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Citation: HANG Cheng, LU Zhi-Yong, MENG Fei, JIANG Jing-Jing, BAI Jun-Feng. A Microporous 3D MOF Constructed from an Acylamide Tetracid Ligand: Effective Reversible Iodine Adsorption Property[J]. Chinese Journal of Inorganic Chemistry, ;2015, (11): 2103-2110. doi: 10.11862/CJIC.2015.276 shu

A Microporous 3D MOF Constructed from an Acylamide Tetracid Ligand: Effective Reversible Iodine Adsorption Property

1.
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China

Corresponding author: BAI Jun-Feng,
Received Date: 30 July 2015
Available Online: 9 September 2015
Fund Project: 国家自然科学基金(No.21371091,21371150)资助项目。 (No.21371091,21371150)

Amicroporous 3D MOF, [Cu₅(L)₂(H₂O)₅] (1) (H₄L=5,5'-((1H-pyrazole-3,5-dicarbonyl)bis(azanediyl))diisophthalic)) with acylamide-functionalized and π-electron walls in its structure was synthesized and characterized. Topological analysis reveals 1 is of 3,3,4,4,6-c net and its porosity was tested by N₂ and CO₂ gas adsorption. Meanwhile, 1 can serve as a good host for encapsulating I₂ (1.94 mmol·g^-1, RT) and exhibits an outstanding performance in reversible adsorption of iodine molecules.
- metal-organic frameworks (MOFs);acylamide bond;π-electron;adsorption of iodine
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