Citation: WU Xiao-Shuo, WANG Peng-Fei, LU Peng-Peng, XU Si-Yuan. Three Transition Metal Coordination Complexes Based on the Substituted Benzenecarboxylic Acid and Flexible N-donor Co-ligands: Syntheses, Crystal Structures, and Physical Properties[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(9): 1667-1675. doi: 10.11862/CJIC.2016.191 shu

Three Transition Metal Coordination Complexes Based on the Substituted Benzenecarboxylic Acid and Flexible N-donor Co-ligands: Syntheses, Crystal Structures, and Physical Properties

School of Chemistry and Material Engineering, Chizhou College, Chizhou, Anhui 247000, China

Corresponding author: WANG Peng-Fei, njuwangpf@163.com
Received Date: 9 May 2016
Revised Date: 21 June 2016

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The hydrothermal reactions of 3,5-dinitrobenzoic acid (3,5-DNBH), 1,2-bis(imidazol-1-ylmethyl)benzene (1,2-bimb) and transition metal salts result in three new transition metal coordination complexes, namely, [M(3,5-DNB)₂(1,2-bimb)] (M=Co(Ⅱ) (1), Cd(Ⅱ) (3)) and [Zn(3,5-DNB)₂(1,2-bimb)]_n (2). These complexes were characterized by IR spectra, elemental analyses, single-crystal and powder X-ray diffraction analyses. Complexes 1 and 3 are isostructural and contain a dinuclear [M₂(COO)₂] (M=Co(Ⅱ) (1), Cd(Ⅱ) (3)) unit made up of metal ions, 3,5-DNB-and 1,2-bimb ligands, which further form the supramolecular structures by the O…π interactions between the nitro group oxygen atom of 3,5-DNB^- anions and the benzene ring of 1,2-bimb molecules. Complex 2 features a 1D chain structure, which further packs to the supramolecular structure by the π…π interactions between the benzene rings from the 3,5-DNB^- anions. The fluorescence properties of the dispersion methanol solution of complexes 2 and 3 have been investigated at room temperature. Relatively high thermal stabilities are found in the three complexes according to the TGA curves. Photocatalytic studies of 1 indicate good degradation ability over rhodamine B (RhB) under visible light irradiation. Furthermore, the dc magnetic susceptibility measurement of 1 reveals that dominant antiferromagnetic interactions are propagated between the Co(Ⅱ) ions in 1. CCDC: 1476334, 1; 1476335, 2; 1476336, 3.
- transition metal complexes,
- magnetic property,
- photocatalytic activity
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