Citation: FANG Zhi-Li, XIONG Shan, LI Kang-Yu, YU Quan-Feng, XU Wen-Yuan. Two Heterometallic 4d-4f Coordination Polymers Based on 4-(1H-1, 2, 4-TriazoL^-1-yl) benzoic Acid: Syntheses, Structures, and Fluorescence Properties[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(2): 280-288. doi: 10.11862/CJIC.2016.046 shu

Two Heterometallic 4d-4f Coordination Polymers Based on 4-(1H-1, 2, 4-TriazoL^-1-yl) benzoic Acid: Syntheses, Structures, and Fluorescence Properties

School of Science, East China Jiaotong University, Nanchang 330013, China

Corresponding author: FANG Zhi-Li, fangzhili1972@126.com
Received Date: 1 June 2015
Revised Date: 4 December 2015

Fund Project: 国家自然科学基金 21365012

Figures(11)

Two 2D heterometallic 4d-4f coordination polymers, {[EuAg (tbc)₃ (H₂O)]ClO₄·H₂O}_n (1) and {[Eu₂Ag₃(tbc)₆(NO₃)₂(H₂O)₂](ClO₄)₂·2H₂O}_n (2) (Htbc=4-(1H-1, 2, 4-triazoL^-1-yl) benzoic acid) were synthesized under hydro-thermal condition using one-step approach and structurally characterized by elemental analysis, FT-IR, powder X-ray diffraction and single-crystal X-ray diffraction. The single-crystal X-ray diffraction analysis reveals that the two complexes present two different types of two dimensional (2D) structures. Complex 1 crystallized in an orthorhombic manner having a P212121 space group, consisting of 1D triple-stranded helical (PPM) [Eu (μ₃-OCO)₂ (μ₂-OCO)] motif as chain which are further linked by the fragments of tbc-ligands and Ag (Ⅰ). Polymer 2 is crystallized in a triclinic fashion having a P1 space group, consisting of 1D mesomeric chains [Eu (μ₃-OCO)₂] which were further linked by the two different [N-Ag-N] units to form an interesting 2D 4d-4f heterometallic coordination polymer in the ab plane. The solid-state luminescent behaviors of compounds 1 and 2 were investigated at room temperature. CCDC: 1018336, 1; 1024087 2.
- 4-(1H-1, 2, 4-triazoL^-1-yl) benzoic acid ligand,
- heterometallic,
- crystal structure
1. [1]
  Xie S M, Zhang Z J, Wang Z Y, et al. J. Am. Chem. Soc., 2011, 133:11892-11895 doi: 10.1021/ja2044453
2. [2]
  Nuzhdin A L, Dybtsev D N, Bryliakov K P, et al. J. Am. Chem. Soc., 2007, 129:12958-12959 doi: 10.1021/ja076276p
3. [3]
  Seo J S, Whang D, Lee H, et al. Nature, 2000, 404:982-986 doi: 10.1038/35010088
4. [4]
  Qu Z R, Zhao H, Wang Y P, et al. Chem. Eur. J., 2004, 10: 53-60
5. [5]
  Ye H T, Ren C Y, Hou G F, et al. Cryst. Growth Des., 2014, 14:3309-3318 doi: 10.1021/cg500197v
6. [6]
  Train C, Gheorghe R, Krstic V, et al. Nat. Mater., 2008, 7: 729-734 doi: 10.1038/nmat2256
7. [7]
  Barron L D. Nat. Mater., 2008, 7:691-692 doi: 10.1038/nmat2263
8. [8]
  Zhang W, Xiong R G. Chem. Rev., 2012, 112:1163-1195 doi: 10.1021/cr200174w
9. [9]
  YU Gang, BIAN Zu-Qiang, LIU Zhi-Wei, et al. Sci. China Ser. B: Chem., 2014, 4(2):267-276
10. [10]
  Gu X, Xue D. Inorg. Chem., 2006, 45:9257-9261 doi: 10.1021/ic060806l
11. [11]
  Lestari W W, Lnnecke P, Streit H C, et al. Eur. J. Inorg. Chem., 2014:1775-1782
12. [12]
  Li J R, Tao Y, Yu Q, et al. Chem. Eur. J., 2008, 14:2771-2776 doi: 10.1002/(ISSN)1521-3765
13. [13]
  YAO Ke-Min, LI Ning, HUANG Qiao-Hong, et al. Sci. China Ser. B: Chem., 1998, 28(6):517-523
14. [14]
  Liu Q Y, Xiong W L, Liu C M, et al. Inorg. Chem., 2013, 52:6773-6775 doi: 10.1021/ic400853r
15. [15]
  Tanase S, Andruh M, Müller A, et al. Chem. Commun., 2001:1084-1085
16. [16]
  GU Jin-Zhong, JIANG Long, LU Tong-Bu, et al. Chinese J. Inorg. Chem., 2008, 24:1743-1747 doi: 10.3321/j.issn:1001-4861.2008.11.003
17. [17]
  Lampropoulos C, Koo C, Hill S O, et al. Inorg. Chem., 2008, 47:11180-11190 doi: 10.1021/ic801484g
18. [18]
  Mukherjee S, Lan Y, Novitchi G, et al. Polyhedron, 2009, 28:1782-1787 doi: 10.1016/j.poly.2008.12.003
19. [19]
  Li Z Y, Huang H Q, Xu L, et al. Cryst. Growth Des., 2013, 13:918-925 doi: 10.1021/cg301649p
20. [20]
  Sun Y G, Wu Y L, Xiong G, et al. Dalton Trans., 2010, 39: 11383-11395 doi: 10.1039/c0dt00579g
21. [21]
  Chen R L, Chen X Y, Zheng S R, et al. Cryst. Growth Des., 2013, 13:4428-4434 doi: 10.1021/cg400926q
22. [22]
  Andrews M B, Cahill C L. CrystEngComm, 2011, 13:7068-7078 doi: 10.1039/c1ce05934c
23. [23]
