Citation: XU Na, CHEN Zhe, SUO Zhong-Yuan, TAN Nai-Di. Effect of Intrinsic Defects on Electrical and Optical Properties of CdS Thin Films Deposited by Chemical Bath Deposition[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(1): 111-116. doi: 10.11862/CJIC.2016.005 shu

Effect of Intrinsic Defects on Electrical and Optical Properties of CdS Thin Films Deposited by Chemical Bath Deposition

XU Na ¹ ,
CHEN Zhe ¹ ,
SUO Zhong-Yuan ² ,
TAN Nai-Di ^3,*,,

1.
College of Materials Science and Engineering, Institute of Chemical and Technology, Jilin, Jilin 132022, China
2.
College of Mechanical and Electrical Engineering, Institute of Chemical and Technology, Jilin, Jilin 132022, China
3.
College of Chemical and Pharmaceutical Engineering, Institute of Chemical and Technology, Jilin, Jilin 132022, China

Corresponding author: TAN Nai-Di, tannaidi@hotmail.com
Received Date: 27 August 2015
Revised Date: 19 October 2015

Figures(6)

CdS thin films were deposited on soda-lime glass (SLG) substrates by chemical bath deposition (CBD). Effects of intrinsic defects on electrical and optical properties of CdS thin films deposited at various concentration of CdSO₄ in solution were systemically investigated. Photoluminescence (PL), UV-Visible spectrophotometer and Hall-effect system were used to study intrinsic defects, optical and electrical properties of CdS thin films. Two intrinsic defects (Cd_i and V_S) were found to be existed in CdS films using photoluminescence (PL), and these defects are donor defects. It is found that the intrinsic defects (V_S) decrease with the reduction of CdSO₄ concentration. The variation of the intrinsic defects results in the shifts of transmittance and conductivity. According to the related equations of transmittance, it is indicated that the transmittance is inversely proportional to conductivity of semiconductor materials. Therefore, the decrease of donor defects (V_S) results in the reduction of conductivity and significant increase of the transmittance of CdS thin films, well supporting our experimental results.
- intrinsic defects,
- CdS thin film,
- chemical bath deposition,
- optical property,
- electrical property
1. [1]
  Singh O P, Muhunthan N, Singh V N, et al. Mater. Chem. Phys., 2014, 146:452-455
2. [2]
  Suryawanshi M P, Agawane G L, Bhosale S M, et al. Mater. Technol., 2013, 28:98-109
3. [3]
  Shirakata S, Ohkubo K, Ishii Y, et al. Sol. Energy Mater. Sol. Cells, 2009, 93:988-992
4. [4]
  Ghosh B, Ghosh D, Hussain S, et al. Mater. Sci. Semicond. Process., 2014, 24:74-82
5. [5]
  Sho S, Hiroyuki O, Kouichi I, et al. Jpn. J. Appl. Phys., 2014, 53:05FW11
6. [6]
  Akiko A, Masakazu Y, Sho S. Jpn. J. Appl. Phys., 2014, 53: 05FW12
7. [7]
  de Melo O, Hernández L, Zelaya-Angel O, et al. Appl. Phys. Lett., 1994, 65:1278-1280
8. [8]
  Boyle D S, Bayer A, Heinrich M R, et al. Thin Solid Films, 2000, 361-362:150-154 doi: 10.1016/S0040-6090(99)00789-0
9. [9]
  Cao M, Sun Y, Wu J, et al. J. Alloys Compd., 2010, 508:297-300
10. [10]
  Tsai C T, Chuu D S, Chen G L, et al. J. Appl. Phys., 1996, 79:9105-9109
11. [11]
  Cortes A, Gómez H, Marotti R E, et al. Sol. Energy Mater. Sol. Cells, 2004, 82:21-34
12. [12]
  Abken A E, Halliday D P, Durose K. J. Appl. Phys., 2009, 105:064515
13. [13]
  Seo W O, Jung Y, Kim J, et al. Appl. Phys. Lett., 2014, 104: 133902
14. [14]
  Subba Ramaiah K, Pilkington R D, Hill A E, et al. Mater. Chem. Phys., 2001, 68:22-30
15. [15]
  Ortega-Borges R, Lincot D. J. Electrochem. Soc., 1993, 140: 3464-3473
16. [16]
  Kim M, Min B K, Kim C D, et al. Curr. Appl. Phys., 2010, 10:S455-S458
17. [17]
  Muthusamy M, Muthukumaran S, Ashokkumar M. Ceram. Int., 2014, 40:10657-10666
18. [18]
  Ariza-Calderon H, Lozada-Morales R, Zelaya-Angel O, et al. J. Vac. Sci. Technol. A, 1996, 14:2480-2482
19. [19]
  Vigil O, Riech I, Garcia-Rocha M, et al. J. Vac. Sci. Technol. A, 1997, 15:2282-2286
20. [20]
  Aguilar-Hernández J, Contreras-Puente G, Morales-Acevedo A, et al. Semicond. Sci. Tech., 2003, 18:111-115
21. [21]
  Agata M, Kurase H, Hayashi S, et al. Solid State Commun., 1990, 76:1061-1065
22. [22]
  Mejía-García C, Escamilla-Esquivel A, Contreras-Puente G, et al. J. Appl. Phys., 1999, 86:3171-3174
23. [23]
  LIU En-Ke, ZHU Bing-Sheng, LUO Jin-Sheng. Semiconductor Physics. Beijing: Electronic Industry Press, 2012.
1. [1]
