Citation: LI Hong-Ren, ZHANG Yan, LIU Shi-Qi, LI Feng. One Step Synthesis of Fe/N Co-Doped Carbon Nanoparticles for Photocatalysis[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(10): 1938-1945. doi: 10.11862/CJIC.2015.270 shu

One Step Synthesis of Fe/N Co-Doped Carbon Nanoparticles for Photocatalysis

1.
Normal College, Shenyang University, Shenyang 110044, China

Corresponding author: LI Feng,
Received Date: 31 March 2015
Available Online: 27 August 2015
Fund Project: 沈阳大学博士启动基金支持项目(No.11202127012)资助项目。 (No.11202127012)

A one step method of synthesis of iron-nitrogen doped carbon nanoparticles (Fe/NCNPs) is developed by pyrolysis using citric acid and ammonium oxalate as carbon source and FeCl3 as iron source. The solution of as-prepared Fe/NCNPs emits blue fluorescent under 365 nm UV. As-prepared Fe/NCNPs are investigated by XRD, TEM, FTIR, FL and XPS. The result indicates that as-prepared Fe/NCNPs are well- dispersed with an average diameter of about 3~5 nm. Its fluorescence spectra show that the particles have excellent fluorescence performance, and with increasing excitation wavelength, the fluorescence spectra shift to longer wavelengths, which is multicolor. In addition, the solution of as-prepared Fe/NCNPs has good short wavelength optical emission with long wavelength visible and infrared light excitation, which is the up-converting function. When as-prepared Fe/NCNPs are applied to photocatalytic degradation of methylene blue (20 mg·L^-1) irradiated by visible light, when the H₂O₂ is absent, the decolorization rate is over 90% in 15 hours; when H₂O₂ is present as oxidant, the decolorization rate is over 97% in 15 min, revealing excellent photocatalytic activity. The redox reaction mechanism of the photocatalytic degradation is evaluated by electrochemical method, and the result is consistent with the theory.
- Fe/N co-doped;carbon nanoparticles;fluorescence;pyrolysis synthesis;photocatalysis
1. [1]
  [1] Sun Y, Zhou B, Lin Y, et al. J. Am. Chem. Soc., 2006,128(40):7756-7757
2. [2]
  [2] Li N, Liang X, Wang L, et al. J. Nanopart Res., 2012,14:1177-1186
3. [3]
  [3] Goh E, Kim K, Kim Y, et al. J. Am. Chem. Soc., 2012,13:2554-2561
4. [4]
  [4] Yu X, Liu R, Zhang G, et al. Nanotechnology, 2013,24:335401-335407
5. [5]
  [5] Hu S, Tian R, Wu L, et al. Chem. Asian J., 2013,08(05):1035-1041
6. [6]
  [6] Zhang Y, Ma D, Zhang Y, et al. Nano Energy, 2013,2:545-552
7. [7]
  [7] Qu S, Wang X, Lu Q, et al. Angew. Chem. Int. Ed., 2012, 51:12215-12218
8. [8]
  [8] Li H, Li F, Wang G, et al. J. Lumin., 2014,156:36-41
9. [9]
  [9] Wang J, Wang C, Chen S. Angew. Chem. Int. Ed., 2012,51:9297-9301
10. [10]
  [10] Lu W, Qin X, Liu S, et al. Anal. Chem., 2012,84:5351-5357
11. [11]
  [11] Feng Y, Zhong D, Miao H, et al. Talanta, 2015,140:128-133
12. [12]
  [12] Li F, Wang G, Li H, et al. Mater. Lett., 2014,122:352-354
13. [13]
  [13] Luo P, Li C, Shi G. Chem. Phys., 2012,14:7360-7366
14. [14]
  [14] Li J, Zhang B, Wang F, et al. New J. Chem., 2011,35:554-557
15. [15]
  [15] Mewada A, Pandey S, Shinde S, et al. Mater. Sci. Eng. C, 2013,33:2914-2917
16. [16]
  [16] Wang L, Ruan F, Lü T, et al. J. Lumin., 2015,158:1-5
17. [17]
  [17] Wilson D, Langell M A. Appl. Surf. Sci., 2014,303:6-13
18. [18]
  [18] Gong X, Lu W, Chin M, et al. Anal. Chim. Acta, 2015,861:74-84
19. [19]
  [19] Zhang B, Liu C, Liu Y, et al. Eur. J. Inorg. Chem., 2010,28:4411-4414
