Citation: WANG Gui-Xian, CAO Ke-Li, XIA Yan, FENG Yun-Long. Syntheses and Crystal Structures of Mn(Ⅱ) and Ca(Ⅱ) Coordination Polymers Based on 5-(4-(2,6-Di(pyrazin-2-yl)pyridin-4-yl)phenoxy)isophthalic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2015, (12): 2337-2342. doi: 10.11862/CJIC.2015.311 shu

Syntheses and Crystal Structures of Mn(Ⅱ) and Ca(Ⅱ) Coordination Polymers Based on 5-(4-(2,6-Di(pyrazin-2-yl)pyridin-4-yl)phenoxy)isophthalic Acid

WANG Gui-Xian ^1,2 ,
CAO Ke-Li ² ,
XIA Yan ² ,
FENG Yun-Long ^2,,

1.
1 Department of chemistry and chemical engineering, Lishui University, Lishui, Zhejiang 323000, China;
2.
2 Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, College of Chemistry and Life Science, Zhejiang Normal University, Jinhua, Zhejiang 321004, China

Corresponding author: FENG Yun-Long,
Received Date: 22 April 2015
Available Online: 11 October 2015
Fund Project: 国家自然科学基金(No.21173197)资助项目。 (No.21173197)

Two new metal-organic coordination polymers {[MnL]·0.5H₂O}_n (1),{[CaL(H₂O)₂]·H₂O}_n (2) (H₂L=5-(4-(2,6-di(pyrazin-2-yl)pyridin-4-yl)phenoxy)isophthalic acid) have been synthesized under solvothermal reaction and characterized by single crystal X-ray diffraction analysis. 1 features a novel 3D supramolecular network built by different monochiral sheets with (3,3)-connected 2D net. 2 displays a 1D inorganic-chain linked by carboxylate oxygen atoms of L^2- with Ca(Ⅱ) ions. Thermogravimetric analyses (TGA) have been measured for 1 and 2. Luminescent properties of 2 were investigated.
- coordination polymer;5-(4-(2,6-di(pyrazin-2-yl)pyridin-4-yl)phenoxy)isophthalic acid;crystal structure;luminescent property
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