Citation: SUN Hai-Jie, CHEN Jian-Jun, HUANG Zhen-Xu, LIU Zhong-Yi, LIU Shou-Chang. Selective Hydrogenation of Benzene to Cyclohexene over the Nano-Sized Ru-Zn Catalyst Modified by Arabic Gum[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(2): 202-210. doi: 10.11862/CJIC.2016.019 shu

Selective Hydrogenation of Benzene to Cyclohexene over the Nano-Sized Ru-Zn Catalyst Modified by Arabic Gum

1.
Institute of Environmental and Catalytic Engineering, Department of Chemistry, Zhengzhou Normal University, Zhengzhou 450044, China
2.
College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, China

Corresponding author: SUN Hai-Jie, sunghaijie406@163.com LIU Zhong-Yi, liuzhongyi@zzu.edu.cn
Received Date: 8 August 2015
Revised Date: 10 November 2015

Figures(12)

A nano-sized Ru-Zn catalyst was prepared by a co-precipitation method and the effect of arabic gum modification on the performance of Ru-Zn catalysts was investigated. The catalysts were characterized by X-ray diffraction (XRD), transimission electron microscopy (TEM), N₂ physisorption, X-ray photoelectron spectroscopy (XPS), and X-ray fluorescence (XRF). It was found that the dosage of arabic gum could tune the particle size of the Ru-Zn catalysts. The maximum cyclohexene yield showed a volcanic-type variation tendency with the particle size of Ru-Zn catalysts increasing. When the mass ratio of arabic gum to RuCl₃·xH₂O was 0.033, a Ru-Zn catalyst with a optimum particle size of 4.0 nm was obtained, and a maximum cyclohexene yield of 59.6% was achieved. Moreover, the catalyst exhibited the excellent reusability.
- benzene,
- selective hydrogenation,
- cyclohexene,
- arabic gum,
- Ru,
- Zn
1. [1]
  Liao H G, Ouyang D H, Zhang J, et al. Chem. Eng. J., 2014, 243:207-216 doi: 10.1016/j.cej.2014.01.014
2. [2]
  WANG Zheng-Bao, ZHANG Qi, LU Xiao-Fei, et al. Chinese J. Catal., 2015, 36 (3): 400-407
3. [3]
  SUN Hai-Jie, ZHOU Xiao-Li, ZHAO Ai-Juan, et al. Chinese J. Inorg. Chem., 2015, 31 (7):1287-1295
4. [4]
  Zhang P, Wu T B, Jiang T, et al. Green Chem., 2013, 15: 152-159 doi: 10.1039/C2GC36596K
5. [5]
  ZHANG Ye, FU Hai-Yan, LI Rui-Xiang, et al. Chinese J. Inorg. Chem., 2013, 29 (3):577-582
6. [6]
  WEI Jun-Fang, WANG Yan-Ji, LI Juan, et al. Chinese J. Inorg. Chem., 2011, 27 (5):850-854
7. [7]
  Ning J B, Xu J, Liu J, et al. Catal. Lett., 2006, 109:175-180 doi: 10.1007/s10562-006-0075-1
8. [8]
  SUN Hai-Jie, LI Shuai-Hui, TIAN Xiang-Yu, et al. J. Mol. Catal. (China), 2013, 27 (4):362-370
9. [9]
  SUN Hai-Jie, JIANG Hou-bin, LI Shuai-Hui, et al. Chinese J. Catal., 2013, 34 (4): 684-694
10. [10]
  SUN Hai-Jie, LI Shuai-Hui, ZHANG Yuan-Xin, et al. Chinese J. Catal., 2013, 34 (8):1482-1488
11. [11]
  Struijk J, Scholten J J F. Appl. Catal. A: Gen., 1992, 82:277-287 doi: 10.1016/0926-860X(92)85010-9
12. [12]
  Spinacé E V, Vaz J M. Catal. Commun., 2003, 4:91-96 doi: 10.1016/S1566-7367(02)00270-4
13. [13]
  Fan G Y, Li R X, Li X J, et al. Catal. Commun., 2008, 9: 1394-1397 doi: 10.1016/j.catcom.2007.11.039
14. [14]
  SUN Hai-Jie, PAN Ya-Jie, WANG Hong-Xia, et al. Chinese J. Catal., 2012, 33 (4): 610-620
15. [15]
  Sun H J, Jiang H B, Li S H, et al. Chem. Eng. J., 2013, 218: 415-424 doi: 10.1016/j.cej.2012.12.041
16. [16]
  HUANG Xin, ZHANG Hui, LIANG Li-Yun. Prog. Chem., 2010, 22 (5):953-961
17. [17]
  LIU Zhong-Yi, SUN Hai-Jie, WANG Dong-Bin, et al. Chinese J. Catal., 2010, 31 (2):150-152
18. [18]
  Sun H J, Wang H X, Jiang H B, et al. Appl. Catal. A: Gen., 2013, 450:160-168 doi: 10.1016/j.apcata.2012.10.016
19. [19]
  SUN Hai-Jie, ZHANG Xu-Dong, CHEN Zhi-Hao, et al. Chinese J. Catal., 2011, 32 (2):224-230
20. [20]
  SUN Hai-Jie, LI Yong-Yu, LI Shuai-hui, et al. Acta Phys.-Chim. Sin., 2014, 30 (7):1332-1340 doi: 10.3866/PKU.WHXB201405072
21. [21]
  CHEN Xi, LI Li, ZHANG Wen-Zhi, et al.. Chinese J. Inorg. Chem., 2015, 31 (10): 1971-1980
22. [22]
  Liu J L, Zhu Y, Liu J, et al. J. Catal., 2009, 268:100-105 doi: 10.1016/j.jcat.2009.09.007
23. [23]
  Bu J, Liu J L, Chen X Y, et al. Catal. Commun., 2008, 9: 2612-2615 doi: 10.1016/j.catcom.2008.07.024
24. [24]
  Prasad K H V, Prasad K B S, Mallikarjunan M M, et al. J. Catal., 32:1-16
25. [25]
  Liu J L, Zhu L J, Pei Y, et al. Appl. Catal. A: Gen., 2009, 353:383-287
26. [26]
  Sun H J, Pan Y J, Jiang H B, et al. Appl. Catal. A: Gen., 2013, 464-465:1-9 doi: 10.1016/j.apcata.2013.05.021
27. [27]
  Sun H J, Pan Y J, Li S H, et al. J. Energy Chem., 2013, 22: 710-716 doi: 10.1016/S2095-4956(13)60094-7
28. [28]
  Su H J, Chen L X, Li S H, et al. J. Rare Earths, 2013, 31: 1023-1028 doi: 10.1016/S1002-0721(13)60024-1
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沈阳化工大学材料科学与工程学院沈阳 110142