Citation: WANG Xiao-Xiao, LIU Yong-Guang, GE Ming, CUI Guang-Hua. Syntheses, Crystal Structures and Fluorescence Properties of Two Metal-Organic Coordination Polymers Derived from Rigid Bis(1,2,4-triazolyl) and Aromatic Carboxylic Acid Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(10): 2065-2072. doi: 10.11862/CJIC.2015.273 shu

Syntheses, Crystal Structures and Fluorescence Properties of Two Metal-Organic Coordination Polymers Derived from Rigid Bis(1,2,4-triazolyl) and Aromatic Carboxylic Acid Ligands

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College of Chemical Engineering, North China University of Science and Technology, Tangshan, Hebei 063009, China

Corresponding author: CUI Guang-Hua,
Received Date: 23 March 2015
Available Online: 13 July 2015
Fund Project: 国家自然科学基金(No.51474086) (No.51474086)河北省自然科学基金-钢铁联合研究基金(No.B2015209299)资助项目。 (No.B2015209299)

Two metal-organic coordination polymers with novel structural based on a rigid bis(triazole) ligand, namely, [Co_1.5(btb)₂(nbta)(H₂O)₂]_n (1), and [Cd(btb)_0.5(nph)(H₂O)]_n (2) (btb=4,4'-bis(1,2,4-triazolyl-1-yl)-biphenyl, H₃nbta=5-nitro-1,2,3-benzenetricarboxylic acid, H₂nph=3-nitrophthalic acid) were synthesized hydrothermally and characterized by IR, elemental analysis, as well as single-crystal X-ray diffraction. Compound 1 features a 2D structure with a (3,4)-connected 3,4L90 topology, which ultimately is extended into a 3D supramolecular framework via O-H…O hydrogen bonding interactions. While complex 2 exhibits a 3D (3,4,4)-connected sqc69 network with the Schläfli symbol of (4.8²)₂(4².8².10²)(8.10⁴.12). Furthermore, the thermal stability and fluorescence properties of the complexes have been investigated. CCDC: 1055345, 1; 1063802, 2.
- bis(triazole);crystal structure;coordination polymer;mixed-ligand;fluorescence
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