Citation: LI Xiao-Jing, WU Wei-Na, XU Zhou-Qing, LI Shou-Jie, ZHAO Liang. Two Cadmium(Ⅱ) Complexes of an Acylhydrazone Ligand Bearing Quinoline Unit: Syntheses, Structures and Fluorescent Properties[J]. Chinese Journal of Inorganic Chemistry, ;2015, (11): 2265-2271. doi: 10.11862/CJIC.2015.303 shu

Two Cadmium(Ⅱ) Complexes of an Acylhydrazone Ligand Bearing Quinoline Unit: Syntheses, Structures and Fluorescent Properties

1.
Department of Physics and Chemistry, Henan Polytechnic University, Jiaozuo, Henan 454000, China

Corresponding author: WU Wei-Na, XU Zhou-Qing,
Received Date: 10 July 2015
Available Online: 6 October 2015
Fund Project: 国家自然科学基金(No.21404033,21401046,21001040) (No.21404033,21401046,21001040)河南省教育厅自然科学基金(No.12B150011,14B150029)资助项目。 (No.12B150011,14B150029)

Two complexes [Cd(L)(H₂O)(NO₃)₂] (1) and [Cd(L)I₂]·CH₃OH (2) (L=4-hydroxy-N-((quinolin-8-yl)methylene)benzohydrazide) have been synthesized and structurally determined by single-crystal X-ray diffraction. The results show that the Cd(Ⅱ) ion in 1 with a mono-capped trigonal prismatic geometry is surrounded by one acylhydrazone ligand with N₂O donor set, one water molecule, one mono-dendate and one bidendate nitrate anions. However, the coordination geometry of the Cd(Ⅱ) ion in 1 is a distorted tetragonal pyramid with oxygen and two nitrogen atoms provided by the ligand L and two iodide anions. The thermal stabilities and luminescent properties of both complexes are also investigated in detail.
- quinoline;Cd(Ⅱ) complex;fluorescence;crystal structure;thermostability
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沈阳化工大学材料科学与工程学院沈阳 110142