Citation: LIN Long, LI Xian-Hong, ZHANG Bo, ZHANG Zhan-Ying, WU Wei-Na, WANG Yuan. Syntheses, Crystal Structures and Fluorescence Properties of Cu(Ⅱ)/Zn(Ⅱ)/Ag(Ⅰ) Complexes with an Amide Type Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(9): 1653-1658. doi: 10.11862/CJIC.2016.204 shu

Syntheses, Crystal Structures and Fluorescence Properties of Cu(Ⅱ)/Zn(Ⅱ)/Ag(Ⅰ) Complexes with an Amide Type Ligand

LIN Long ^1,*,, ,
LI Xian-Hong ¹ ,
ZHANG Bo ¹ ,
ZHANG Zhan-Ying ¹ ,
WU Wei-Na ^2,*,, ,
WANG Yuan ²

1.
School of Materials Science and Engineering, Henan Polytechnic University, Jiaozuo, Henan 454000, China
2.
College of Chemistry and Chemical Engineering, Henan Polytechnic University, Jiaozuo, Henan 454000, China

Corresponding author: LIN Long, linlong@hpu.edu.cn WU Wei-Na, wuwn08@hpu.edu.cn
Received Date: 11 June 2016
Revised Date: 1 August 2016

Figures(3)

Five complexes, [CuLCl₂]·CH₃COCH₃ (1), [ZnLCl₂]·CH₃COCH₃ (2), [ZnL(NO₃)₂]·0.5CH₃COCH₃ (3), [AgL₂]ClO₄ (4) and [AgL₂]BF₄ (5) (L=2-(5-chloroquinolin-8-yloxy)-1-(pyrrolidin-1-yl)ethanone), were synthesized and characterized by X-ray diffraction. Complexes 1 and 2 are isostructural, and in each of them the five-coordinated metal ion is in a distorted tetragonal pyramid with a NO₂ donor set from one ligand L and two chloride anions. However, the Zn(Ⅱ) ion in complex 3 is coordinated with one tridentate ligand L, one monodentate and one bidentate nitrate anions, giving a distorted octahedral coordination geometry. The structures of 1~3 are quite similar as those of the acetonitrile solvates derived from the same ligand L and metal salts. By contrast, the ratio of the metal ion and ligand L is 1:2 in complexes 4 and 5, the central Ag(Ⅰ) ion in each complex is six-coordinated with two independent ligands with N₂O donor set, thus possesses a distorted octahedral coordination geometry. In CH₃CN solution, the emission spectra of complexes 1, 3, 4 and 5 exhibit similar peak at 410 nm as the ligand L. However, the emission band of complex 3 red-shifts to 430 nm because of energy transferring from the ligand L to the Zn(Ⅱ) ion. CCDC: 1484068, 1; 1484069, 2; 1484070, 3; 1484071, 4; 1484072, 5.
- Cu(Ⅱ) complex,
- Zn(Ⅱ) complex,
- Ag(Ⅰ) complex,
- amide type ligand,
- fluorescence
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沈阳化工大学材料科学与工程学院沈阳 110142