Citation: YANG Fang, DONG Bao-Xia, TANG Meng, LIU Wen-Long. Syntheses, Crystal Structures and Photoluminescence of Two Metal Coordination Polymers Constructed from 2-Mercaptobenzoic Acid and Its in situ Oxidized Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(1): 1-8. doi: 10.11862/CJIC.2016.017 shu

Syntheses, Crystal Structures and Photoluminescence of Two Metal Coordination Polymers Constructed from 2-Mercaptobenzoic Acid and Its in situ Oxidized Ligand

College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu 225002, China

Corresponding author: LIU Wen-Long, liuwl@yzu.edu.cn
Received Date: 27 September 2015
Revised Date: 13 November 2015

Figures(5)

Two novel coordination polymers, [Cd(2-mba)(bimb)]_n(1) and [Pb(2-sb)]_n(2) [H₂(2-mba)=2-mercaptobenzoic acid, bimb=4,4-bis(1-imidazolyl)bibenzene, sb^2-=2-sulfinobenzoate] have been solvothermal synthesized and characterized by elemental analysis, IR, powder X-ray diffraction and single crystal X-ray diffraction. Complex 1 features a two-dimensional (2D) net structure in which 1D [Cd(2-mba)]_n chains are interconnected by bimb ligands. In complex 1, the ligand 2-mercaptobenzoic acid was oxidized into 2-sulfinobenzoate under solvothermal conditions via in situ ligand reactions. Complex 2 exhibits a 2D(4, 4)-connected framework bridged with carboxylate and sulfinate groups of 2-sulfinobenzoate ligands. The thermal stabilities and solid state photoluminescent properties of two compounds were also investigated. CCDC: 1056796, 1; 1056797, 2.
- cadmium(Ⅱ),
- lead(Ⅱ),
- coordination polymer,
- solvothermal synthesis in situ,
- crystal structure,
- luminescence
1. [1]
  Furukawa H, Cordova K E, O′Keeffe M, et al. Science, 2013,341:1230444-1-1230444-12 doi: 10.1126/science.1230444
2. [2]
  Cui Y, Yue Y, Qian G, et al. Chem. Rev., 2012,112:1126- 1162 doi: 10.1021/cr200101d
3. [3]
  Dang D B, An B, Bai Y, et al. Chem. Commun., 2013,49: 243-2245 doi: 10.1039/C2CC36316J
4. [4]
  Liu L J, Telfer S G. J. Am. Chem. Soc., 2015,37:3901-3909
5. [5]
  Sun H L, Wang Z M, Gao S. Coord. Chem. Rev., 2010,54: 1081-1100
6. [6]
  Adarsh N N, Kumar D K, Dastidar P. CrystEngComm, 2009, 11:796-802 doi: 10.1039/b816221b
7. [7]
  Zheng S T, Wu T, Chou C T, et al. J. Am. Chem. Soc., 2012,134:4517-4520 doi: 10.1021/ja2118255
8. [8]
  Khan N A, Jhung S H. Angew. Chem. Int. Ed., 2012,51: 1224-1227
9. [9]
  Ren Y X, Zheng X J, Jin L P. CrystEngComm, 2011,13: 5915-5923 doi: 10.1039/c1ce05303e
10. [10]
  Wang J, Wang J G, Li X H, et al. Transition Met. Chem., 2013,38:765-770 doi: 10.1007/s11243-013-9747-z
11. [11]
  Sun L, Miyakai T, Seki S, et al. J. Am. Chem. Soc., 2013, 135:8185-8188 doi: 10.1021/ja4037516
12. [12]
  Casarin M, Devic T, Famengo A, et al. Inorg. Chem., 2010, 49:4099-4108 doi: 10.1021/ic902076r
