Citation: LIU Xuan-Wen, QI Jian-Quan, GUO Rui, LIU Fang-Chen, LIU Guang, ZHANG Xiao-Lei, ZHANG Yang. Synthesis and up/down Conversion Luminescence Properties of Er³⁺/Yb³⁺ Co-doped La₂TiO₅ Phosphor[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(1): 49-55. doi: 10.11862/CJIC.2016.022 shu

Synthesis and up/down Conversion Luminescence Properties of Er³⁺/Yb³⁺ Co-doped La₂TiO₅ Phosphor

LIU Xuan-Wen ^1,2 ,
QI Jian-Quan ^1,2 ,
GUO Rui ^1,2,*,, ,
LIU Fang-Chen ^1,2 ,
LIU Guang ^1,2 ,
ZHANG Xiao-Lei ^1,2 ,
ZHANG Yang ^1,2

1.
School of Materials and Metallurgy, Northeastern University, Shenyang 110004, China
2.
School of Resources and Materials, Qinhuangdao branch, Northeastern University, Qinhuangdao, Hebei 066004, China

Corresponding author: GUO Rui, guorui791129@126.com
Received Date: 17 June 2015
Revised Date: 21 October 2015

Figures(8)

Er³⁺ doped and Er³⁺/Yb³⁺ co-doped La₂TiO₅ phosphors were synthesized by using sol-gel reactions. Good crystallinity was achieved after annealing the samples at 1 100 ℃ for 3 h in air. X-ray powder diffraction results revealed the formation of desired La₂TiO₅ host with pyrochlore structure. The UV excitation spectra of the samples consist of two regions in which the broad band at 250~320 nm originates from the charge-transition(CT) band between Er³⁺ ion and the nearest neighboring O2- ions and the sharp lines at 350~500 nm correspond to the f-f transition of Er³⁺ ion. Er³⁺ ion in La₂TiO₅ emits intense characteristic green light (546 nm, ⁴S_3/2-⁴I_15/2) under the excitation at 378 nm and the emission intensity reaches the maximum at Er³⁺ concentration of 1% (molar fraction). In the NIR-excited (980 nm) up-converted spectra, Yb³⁺ ion as an efficient sensitizer enhanced the emission intensities of Er³⁺ ion in comparison with those in La₂TiO₅:Er³⁺ phosphors. The luminescence decay curve and quantum yield were also measured and discussed in details.
- erbium,
- ytterbium,
- La₂TiO₅,
- up/down-conversion,
- luminescence
1. [1]
  Lin H, Yan X H, Wang X F. Mater. Sci. Eng. B, 2011,176: 1537-1540 doi: 10.1016/j.mseb.2011.09.020
2. [2]
  ZHANG Qing-Bin, CHENG Cheng. Chinese J. Inorg. Chem., 2015,31:81-86
3. [3]
  Liu X W, Guo R, Liu H, et al. RSC Adv., 2015,5:15059-15068 doi: 10.1039/C4RA13533D
4. [4]
  Fan B, Chlique C, Conanec O M, et al. J. Phys. Chem. C, 2012,116:11652-11657 doi: 10.1021/jp3016744
5. [5]
  Lin H, Chen D Q, Yu Y L, et al. Opt. Lett., 2011,36:876-878 doi: 10.1364/OL.36.000876
6. [6]
  Lin H, Yan X H, Wang X F. Mater. Sci. Eng. B, 2011,176: 1537-1540 doi: 10.1016/j.mseb.2011.09.020
7. [7]
  Yang Y M, Liu L L, Cai S Z, et al. J. Lumin., 2014,146:284-287 doi: 10.1016/j.jlumin.2013.09.069
8. [8]
  Xiao S, Yang X, Ding J W. Appl. Phys. B, 2010,99:769-773 doi: 10.1007/s00340-010-3960-7
9. [9]
  Li J J, Sun J S, Liu J T, et al. Mater. Res. Bull., 2013,48: 2159-2165 doi: 10.1016/j.materresbull.2013.02.009
