Citation: GAO Li-Guo, SONG Xiao-Li, CAO Wei, LÜ Ling-Ling. Luteolin and Luteolin-Cr(Ⅲ) Complexes: Antioxidation and Reaction Mechanism with Hydrogen Peroxide Radical[J]. Chinese Journal of Inorganic Chemistry, ;2015, (11): 2229-2235. doi: 10.11862/CJIC.2015.275 shu

Luteolin and Luteolin-Cr(Ⅲ) Complexes: Antioxidation and Reaction Mechanism with Hydrogen Peroxide Radical

1.
1 College of Chemistry and Chemical Engineering, Yulin University, Yulin, Shaanxi 719000, China;
2.
2 College of Chemical Engineering, Northwest University, Xi'an 710069, China;
3.
3 College of Life Science and Chemistry, Tianshui Normal University, Tianshui, Gansu 741001, China

Corresponding author: GAO Li-Guo,
Received Date: 3 May 2015
Available Online: 29 August 2015
Fund Project: 国家自然科学基金(No.31272510) (No.31272510)陕西省榆林市科技计划(No.2013zx02,2014cxy-08)资助项目。 (No.2013zx02,2014cxy-08)

Density functional theory(DFT) calculations have been performed to explore the molecular structure and O-H bond dissociation enthalpy(BDE) of luteolin and luteolin-Cr(Ⅲ) complex. Possible antioxidation mechanism between hydrogen peroxide radical·O₂H and luteolin has been discussed, and the hydrogen atom transferring mechanism has been analyzed using the natural bond orbital (NBO) theory. Besides the theoretical studies, the experiment was performed to revise the theoretical peroration. According to the experiment, the complex has a higher ·O₂H radical scavenging activity than that of luteolin which agrees with that by theoretical studies.
- coordination chemistry;radical scavenging activity ;density functional theory;antioxidation mechanism
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