13. [13]
  Humphrey S M, Mole R A, McPartlin M, et al. Inorg. Chem., 2005,44:5981-5983 doi: 10.1021/ic050768q
14. [14]
  Chen H W, Fackler J P, Schussler D P, et al. J. Am. Chem. Soc., 1978,100:2370- 2375 doi: 10.1021/ja00476a018
15. [15]
  Humphrey S M, Mole R A, Rawson J M, et al. Dalton Trans., 2004:1670-1678
16. [16]
  Duran N, Clegg W, Cucurull-Sanchez L, et al. Inorg. Chem., 2000,39:4821-4832 doi: 10.1021/ic000223q
17. [17]
  Ma C L, Zhang Q F, Zhang R F, et al. Chem. -Eur. J., 2006, 12:420-428 doi: 10.1002/(ISSN)1521-3765
18. [18]
  Nomiya K, Noguchi R, Kato C. Chem. Lett., 2000:162-163
19. [19]
  Cave D, Gascon J-M, Bond A D, et al. Chem.Commun., 2002:1050 -1051
20. [20]
  Sun D, Liu F J, Huang R B, et al. Inorg. Chem., 2011,50: 12393-12395 doi: 10.1021/ic201746q
21. [21]
  Sun D, Wang D F, Liu F J, et al. CrystEngComm, 2011,13: 2833-2836 doi: 10.1039/c1ce05023k
22. [22]
  Sun D, Luo G G, Zhang N, et al. Inorg. Chem. Commun., 2010,13:306-309 doi: 10.1016/j.inoche.2009.12.011
23. [23]
  Sun D, Yan Z H. Acta Crystallogr. Sect. C, 2012,C68:m229- m232
24. [24]
  Ge S Z, Liu Q, Deng S, et al. J. Inorg. Organomet. Polym., 2013,23:571-578 doi: 10.1007/s10904-012-9814-5
25. [25]
  Wang H, Huo L H, Deng Z P, et al. CrystEngComm, 2012,14:3501-3508 doi: 10.1039/c2ce06584c
26. [26]
  Zheng S L, Tong M L, Yu X L, et al. Dalton Trans., 2001: 586-592
27. [27]
  Begum R A, Farah A A, Hunter H N, et al. Inorg. Chem., 2009,48:2018-2027 doi: 10.1021/ic801898t
28. [28]
  Li F Y, Xu L, Gao G G, et al. Dalton Trans., 2007:1661- 1664
29. [29]
  Fan J, Hanson B E. Chem. Commun., 2005:2327-2329
30. [30]
  Jackson W G, Rahman A F M M. Inorg. Chem., 2003,42: 383-388 doi: 10.1021/ic020207o
31. [31]
  Yue C Y, Lin Z Z, Chen L F, et al. J. Mol. Struct., 2005, 779:6-22
32. [32]
  SADABS, SMART and SAINT, Bruker AXS Inc., Madison, Wisconsin, USA, 2003.
33. [33]
  APEX2, Bruker AXS Inc., Madison, Wisconsin, USA, 2005.
34. [34]
  Sheldrick G M. Acta Crystallogr., 2008,A64:112-122
35. [35]
  Marandi F, Mirtamizdoust B, Soudi A A, et al. Inorg. Chem. Commun., 2007,10:174-177 doi: 10.1016/j.inoche.2006.10.017
36. [36]
  Mao J G, Wang Z, Clearfield A. Inorg. Chem., 2002,41: 6106-6111 doi: 10.1021/ic020396a
37. [37]
  Nakamoto K. Infrared and Raman Spectra of Inorganic and Coordination Compounds. 5th Ed. Part B. New York: John Willey & Sons, 1997.
38. [38]
  Higashi L S, Lundeen M, Hilti E, et al. Inorg. Chem., 1977,16:310-313 doi: 10.1021/ic50168a017
39. [39]
  Liu W L, Ye L H, Liu X F, et al. CrystEngComm, 2008,10: 395-1403
40. [40]
  Zhang L, Qin Y Y, Li Z J, et al. Inorg. Chem., 2008,47: 8286-8293 doi: 10.1021/ic800871r
41. [41]
  Blasse G, Grabmaier B C. Luminescent Materials. Berlin: Springer Verlag, 1994:134-135
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