Citation: FAN Yan, QU Zhi-Rong, JIN Xiao-Fei, GUO Yan-Hong, WANG Zuo-Xiang. Syntheses, Crystal Structures and Luminescent Properties of Two Cu(Ⅱ) Complexes with 2-(2-Pyridyl)imidazole Derivatives[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(10): 2051-2058. doi: 10.11862/CJIC.2015.262 shu

Syntheses, Crystal Structures and Luminescent Properties of Two Cu(Ⅱ) Complexes with 2-(2-Pyridyl)imidazole Derivatives

1.
1 Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, Hangzhou 311121, China;
2.
2 School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China

Corresponding author: QU Zhi-Rong, WANG Zuo-Xiang,
Received Date: 25 February 2015
Available Online: 4 August 2015

Two complexes, [Cu(DMPM)₂(Bz)][Cu(DMPM)(Bz)₃]·H₂O (1) and [Cu(PMA)Cl₂] (2) (DMPM=4,5-dimethyl-2-(2-pyridyl)imidazole, PMA=ethyl [2-(2-pyridyl)imidazole-1-yl)]acetate, Bz=benzoate anion) were synth-esized and characterized by ultraviolet spectrophotometry (UV-Vis), thermogravimetric analysis (TG), differential scanning calorimetry (DSC), electron spin resonance (ESR) and single crystal X-ray diffraction. Results show that the crystal structure of complex 1 belongs to triclinic system, space group P1, and complex 2 belongs to monoclinic system, space group P2₁/c. Complex 1 assembles into a 3D structure by the intermolecular hydrogen bonding interactions, whereas a 2D layer structure of complex 2 is assembled by hydrogen bonds. CCDC: 1414243, 1; 1414242, 2.
- 2-(2-pyridyl)imidazole derivatives;synthesis;crystal structure
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沈阳化工大学材料科学与工程学院沈阳 110142