10. [10]
  Schietinger S, Aichele T, Wang H Q, et al. Nano Lett., 2010,10:134-138 doi: 10.1021/nl903046r
11. [11]
  SHAO Li-Ming , JING Xi-Ping . Chinese J. Inorg. Chem., 2014,30:2295-2300
12. [12]
  Sunil S K, Kaushal K, Rai S B. Sens. Actuators A, 2009, 149:16-20 doi: 10.1016/j.sna.2008.09.019
13. [13]
  FAN Le-Qing, LI Zhao-Lei, HUANG Yun-Fang, et al. Chinese J. Inorg. Chem., 2015,31:147-152
14. [14]
  Wang G F, Qin W P, Wang L L, et al. J. Rare Earths, 2009, 27:394-397 doi: 10.1016/S1002-0721(08)60258-6
15. [15]
  Chen Z S, Gong W P, Chen T F, et al. Mater. Lett., 2012, 68:137-139 doi: 10.1016/j.matlet.2011.10.001
16. [16]
  Wang X J, Lei M K, Yang T, et al. Opt. Mater., 2004,26: 253-259 doi: 10.1016/j.optmat.2004.01.011
17. [17]
  Tian Y, Hua R, Yu J, et al. Mater. Chem. Phys., 2012,133: 617-620 doi: 10.1016/j.matchemphys.2012.01.025
18. [18]
  Wang R, Zhou D, Yang Z, et al. J. Non-Cryst. Solids, 2011, 357:2413-2416 doi: 10.1016/j.jnoncrysol.2010.12.026
19. [19]
  Dhlamini M S, Mhlongo G H, Swart H C, et al. J. Lumin., 2011,131:790-794 doi: 10.1016/j.jlumin.2010.12.005
20. [20]
  Zhang S, Liang H B, Liu C M. J. Phys. Chem. C, 2013,117: 2216-2221 doi: 10.1021/jp3120258
21. [21]
  Deng K, Wei X, Wang X, et al. Appl. Phys. B, 2011,102: 555-558 doi: 10.1007/s00340-011-4413-7
22. [22]
  Xia Z G, Luo Y, Guan M, et al. Opt. Express, 2012,20: A722-728 doi: 10.1364/OE.20.00A722
23. [23]
  Vetrone F, Boyer J C, Capobianco J A, et al. J. Phys. Chem. B, 2002,106:5622-5628 doi: 10.1021/jp020256m
24. [24]
  Gao F, Wu G, Zhou H, et al. J. Appl. Phys., 2009,106: 126104-126111 doi: 10.1063/1.3273477
25. [25]
  Chen X Q, Li Y L, Kong F, et al. J. Alloys Compd., 2012, 541:505-509 doi: 10.1016/j.jallcom.2012.07.008
26. [26]
  Auzel F, Chen Y. J. Lumin., 1995,65:45-56 doi: 10.1016/0022-2313(94)00071-J
27. [27]
  Ajroud M, Haouari M, Ben O H, et al. Phys. Status Solidi A, 2005,202:316-329 doi: 10.1002/pssa.v202:2
28. [28]
  Lakshminarayana G, Qiu J, Brik M G, et al. J. Phys.: Condens. Mater., 2008,20:375101-375108 doi: 10.1088/0953-8984/20/37/375101
29. [29]
  Xu C F, Yang L W, Han H L, et al. Opt. Mater., 2010,32: 1188-1192 doi: 10.1016/j.optmat.2010.03.029
30. [30]
  Blasse G. Philips Res. Rep., 1969,24:131-144
31. [31]
  Victory D C, Rajmuhon S N. Spectrochim. Acta Part A, 2015,146:331-341 doi: 10.1016/j.saa.2015.03.039
32. [32]
  Stouwdam J W, Van V F. Nano Lett., 2002,2:733-739 doi: 10.1021/nl025562q
1. [1]
  Ting WANG , Peipei ZHANG , Shuqin LIU , Ruihong WANG , Jianjun ZHANG . A Bi-CP-based solid-state thin-film sensor: Preparation and luminescence sensing for bioamine vapors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1615-1621. doi: 10.11862/CJIC.20240134
2. [2]
