Citation: WANG Hui-Sheng, YUE Lin, PAN Min, ZHONG Wen-Da, TU Wei, PAN Zhi-Quan. Synthesis, Crystal Structure and Magnetic Properties of a Heptanuclear Mn Complex with 2-(Hydroxymethyl) pyridine and 1, 1, 1-Tris (hydroxymethyl) ethane Mixed-Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(1): 153-160. doi: 10.11862/CJIC.2016.012 shu

Synthesis, Crystal Structure and Magnetic Properties of a Heptanuclear Mn Complex with 2-(Hydroxymethyl) pyridine and 1, 1, 1-Tris (hydroxymethyl) ethane Mixed-Ligands

School of Chemistry and Environmental Engineering, Wuhan Institute of Technology, Key Laboratory for Green Chemical Process of Ministry of Education, Wuhan 430074, China

Corresponding author: PAN Zhi-Quan, wangch198201@163.com
Received Date: 2 September 2015
Revised Date: 4 November 2015

Figures(8)

One heptanuclear Mn cluster [Mn₃^ⅡMn₄^Ⅲ(Cl)₆(hmp)₆(thme)₂]·H₂O·3CH₃CN (1·H₂O·3CH₃CN, hmpH=2-(hydroxymethyl) pyridine and thmeH₃=1, 1, 1-tris (hydroxymethyl) ethane) has been synthesized by the reaction of MnCl₂·4H₂O, hmpH and thmeH₃ in MeCN. The complex was characterized by single crystal X-ray diffraction, elemental analyses, IR and magnetic investigation. Complex 1·H₂O·3CH₃CN crystallizes in the monoclinic space group I2/a and its core can be viewed as a Mn₆ hexagon of alternating Mn^Ⅱ and Mn^Ⅲ ions surrounding a central Mn^Ⅲ ion, which has previously not been seen for this topology. Magnetic studies reveal that overall ferromagnetic coupling between Mn^Ⅲ and Mn^Ⅱ or Mn^Ⅲ ions within 1·H₂O are present and weak frequency dependence of the ac-susceptibility was found. CCDC: 1045766.
- heptanuclear Mn complex,
- mixed-chelating ligand,
- multidentate chelating ligand,
- crystal structure,
- magnetic property
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