Citation: ZHOU Jie, DONG Shun-Fang, QIAO Yong-Feng, DU Lin, YAN Tong, XIE Ming-Jin, ZHAO Qi-Hua. Assembly and Properties of Four Intriguing One-Dimensional Coordination Polymers with 1,4-Bis(3- or 4-pyridyl)-2,3-diaza-1,3-butadiene Ligands: Effect of Central Metal Ions on the Structures[J]. Chinese Journal of Inorganic Chemistry, ;2015, (11): 2095-2102. doi: 10.11862/CJIC.2015.294 shu

Assembly and Properties of Four Intriguing One-Dimensional Coordination Polymers with 1,4-Bis(3- or 4-pyridyl)-2,3-diaza-1,3-butadiene Ligands: Effect of Central Metal Ions on the Structures

1.
School of Chemistry Science and Technology, Yunnan University, Kunming 650091, China

Corresponding author: ZHAO Qi-Hua,
Received Date: 6 July 2015
Available Online: 19 September 2015
Fund Project: 国家自然科学基金(No.21371151,21461029,21561033) (No.21371151,21461029,21561033)

Four mixed-ligand coordination polymers, {[Zn(4-bpdb)(pnba)₂]·4H₂O}_n (1), [Cd(4-bpdb)(pnba)₂]_n (2), {[Cd₂(3-bpdb)₂(OAc)₄]·5H₂O}_n (3), and {[Co(3-bpdb)(pnba)₂(H₂O)₂]·2H₂O}_n (4), (4-bpdb=1,4-bis(4-pyridyl)-2,3-diaza-1,3-butadiene, 3-bpdb=1,4-bis(3-pyridyl)-2,3-diaza-1,3-butadiene, Hpnba=p-nitrobenzoic acid, HOAc=Acetic acid) were synthesized and characterized. Single crystal X-ray analysis revealed that complex 1 featured a 1D zigzag chain structure and the Zn(Ⅱ) ions adopted slightly distorted tetrahedral coordination geometry. While polymers 2 and 3 possessed 1D ladder-like double chain structures with Cd(Ⅱ) ions in pentagonal bipyramidal coordination geometry. Polymer 3 displayed a 1D linear chain structure where Co(Ⅱ) ions had octahedral geometry. Moreover, the elemental analysis, infrared spectroscopy, thermal analysis, PXRD, and photoluminescence properties of the complexes were also investigated.
- bis-pyridyl ligand;coordination polymer;crystal structure;fluorescent property
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