Citation: YIN Yan-Ping, LU Hua-Quan, WANG Zhong, SUN Xue-Yi, ZHUANG Wei-Dong, LU Shi-Gang. Effect of Different Second Particle Size on Rate Capability of Li-Rich Layered Cathode Materials Li_1.2Mn_0.54Ni_0.13Co_0.13O₂[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(10): 1966-1970. doi: 10.11862/CJIC.2015.271 shu

Effect of Different Second Particle Size on Rate Capability of Li-Rich Layered Cathode Materials Li_1.2Mn_0.54Ni_0.13Co_0.13O₂

1.
R & D Center for Vehicle Battery and Energy Storage, General Research Institute for Non-ferrous Metals, Beijing 100088, China

Corresponding author: ZHUANG Wei-Dong,
Received Date: 2 February 2015
Available Online: 27 August 2015
Fund Project: 国家自然科学基金(No.51302017) (No.51302017)北京市科技计划(No.Z121100006712002) (No.Z121100006712002)863计划(2012AA110102)资助项目。 (2012AA110102)

Li-rich layered cathode materials Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ with different second particle size distribution were prepared by carbonate based co-precipitation. The samples were characterized by X-ray diffraction (XRD), field emission scanning electron microscope (FESEM), laser particle size analyze and electrochemical performance tests. The results showed that there were no significant differences in structures between the Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ materials with different second particle size, and the three samples had similar discharge capacities (281 mAh·g^-1) for the first cycle. However, the sample with smaller second particle size showed a much superior rate capability to the sample with bigger particle size. When the D₅₀ of second particle size reduced to 4.59 μm, the sample delivered a discharge capacity of 199 mAh·g^-1 at 3C-rate. The improvement in rate capability could be attributed to the smaller particle size, which gives a better contact between the active material and the electrolyte/conductive agent, at the same time a shorter diffusion path.
- lithium-ion batteries;cathode material;Li-rich layered;second particle size;electrochemical performance
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Effect of Different Second Particle Size on Rate Capability of Li-Rich Layered Cathode Materials Li1.2Mn0.54Ni0.13Co0.13O2

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通讯作者: 陈斌, bchen63@163.com

Effect of Different Second Particle Size on Rate Capability of Li-Rich Layered Cathode Materials Li_1.2Mn_0.54Ni_0.13Co_0.13O₂