  Dongheng WANG , Si LI , Shuangquan ZANG . Construction of chiral alkynyl silver chains and modulation of chiral optical properties. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 131-140. doi: 10.11862/CJIC.20240379
2. [2]
  Laiying Zhang , Yinghuan Wu , Yazi Yu , Yecheng Xu , Haojie Zhang , Weitai Wu . Innovation and Practice of Polymer Chemistry Experiment Teaching for Non-Polymer Major Students of Chemistry: Taking the Synthesis, Solution Property, Optical Performance and Application of Thermo-Sensitive Polymers as an Example. University Chemistry, 2024, 39(4): 213-220. doi: 10.3866/PKU.DXHX202310126
3. [3]
  Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
4. [4]
  Zhiwen HUANG , Qi LIU , Jianping LANG . W/Cu/S cluster-based supramolecular macrocycles and their third-order nonlinear optical responses. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 79-87. doi: 10.11862/CJIC.20240184
5. [5]
  Shenhao QIU , Qingquan XIAO , Huazhu TANG , Quan XIE . First-principles study on electronic structure, optical and magnetic properties of rare earth elements X (X=Sc, Y, La, Ce, Eu) doped with two-dimensional GaSe. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2250-2258. doi: 10.11862/CJIC.20240104
6. [6]
  Xuan Zhou , Yi Fan , Zhuoqi Jiang , Zhipeng Li , Guowen Yuan , Laiying Zhang , Xu Hou . Liquid Gating Mechanism and Basic Properties Characterization: a New Experimental Design for Interface and Surface Properties in the Chemistry “101 Plan”. University Chemistry, 2024, 39(10): 113-120. doi: 10.12461/PKU.DXHX202407111
7. [7]
  Jingwen Wang , Minghao Wu , Xing Zuo , Yaofeng Yuan , Yahao Wang , Xiaoshun Zhou , Jianfeng Yan . Advances in the Application of Electrochemical Regulation in Investigating the Electron Transport Properties of Single-Molecule Junctions. University Chemistry, 2025, 40(3): 291-301. doi: 10.12461/PKU.DXHX202406023
8. [8]
  Zitong Chen , Zipei Su , Jiangfeng Qian . Aromatic Alkali Metal Reagents: Structures, Properties and Applications. University Chemistry, 2024, 39(8): 149-162. doi: 10.3866/PKU.DXHX202311054
9. [9]
  Yihao Zhao , Jitian Rao , Jie Han . Synthesis and Photochromic Properties of 3,3-Diphenyl-3H-Naphthopyran: Design and Teaching Practice of a Comprehensive Organic Experiment. University Chemistry, 2024, 39(10): 149-155. doi: 10.3866/PKU.DXHX202402050
10. [10]
  Wei Li , Ze Chang , Meihui Yu , Ying Zhang . Curriculum Ideological and Political Design of Piezoelectricity Measurement Experiments of Coordination Compounds. University Chemistry, 2024, 39(2): 77-82. doi: 10.3866/PKU.DXHX202308004
11. [11]
  Feiya Cao , Qixin Wang , Pu Li , Zhirong Xing , Ziyu Song , Heng Zhang , Zhibin Zhou , Wenfang Feng . Magnesium-Ion Conducting Electrolyte Based on Grignard Reaction: Synthesis and Properties. University Chemistry, 2024, 39(3): 359-368. doi: 10.3866/PKU.DXHX202308094
12. [12]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
13. [13]
  Qingyang Cui , Feng Yu , Zirun Wang , Bangkun Jin , Wanqun Hu , Wan Li . From Jelly to Soft Matter: Preparation and Properties-Exploring of Different Kinds of Hydrogels. University Chemistry, 2024, 39(9): 338-348. doi: 10.3866/PKU.DXHX202309046
14. [14]
  Chen LU , Qinlong HONG , Haixia ZHANG , Jian ZHANG . Syntheses, structures, and properties of copper-iodine cluster-based boron imidazolate framework materials. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 149-154. doi: 10.11862/CJIC.20240407
15. [15]
  Xianggui Kong , Wenying Shi . Comprehensive Chemical Experimental Design of Optically Encrypted Materials. University Chemistry, 2025, 40(3): 355-362. doi: 10.12461/PKU.DXHX202406067
16. [16]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
17. [17]
  Wenjie SHI , Fan LU , Mengwei CHEN , Jin WANG , Yingfeng HAN . Synthesis and host-guest properties of imidazolium-functionalized zirconium metal-organic cage. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 105-113. doi: 10.11862/CJIC.20240360
18. [18]
  Yulian Hu , Xin Zhou , Xiaojun Han . A Virtual Simulation Experiment on the Design and Property Analysis of CO₂ Reduction Photocatalyst. University Chemistry, 2025, 40(3): 30-35. doi: 10.12461/PKU.DXHX202403088
19. [19]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
20. [20]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(770)
HTML views(203)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142