Citation: SHI Wei-Dong, ZHENG De-Hua, WANG Mei. Preparation and Crystal Structures of Cobalt and Nickel Complexes Containing a Pyridine-Amine Polydentate Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2015, (11): 2205-2212. doi: 10.11862/CJIC.2015.297 shu

Preparation and Crystal Structures of Cobalt and Nickel Complexes Containing a Pyridine-Amine Polydentate Ligand

1.
State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, Liaoning 116024, China

Corresponding author: ZHENG De-Hua,
Received Date: 6 July 2015
Available Online: 21 September 2015
Fund Project: 国家自然科学基金(No.21373040)资助项目。 (No.21373040)

Four new cobalt and nickel complexes containing a polypyridine-amine ligand were designed and prepared, namely, [M(L1)](BF₄)₂ (L1=N,N,N',N'-tetrakis(2-pyridylmethyl)ethane-1,2-diamine; C1, M=Co; C2, M=Ni) and [M(L2)](BF₄)_n (L2=N,N,N',N'-tetrakis(2-pyridylmethyl)propane-1,3-diamine; C3 M=Co, n=3; C4, M=Ni, n=2). These complexes were characterized by infrared spectroscopy (IR) and element analysis (EA). The structures of the complexes were determined by X-ray single crystal diffraction. The four complexes all belong to the monoclinic crystal system but with different space groups (C1, Cc; C2, P2₁/n; C3, C2/c; C4, P2₁/c). Different three-dimensional packing structures were found for these complexes.
- pyridine-amine polydentate ligand;cobalt complex;nickel complex;crystal structure
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