Citation: TANG Wen-Yuan, REN Shi-Bin, ZHU Dong-Dong, HAN De-Man, ZHOU Xin-Hui. Crystal Structures and Properties of Zn(Ⅱ)/Cd(Ⅱ) Coordination Polymers Based on Semirigid Tetrahedral Quadridentate Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(10): 2073-2078. doi: 10.11862/CJIC.2015.229 shu

Crystal Structures and Properties of Zn(Ⅱ)/Cd(Ⅱ) Coordination Polymers Based on Semirigid Tetrahedral Quadridentate Ligand

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1 School of Pharmaceutical and Chemical Engineering, Taizhou University, Taizhou, Zhejiang 317000, China;
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2 State Key Laboratory of Analytical Chemistry for Life Science, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China;
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3 Key Laboratory for Organic Electronics & Information Displays(KLOEID)and Institute of Advanced Materials(IAM), Nanjing University of Posts & Telecommunications, Nanjing 210023, China

Corresponding author: REN Shi-Bin, ZHOU Xin-Hui,
Received Date: 13 April 2015
Available Online: 14 May 2015
Fund Project: 国家自然科学基金(No.21471110,21375092) (No.21471110,21375092)浙江省自然科学基金(No.LY12B01006) (No.LY12B01006)中国博士后基金(No.2013M531314) (No.2013M531314)生命分析国家重点实验室开放课题(No.SKLACLS1206) (No.SKLACLS1206)浙江省大学生创新计划项目(No.2014R428014) (No.2014R428014)台州市科技局项目(No.131KY03) (No.131KY03)浙江省科技厅公益分析测试项目(No.2015C37034)资助项目。 (No.2015C37034)

Two complexes, {[Cd₂(L₁)(1,4-NDC)₂]·2H₂O}_n (1) and {[Zn₂(L₂)(1,4-NDC)₂]·DMF·3H₂O)}_n (2) (L₁=tetrakis(4-pyridyloxymethylene)methane, L₂=tetrakis(3-pyridyloxymethylene)methane, 1,4-NDC=naphthalene-1,4-dicarbox-ylic acid) are obtained by the self-assembly reaction of L₁ or L₂, 1,4-NDC, and d¹⁰ metal ions under solvothermal conditions. The X-ray analysis reveals that 1 is constructed from a 1D zigzag chain [Cd(1,4-NDC)]_n which is linked by L₁ ligand to yield a 3D framework. And yet in case of 2, one double helix is mutually interdigitated by another 1D chain into a 2D network. Above all, the effect of steric hindrance of the auxiliary linker on the structural diversity of CPs can be discussed in great detail by the introduction of two kinds of auxiliary linkers with different steric hindrance. Additionally, their luminescent properties are also observed. CCDC: 1019510, 1; 1019511, 2.
- carboxylate ligands;isomerization;steric hindrance;luminescence
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