Citation: SUN Yin-Xia, LI Chun-Yu, YANG Cheng-Juan, ZHAO Ya-Yuan, GUO Jian-Qiang, YU Bin. Two Cu (Ⅱ) Complexes with Schiff Base Ligands: Syntheses, Crystal Structures, Spectroscopic Properties, and Substituent Effect[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(2): 327-335. doi: 10.11862/CJIC.2016.034 shu

Two Cu (Ⅱ) Complexes with Schiff Base Ligands: Syntheses, Crystal Structures, Spectroscopic Properties, and Substituent Effect

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, China

Corresponding author: SUN Yin-Xia, sun_yinxia@163.com
Received Date: 8 September 2015
Revised Date: 25 November 2015

Figures(11)

Two new Cu (Ⅱ) complexes [Cu (L¹)₂](1) (HL¹=1-(3-((2-hydroxybenzylidene) amino) phenyl) ethanone O-benzyl oxime) and [Cu (L²)₂] (2) (HL² =1-(3-((2-Hydroxy-naphthalen-1-ylmethylene)-amino)-phenyl)-ethanone oxime) have been synthesized and characterized by elemental analyses, IR spectra, UV-Vis spectra, fluorescence measurement and X-ray single crystal diffraction method. X-ray crystallographic analyses have indicated that complexes 1 and 2 have the similar structure, consisting of one Cu (Ⅱ) ion, two ligand units. In the complexes, the Cu (Ⅱ) ion lying on an inversion centre, is four-coordinated in a trans-CuN₂O₂ square-planar geometry by two hydroxy O and two imine N atoms from two symmetry-related N, O-bidentate Schiff base ligands. The supramolecular structures of the two complexes 1 and 2 are also similar two-dimensional supramolecular structure linking by different intermolecular interaction. Complex 1 forms an infinite two-dimensional supramolecular structure by two π…π interaction, while that of complex 2 by intermolecular O-H…N and C-H…π hydrogen bond interactions. The fluorescence property of complex 1 and substituent effects of the two complexes are discussed. CCDC: 1003363, 1; 1043506, 2.
- Cu (Ⅱ) complex,
- crystal structure,
- Schiff base ligand,
- substituent effect
1. [1]
  Pini D, Mandoli A, Orlandi S, et al. Tetrahedron: Asymmetry, 1999, 10(20):3883-3886 doi: 10.1016/S0957-4166(99)00426-7
2. [2]
  Yang H Q, Zhang L, Zhong L, et al. Angew. Chem. Int. Ed., 2007, 46(36):6861-6865 doi: 10.1002/(ISSN)1521-3773
3. [3]
  Brewer C, Brewer G, Scheidt W R, et al. Inorg. Chim. Acta., 2001, 313(1):65-70
4. [4]
  Brayshaw P A, Bünzli J-C G, Froidevaux P, et al. Inorg. Chem., 1995, 34:2068-2076 doi: 10.1021/ic00112a019
5. [5]
  Miyasaka H, Matsumoto N, Okawa H, et al. J. Am. Chem. Soc., 1996, 118(5):981-994 doi: 10.1021/ja952706c
6. [6]
  Bencini A, Benelli C, Caneschi A, et al. J. Am. Chem. Soc., 1985, 107(26):8128-8136 doi: 10.1021/ja00312a054
7. [7]
  Sasaki M, Manseki K, Horiuchi H, et al. J. Chem. Soc. Dalton Trans., 2000, 3:259-263
8. [8]
  Edder C, Piguet C, Bünzli J-C G, et al. Chem. Eur. J., 2001, 7(14):3014-3024 doi: 10.1002/(ISSN)1521-3765
9. [9]
  Bünzli J C G, Piguet C. Chem. Rev., 2002, 102(6):1897-1928 doi: 10.1021/cr010299j
10. [10]
  Kohawole G A, Patel K S J. Chem. Soc., Dalton Trans., 1981, 1241-1245
11. [11]
  Sun Y X, Wang L, Dong X Y, et al. Synth. React. Inorg. Met.-Org. Nano-Met. Chem., 2013, 43(5):599-603 doi: 10.1080/15533174.2012.751424
12. [12]
  Sun Y X, Xu L, Zhao T H, et al. Synth. React. Inorg. Met-Org. Nano-Met. Chem., 2013, 43(4):509-513 doi: 10.1080/15533174.2012.740756
13. [13]
  DONG Wen-Kui, TANG Xiao-Lu, HE Xue-Ni, et al. Chinese. J. Inorg. Chem., 2009, 25(3):528-532
14. [14]
  Sheldrick G M. SADABS, University of Göttingen, Germany, 1996.
15. [15]
  Sheldrick G M. SHELXS 97, Program for Refinement of Crystal Structures, University of Göttingen, Germany, 1997.
16. [16]
  Asadi M, Jamshid K A, Kyanfar A H. Inorg. Chim. Acta, 2007, 360:1725-1730 doi: 10.1016/j.ica.2006.09.013
17. [17]
  Tümer M, Koksal H, Sener M K, et al. Transition Met. Chem., 1999, 24(4):414-420 doi: 10.1023/A:1006973823926
18. [18]
  Majumder A, Rosair G M, Mallick A, et al. Polyhedron, 2006, 25:1753-1762 doi: 10.1016/j.poly.2005.11.029
19. [19]
  Akine S, Taniguchi T, Nabeshima T. Inorg. Chem., 2004, 43: 6142-6144 doi: 10.1021/ic049282k
20. [20]
  Gomes L, Pereira E, Castro D B. J. Chem. Soc. Dalton Trans., 2000, 8:1373-1379
21. [21]