  Yanting Yang , Guorong Wang , Kangjing Li , Wen Yang , Jing Zhang , Jian Zhang , Shili Li , Xianming Zhang . Tuning up of chromism, luminescence in cadmium-viologen complexes through polymorphism strategy: Inkless erasable printing application. Chinese Chemical Letters, 2025, 36(1): 110123-. doi: 10.1016/j.cclet.2024.110123
3. [3]
  Pan Liu , Yanming Sun , Alberto J. Fernández-Carrión , Bowen Zhang , Hui Fu , Lunhua He , Xing Ming , Congling Yin , Xiaojun Kuang . Bismuth-based halide double perovskite Cs₂KBiCl₆: Disorder and luminescence. Chinese Chemical Letters, 2024, 35(5): 108641-. doi: 10.1016/j.cclet.2023.108641
4. [4]
  Yan Cheng , Hua-Peng Ruan , Yan Peng , Longhe Li , Zhenqiang Xie , Lang Liu , Shiyong Zhang , Hengyun Ye , Zhao-Bo Hu . Magnetic, dielectric and luminescence synergetic switchable effects in molecular material [Et₃NCH₂Cl]₂[MnBr₄]. Chinese Chemical Letters, 2024, 35(4): 108554-. doi: 10.1016/j.cclet.2023.108554
5. [5]
  Shihong Wu , Ronghui Zhou , Hang Zhao , Peng Wu . Sonoafterglow luminescence for in vivo deep-tissue imaging. Chinese Chemical Letters, 2024, 35(10): 110026-. doi: 10.1016/j.cclet.2024.110026
6. [6]
  Huijie An , Chen Yang , Zhihui Jiang , Junjie Yuan , Zhongming Qiu , Longhao Chen , Xin Chen , Mutu Huang , Linlang Huang , Hongju Lin , Biao Cheng , Hongjiang Liu , Zhiqiang Yu . Luminescence-activated Pt(Ⅳ) prodrug for in situ triggerable cancer therapy. Chinese Chemical Letters, 2024, 35(7): 109134-. doi: 10.1016/j.cclet.2023.109134
7. [7]
  Chaohui Zheng , Jing Xi , Shiyi Long , Tianpei He , Rui Zhao , Xinyuan Luo , Na Chen , Quan Yuan . Persistent luminescence encoding for rapid and accurate oral-derived bacteria identification. Chinese Chemical Letters, 2025, 36(1): 110223-. doi: 10.1016/j.cclet.2024.110223
8. [8]
  Yuanpeng Ye , Longfei Yao , Guofeng Liu . Engineering circularly polarized luminescence through symmetry manipulation in achiral tetraphenylpyrazine structures. Chinese Journal of Structural Chemistry, 2025, 44(2): 100460-100460. doi: 10.1016/j.cjsc.2024.100460
9. [9]
  Zhao-Xia Lian , Xue-Zhi Wang , Chuang-Wei Zhou , Jiayu Li , Ming-De Li , Xiao-Ping Zhou , Dan Li . Producing circularly polarized luminescence by radiative energy transfer from achiral metal-organic cage to chiral organic molecules. Chinese Chemical Letters, 2024, 35(8): 109063-. doi: 10.1016/j.cclet.2023.109063
10. [10]
  Yongjing Deng , Feiyang Li , Zijian Zhou , Mengzhu Wang , Yongkang Zhu , Jianwei Zhao , Shujuan Liu , Qiang Zhao . Chiral induction and Sb³⁺ doping in indium halides to trigger second harmonic generation and circularly polarized luminescence. Chinese Chemical Letters, 2024, 35(8): 109085-. doi: 10.1016/j.cclet.2023.109085
11. [11]
  Junying Zhang , Ruochen Li , Haihua Wang , Wenbing Kang , Xing-Dong Xu . Photo-induced tunable luminescence from an aggregated amphiphilic ethylene-pyrene derivative in aqueous media. Chinese Chemical Letters, 2024, 35(6): 109216-. doi: 10.1016/j.cclet.2023.109216
12. [12]
