Citation: ZHANG Qian, HAN Yan, JIAO Yuan-Hong. Synthesis, Crystal Structure and Catecholase Activity of the Cobalt (Ⅱ) Complex Containing Benzimidazole Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(1): 131-138. doi: 10.11862/CJIC.2016.031 shu

Synthesis, Crystal Structure and Catecholase Activity of the Cobalt (Ⅱ) Complex Containing Benzimidazole Ligand

ZHANG Qian ¹ ,
HAN Yan ² ,
JIAO Yuan-Hong ^1,*,,

1.
College of Chemistry and Chemical Engineering, Hubei Polytechnic University, Huangshi, Hubei 435003, China
2.
College of Chemistry and Chemical Engineering, Xinxiang University, Xinxiang, Henan 453003, China

Corresponding author: JIAO Yuan-Hong, yhjiao2014@163.com
Received Date: 21 July 2015
Revised Date: 16 November 2015

Figures(8)

A cobalt (Ⅱ) complex, [CoLCl]₂[CoLCl_0.5(H₂O)_0.5]₂ClO₄·10H₂O (1) (LH=(2-(bis ((1H-benzo[d]-imidazol-2-yl) methyl) amino) acetic acid)) has been synthesized and characterized. Its catecholase catalytic activity has been exploited by UV-Vis spectrophotometric study by using 3, 5-di-tert-butylcatechol (3, 5-DTBC) as the substrate. The results showed that two cobalt (Ⅱ) ions of the asymmetric unit were both coordinated by the ligands in a distorted trigonal-bipyramidal geometry in the crystal structure. Complex 1 exhibited pH value dependence for the oxidation of 3, 5-DTBC in the range of pH 5 to 11, and its catecholase catalytic activity increased with increasing temperature. The kinetics of oxidation of 3, 5-DTBC catalyzed by complex 1 accorded with the Michaelis-Mentent equation. CCDC: 950329, 1.
- cobalt (Ⅱ) complex,
- crystal structure,
- catecholase,
- catalytic activity
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沈阳化工大学材料科学与工程学院沈阳 110142