Citation: NASEN Bate, CHEN Wei-Lin, LIU Zhu-Jun, XU Sha-Sha, WANG En-Bo. Four Keggin-Based Nanomaterials: Synthesis and Adsorption of Organic Dyes[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(9): 1820-1826. doi: 10.11862/CJIC.2015.246 shu

Four Keggin-Based Nanomaterials: Synthesis and Adsorption of Organic Dyes

1.
Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Changchun 130024, China

Corresponding author: CHEN Wei-Lin, WANG En-Bo,
Received Date: 28 May 2015
Available Online: 17 July 2015
Fund Project: 国家自然科学基金(No.21201031) (No.21201031)高等学校博士学科点专项科研基金新教师类资助课题(No.20120043120007) (No.20120043120007)吉林省科技发展计划青年科研基金(No.201201072)资助项目。 (No.201201072)

Four Keggin-based nanomaterials (PMo₁₂^b, PW₁₂^b, SiW₁₂^b and GeW₁₂^b) were controllably prepared. The structure and the size of all the compounds have been characterized by IR, UV-Vis, XRD and SEM. Further investigations showed that four Keggin-based nanomaterials exhibited fast adsorption rate towards dye molecules. The adsorption efficiency of those compounds (100 mg) towards MB (100 mL of 20 mg·L^-1) could reach up to 96.3% in the initial 5 min under dark condition, the adsorption efficiency sequence is PMo₁₂^b > PW₁₂^b > GeW₁₂^b > SiW₁₂^b. And also, the adsorption efficiency towards RhB (100 mL of 20 mg·L^-1)could reach up to 96.1% in 30 min under same conditions, the adsorption efficiency sequence is PW₁₂^b > PMo₁₂^b > SiW₁₂^b > GeW₁₂^b. All the investigations indicate that the four kind of POMs-nanomaterials present excellent adsorption properties of the organic dyes.
- nanomaterial;polyoxometalate (POM);adsorption;methylene blue (MB);Rhodamin B (RhB)
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沈阳化工大学材料科学与工程学院沈阳 110142