  Dong W K, He X N, Yan H B, et al. Polyhedron, 2009, 28: 1419-1428 doi: 10.1016/j.poly.2009.03.017
22. [22]
  Nathan L C, Koehne J E, Gilmore J M, et al. Polyhedron, 2003, 22(6):887-894 doi: 10.1016/S0277-5387(03)00029-9
1. [1]
  Yinling HOU , Jia JI , Hong YU , Xiaoyun BIAN , Xiaofen GUAN , Jing QIU , Shuyi REN , Ming FANG . A rhombic Dy₄-based complex showing remarkable single-molecule magnet behavior. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 605-612. doi: 10.11862/CJIC.20240251
2. [2]
  Jia JI , Zhaoyang GUO , Wenni LEI , Jiawei ZHENG , Haorong QIN , Jiahong YAN , Yinling HOU , Xiaoyan XIN , Wenmin WANG . Two dinuclear Gd(Ⅲ)-based complexes constructed by a multidentate diacylhydrazone ligand: Crystal structure, magnetocaloric effect, and biological activity. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 761-772. doi: 10.11862/CJIC.20240344
3. [3]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
4. [4]
  Lulu DONG , Jie LIU , Hua YANG , Yupei FU , Hongli LIU , Xiaoli CHEN , Huali CUI , Lin LIU , Jijiang WANG . Synthesis, crystal structure, and fluorescence properties of Cd-based complex with pcu topology. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 809-820. doi: 10.11862/CJIC.20240171
5. [5]
  Xiaoling WANG , Hongwu ZHANG , Daofu LIU . Synthesis, structure, and magnetic property of a cobalt(Ⅱ) complex based on pyridyl-substituted imino nitroxide radical. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 407-412. doi: 10.11862/CJIC.20240214
6. [6]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
7. [7]
  Yao HUANG , Yingshu WU , Zhichun BAO , Yue HUANG , Shangfeng TANG , Ruixue LIU , Yancheng LIU , Hong LIANG . Copper complexes of anthrahydrazone bearing pyridyl side chain: Synthesis, crystal structure, anticancer activity, and DNA binding. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 213-224. doi: 10.11862/CJIC.20240359
8. [8]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
9. [9]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
10. [10]
  Xiumei LI , Linlin LI , Bo LIU , Yaru PAN . Syntheses, crystal structures, and characterizations of two cadmium(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 613-623. doi: 10.11862/CJIC.20240273
11. [11]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
12. [12]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
13. [13]
  Yan XU , Suzhi LI , Yan LI , Lushun FENG , Wentao SUN , Xinxing LI . Structure variation of cadmium naphthalene-diphosphonates with the changing rigidity of N-donor auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 395-406. doi: 10.11862/CJIC.20240226
14. [14]
  Xiaofen GUAN , Yating LIU , Jia LI , Yiwen HU , Haiyuan DING , Yuanjing SHI , Zhiqiang WANG , Wenmin WANG . Synthesis, crystal structure, and DNA-binding of binuclear lanthanide complexes based on a multidentate Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2486-2496. doi: 10.11862/CJIC.20240122
15. [15]
  Tao Yu , Vadim A. Soloshonok , Zhekai Xiao , Hong Liu , Jiang Wang . Probing the dynamic thermodynamic resolution and biological activity of Cu(Ⅱ) and Pd(Ⅱ) complexes with Schiff base ligand derived from proline. Chinese Chemical Letters, 2024, 35(4): 108901-. doi: 10.1016/j.cclet.2023.108901
16. [16]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
17. [17]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
18. [18]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
19. [19]
  Maitri Bhattacharjee , Rekha Boruah Smriti , R. N. Dutta Purkayastha , Waldemar Maniukiewicz , Shubhamoy Chowdhury , Debasish Maiti , Tamanna Akhtar . Synthesis, structural characterization, bio-activity, and density functional theory calculation on Cu(Ⅱ) complexes with hydrazone-based Schiff base ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1409-1422. doi: 10.11862/CJIC.20240007
20. [20]
  Zhaodong WANG . In situ synthesis, crystal structure, and magnetic characterization of a trinuclear copper complex based on a multi-substituted imidazo[1,5-a]pyrazine scaffold. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 597-604. doi: 10.11862/CJIC.20240268

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(396)
HTML views(73)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142