Citation: ZHANG Yu, SU Zhi, PAN Hui. Synthesis and Performance of LiNi_0.5Co_0.4Al_0.1O₂ Composite Material for Lithium Ion Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(9): 1827-1830. doi: 10.11862/CJIC.2015.250 shu

Synthesis and Performance of LiNi_0.5Co_0.4Al_0.1O₂ Composite Material for Lithium Ion Batteries

1.
College of Chemistry and Chemical Engineering, Xinjiang Normal University, Urumiqi 830054, China

Corresponding author: SU Zhi,
Received Date: 25 May 2015
Available Online: 20 July 2015
Fund Project: 国家自然科学基金(No.21061015)资助项目。 (No.21061015)

LiNi_0.5Co_0.4Al_0.1O₂ compositions were synthesized by high temperature solid-state method. The crystal structures and surface morphology of LiNi_0.5Co_0.4Al_0.1O₂ powders were characterized by X-ray diffractometry(XRD), fourier transform infrared spectrometer(FTIR) and scanning electron microscopy(SEM). The electrochemical properties of LiNi_0.5Co_0.4Al_0.1O₂ were examined by charge-discharge tests and cyclic voltammetry. The results showed that thematerial delivered the initial discharge capacity of 159.9 mAh·g^-1 with the voltage range 3~4.5 V and 0.2C rate, and it retained 142.6 mAh·g^-1 discharge capacity after 50 cycles.
- high temperature solid-state method;lithium ion batteries;composite material;electrochemical properties
1. [1]
  [1] Tarascon J M, Armand M. Nature, 2001,414(6861):359-367
2. [2]
  [2] Diouf B, Pode R. Renewable Energy, 2015,76:375-380
3. [3]
  [3] Ohzuku T, Makimura Y. Chem. Lett., 2001,30(7):642-643
4. [4]
  [4] He Y S, Ma Z F, Liao X Z, et al. J. Power Sources, 2007, 163(2):1053-1058
5. [5]
  [5] ZHU Yong-Jun(朱永军), LI Hai-Xin(李海新), WANG Zhi-Xing(王志兴), et al. Chinese J. Nonferrous Met.(中国有色金属学报), 2006,16(12):2110-2113
6. [6]
  [6] Li J, He X, Fan M, et al. Ionics, 2006,12(1):77-80
7. [7]
  [7] CHENG Xue-Lian(成雪莲), WANG Jin(王瑾), WANG Zi-Gang(王子港), et al. J. Funct. Mater.(功能材料), 2010,41(5):581-584
8. [8]
  [8] TAN Long(谭龙), LIU Hao-Wen(刘浩文). Chem. World(化学世界), 2010,2:122-125
9. [9]
  [9] WU Bin(伍斌). Thesis for the Master of Central South University(中南大学硕士论文). 2011.
10. [10]
  [10] Kostecki R, McLarnon F. Electrochem. Solid-State Lett., 2004,7(10):A380-A383
11. [11]
  [11] LI Xiao-Wei(李晓伟), LIN Ying-Bin(林应斌), LIN Ying(林莹) et al. Chinese J. Inorg. Chem.(无机化学学报), 2011,27(4):643-648
12. [12]
  [12] BAO Li-Ying(包丽颖), CHE Hui-Quan(车辉泉), HU Dao-Zhong(胡道中), et al. Chin. Sci. Bull.(科学通报), 2013,58(19):1809-1816
13. [13]
  [13] LIAO Li(廖力). Thesis for the Master of Xiangtan University (湘潭大学硕士论文). 2006.
14. [14]
  [14] Song S W, Zhuang G V, Ross P N. J. Electrochem. Soc., 2004,151(8):A1162-A1167
15. [15]
  [15] LIU Wan-Min(刘万民). Thesis for Doctorate of Central South University(中南大学硕士论文). 2012.
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis and Performance of LiNi0.5Co0.4Al0.1O2 Composite Material for Lithium Ion Batteries

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通讯作者: 陈斌, bchen63@163.com

Synthesis and Performance of LiNi_0.5Co_0.4Al_0.1O₂ Composite Material for Lithium Ion Batteries