hazard. Mater., 2012, 21:95-103
26. [26]
  Casbeer E, Sharma V K, Li X Z. Sep. Purif. Technol., 2012, 87:1-14 doi: 10.1016/j.seppur.2011.11.034
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