  Cai B, Yang P, Dai J W, et al. CrystEngComm, 2011, 13: 985-991 doi: 10.1039/C0CE00340A
24. [24]
  Cai S L, Zheng S R, Wen Z Z, et al. Cryst. Growth. Des., 2012, 12:2355-2361 doi: 10.1021/cg3000203
25. [25]
  Zhou Y, Li X, Zhang L, et al. Inorg. Chem., 2014, 53:3362-3370 doi: 10.1021/ic402718c
26. [26]
  Sheldrick G M. SADABS, Program for Empirical Absorption Correction, University of Göttingen, Germany, 1996.
27. [27]
  Sheldrick G M. SHELXS-97 and SHELXL-97, Program for the Solution of Crystal Structure, University of Göttingen, Germany, 1997.
28. [28]
  Quici S, Cavazzini M, Marzanni G, et al. Inorg. Chem., 2005, 44:529-537 doi: 10.1021/ic0486466
1. [1]
  Jia JI , Zhaoyang GUO , Wenni LEI , Jiawei ZHENG , Haorong QIN , Jiahong YAN , Yinling HOU , Xiaoyan XIN , Wenmin WANG . Two dinuclear Gd(Ⅲ)-based complexes constructed by a multidentate diacylhydrazone ligand: Crystal structure, magnetocaloric effect, and biological activity. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 761-772. doi: 10.11862/CJIC.20240344
2. [2]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
3. [3]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
4. [4]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
5. [5]
  Yao HUANG , Yingshu WU , Zhichun BAO , Yue HUANG , Shangfeng TANG , Ruixue LIU , Yancheng LIU , Hong LIANG . Copper complexes of anthrahydrazone bearing pyridyl side chain: Synthesis, crystal structure, anticancer activity, and DNA binding. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 213-224. doi: 10.11862/CJIC.20240359
6. [6]
  Yinling HOU , Jia JI , Hong YU , Xiaoyun BIAN , Xiaofen GUAN , Jing QIU , Shuyi REN , Ming FANG . A rhombic Dy₄-based complex showing remarkable single-molecule magnet behavior. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 605-612. doi: 10.11862/CJIC.20240251
7. [7]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
8. [8]
  Lulu DONG , Jie LIU , Hua YANG , Yupei FU , Hongli LIU , Xiaoli CHEN , Huali CUI , Lin LIU , Jijiang WANG . Synthesis, crystal structure, and fluorescence properties of Cd-based complex with pcu topology. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 809-820. doi: 10.11862/CJIC.20240171
9. [9]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
10. [10]
  Xiumei LI , Linlin LI , Bo LIU , Yaru PAN . Syntheses, crystal structures, and characterizations of two cadmium(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 613-623. doi: 10.11862/CJIC.20240273
11. [11]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
12. [12]
  Xiaoling WANG , Hongwu ZHANG , Daofu LIU . Synthesis, structure, and magnetic property of a cobalt(Ⅱ) complex based on pyridyl-substituted imino nitroxide radical. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 407-412. doi: 10.11862/CJIC.20240214
13. [13]
  Yan XU , Suzhi LI , Yan LI , Lushun FENG , Wentao SUN , Xinxing LI . Structure variation of cadmium naphthalene-diphosphonates with the changing rigidity of N-donor auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 395-406. doi: 10.11862/CJIC.20240226
14. [14]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
15. [15]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
16. [16]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
17. [17]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
18. [18]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
19. [19]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
20. [20]
  Zhaodong WANG . In situ synthesis, crystal structure, and magnetic characterization of a trinuclear copper complex based on a multi-substituted imidazo[1,5-a]pyrazine scaffold. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 597-604. doi: 10.11862/CJIC.20240268

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(249)
HTML views(16)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Two Heterometallic 4d-4f Coordination Polymers Based on 4-(1H-1, 2, 4-TriazoL-1-yl) benzoic Acid: Syntheses, Structures, and Fluorescence Properties

Metrics

通讯作者: 陈斌, bchen63@163.com

Two Heterometallic 4d-4f Coordination Polymers Based on 4-(1H-1, 2, 4-TriazoL^-1-yl) benzoic Acid: Syntheses, Structures, and Fluorescence Properties