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Citation: WANG Gui-Xian, CHEN Fei-Yan, WANG Xiao-Juan, FENG Yun-Long. Four-and Three-Fold Interpenetrated (3, 4)-Connected d10 Metal Coordination Polymers Constructed by 3, 5-Bis (pyridin-4-ylmethoxy) benzoic Acid and Aromatic Dicarboxylic Acid Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(3): 545-554. doi: 10.11862/CJIC.2016.062 shu

Four-and Three-Fold Interpenetrated (3, 4)-Connected d10 Metal Coordination Polymers Constructed by 3, 5-Bis (pyridin-4-ylmethoxy) benzoic Acid and Aromatic Dicarboxylic Acid Ligands

  • 1.

    Department of chemistry and chemical engineering, Lishui University, Lishui, Zhejiang 323000, China

  • 2.

    Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, College of Chemistry and Life Science, Zhejiang Normal University, Jinhua, Zhejiang 321004, China

  • Corresponding author: FENG Yun-Long, sky37@zjnu.cn
  • Received Date: 20 October 2015
    Revised Date: 9 January 2016

Figures(8)

  • The reaction of 3, 5-bis (pyridin-4-ylmethoxy) benzoic acid (HL) and a combination of dicarboxylic acid ligands such as thiophene-2, 5-dicarboxylic acid (H2tdc), 5-hydroxybenzene-1, 3-dicarboxylic acid (H3hdc), 1, 4-benzenedithioacetic acid (H2bdtc) with Zn (Ⅱ) and Cd (Ⅱ) metal ions give rise to four coordination polymers with interpenetrating (3, 4)-connected networks, namely, [Zn2L2(tdc)]n (1), {[Zn4L4(Hhdc)2]·H2O}n (2), {[Zn2L2(Hhdc)]·H2O}n (3), {[Cd2L2(bdtc)(H2O)]· 0.5H2O}n (4). 1~3 exhibit (3, 4)-connected 4-fold-interpenetrating 3D networks with point symbol of (4.82)(4.85) (1), (63)(65.8) (2) and (63)(65.8) (3) topology, respectively. 4 displays a (3, 4)-connected 3-fold-interpenetrating 2D network with (63)(66) topology. Luminescent properties of 1, 3 and 4 were also investigated. CCDC: 852424, 1; 872035, 2; 887738, 3; 872037, 4.
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