20. [20]
  [20] Cao L, Wang Meziani X M, et al. Am. Chem. Soc., 2007, 129(37):11318-11319
21. [21]
  [21] Liu R, Huang H, Li H, et al. ACS Catal., 2014,4:328-335
1. [1]
  Qin Hu , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Ni掺杂构建电子桥及激活MoS₂惰性基面增强光催化分解水产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-. doi: 10.3866/PKU.WHXB202406024
2. [2]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . 熔融中间体运输导向合成富氨基g-C₃N₄纳米片用于高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-. doi: 10.3866/PKU.WHXB202406021
3. [3]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
4. [4]
  Feng Lu , Tao Wang , Qi Wang . Preparation and Characterization of Water-Soluble Silver Nanoclusters: A New Design and Teaching Practice in Materials Chemistry Experiment. University Chemistry, 2025, 40(4): 375-381. doi: 10.12461/PKU.DXHX202406005
5. [5]
  Xi YANG , Chunxiang CHANG , Yingpeng XIE , Yang LI , Yuhui CHEN , Borao WANG , Ludong YI , Zhonghao HAN . Co-catalyst Ni₃N supported Al-doped SrTiO₃: Synthesis and application to hydrogen evolution from photocatalytic water splitting. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 440-452. doi: 10.11862/CJIC.20240371
6. [6]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
7. [7]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
8. [8]
  Xin Zhou , Zhi Zhang , Yun Yang , Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi₂MoO₆ Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008
9. [9]
  Yadan Luo , Hao Zheng , Xin Li , Fengmin Li , Hua Tang , Xilin She . 调节O,S共掺杂C₃N₄中的活性氧生成以促进光催化降解微塑料. Acta Physico-Chimica Sinica, 2025, 41(6): 100052-. doi: 10.1016/j.actphy.2025.100052
10. [10]
  Chenye An , Abiduweili Sikandaier , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . 红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-. doi: 10.3866/PKU.WHXB202405019
11. [11]
  Qin Li , Huihui Zhang , Huajun Gu , Yuanyuan Cui , Ruihua Gao , Wei-Lin Dai . In situ Growth of Cd_0.5Zn_0.5S Nanorods on Ti₃C₂ MXene Nanosheet for Efficient Visible-Light-Driven Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2025, 41(4): 100031-. doi: 10.3866/PKU.WHXB202402016
12. [12]
  Yang Xia , Kangyan Zhang , Heng Yang , Lijuan Shi , Qun Yi . 构建双通道路径增强iCOF/Bi₂O₃ S型异质结在纯水体系中光催化合成H₂O₂性能. Acta Physico-Chimica Sinica, 2024, 40(11): 2407012-. doi: 10.3866/PKU.WHXB202407012
13. [13]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . 两步焙烧法制备大比表面积和结晶性增强超薄g-C₃N₄纳米片及其高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-. doi: 10.3866/PKU.WHXB202406019
14. [14]
  Chen LU , Qinlong HONG , Haixia ZHANG , Jian ZHANG . Syntheses, structures, and properties of copper-iodine cluster-based boron imidazolate framework materials. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 149-154. doi: 10.11862/CJIC.20240407
15. [15]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
16. [16]
  Jianyin He , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . ZnCoP/CdLa₂S₄肖特基异质结的构建促进光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2404030-. doi: 10.3866/PKU.WHXB202404030
17. [17]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
18. [18]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
19. [19]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005
20. [20]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(249)
HTML views(23)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142