  Hui-Juan Wang , Wen-Wen Xing , Zhen-Hai Yu , Yong-Xue Li , Heng-Yi Zhang , Qilin Yu , Hongjie Zhu , Yao-Yao Wang , Yu Liu . Cucurbit[7]uril confined phenothiazine bridged bis(bromophenyl pyridine) activated NIR luminescence for lysosome imaging. Chinese Chemical Letters, 2024, 35(6): 109183-. doi: 10.1016/j.cclet.2023.109183
13. [13]
  Sifan Du , Yuan Wang , Fulin Wang , Tianyu Wang , Li Zhang , Minghua Liu . Evolution of hollow nanosphere to microtube in the self-assembly of chiral dansyl derivatives and inversed circularly polarized luminescence. Chinese Chemical Letters, 2024, 35(7): 109256-. doi: 10.1016/j.cclet.2023.109256
14. [14]
  Jun-Ting Mo , Zheng Wang . Achieving tunable long persistent luminescence in metal organic halides based on pyridine solvent. Chinese Chemical Letters, 2024, 35(9): 109360-. doi: 10.1016/j.cclet.2023.109360
15. [15]
  Xue-Zhi Wang , Yi-Tong Liu , Chuang-Wei Zhou , Bei Wang , Dong Luo , Mo Xie , Meng-Ying Sun , Yong-Liang Huang , Jie Luo , Yan Wu , Shuixing Zhang , Xiao-Ping Zhou , Dan Li . Amplified circularly polarized luminescence of chiral metal-organic frameworks via post-synthetic installing pillars. Chinese Chemical Letters, 2024, 35(10): 109380-. doi: 10.1016/j.cclet.2023.109380
16. [16]
  Hao Jiang , Yuan-Yuan He , Hai-Chao Liang , Meng-Jia Shang , Han-Han Lu , Chun-Hua Liu , Yin-Shan Meng , Tao Liu , Yuan-Yuan Zhu . Tuning lanthanide luminescence from bipyridine-bis(oxazoline/thiazoline) tetradentate ligands. Chinese Journal of Structural Chemistry, 2024, 43(9): 100354-100354. doi: 10.1016/j.cjsc.2024.100354
17. [17]
  Yang Li , Yihan Chen , Jiaxin Luo , Qihuan Li , Yiwu Quan , Yixiang Cheng . Enhanced circularly polarized luminescence emission promoted by achiral dichroic oligomers of F8BT in cholesteric liquid crystal. Chinese Chemical Letters, 2024, 35(11): 109864-. doi: 10.1016/j.cclet.2024.109864
18. [18]
  Xiang Wang , Qingping Song , Zixiang He , Gong Zhang , Tengfei Miao , Xiaoxiao Cheng , Wei Zhang . Constructing diverse switchable circularly polarized luminescence via a single azobenzene polymer film. Chinese Chemical Letters, 2025, 36(1): 110047-. doi: 10.1016/j.cclet.2024.110047
19. [19]
  Husitu Lin , Shuangkun Zhang , Dianfa Zhao , Yongkang Wang , Wei Liu , Fan Yang , Jianjun Liu , Dongpeng Yan , Zhanpeng Wu . Flexible polyphosphazene nanocomposite films: Enhancing stability and luminescence of CsPbBr₃ perovskite nanocrystals. Chinese Chemical Letters, 2025, 36(4): 109795-. doi: 10.1016/j.cclet.2024.109795
20. [20]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(381)
HTML views(53)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis and up/down Conversion Luminescence Properties of Er3+/Yb3+ Co-doped La2TiO5 Phosphor

Metrics

通讯作者: 陈斌, bchen63@163.com

Synthesis and up/down Conversion Luminescence Properties of Er³⁺/Yb³⁺ Co-doped La₂TiO₅ Phosphor