Citation: MA Ai-Qing, ZHU Long-Guan. Structural Diversity, Supramolecular Assembly, and Electronic Spectra of Four Silver Coordination Polymers with Same Components of 2-Nitro-1,4-benzenedicarboxylate and 4,4'-Bipyridine[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(8): 1651-1660. doi: 10.11862/CJIC.2015.227 shu

Structural Diversity, Supramolecular Assembly, and Electronic Spectra of Four Silver Coordination Polymers with Same Components of 2-Nitro-1,4-benzenedicarboxylate and 4,4'-Bipyridine

MA Ai-Qing ^1,2 ,
ZHU Long-Guan ^1,,

1.
1. Department of Chemistry, Zhejiang University, Hangzhou 310027, China;
2.
2. School of Pharmacy, Guangdong Medical University, Dongguan, Guangdong 523808, China

Corresponding author: ZHU Long-Guan,
Received Date: 4 May 2015
Available Online: 4 June 2015
Fund Project: 国家自然科学基金(No.21073157)资助项目。 (No.21073157)

Four diverse silver coordination polymers with the same components of silver, 4,4'-bipyridine(4,4'-bipy), and 2-nitro-1,4-benzenedicarboxylic acid (2-H₂nbdc) have been synthesized, namely {[Ag(4,4'-bipy)]·2-Hnbdc·2H₂O·CH₃OH}_n (1), {[Ag(4,4'-bipy)(2-Hnbdc)]}_n (2), {[Ag₂(4,4'-bipy)₂(2-nbdc)]·2H₂O}_n (3), and {[Ag₂(4,4'-bipy)₂(2-nbdc)(H₂O)]·2H₂O}_n (4), and characterized by IR, elemental analysis, TG, UV, fluorescence spectra, and powder X-ray analysis. The single crystal X-ray analysis showed that complex 1 is a 1D cation-anionic polymer, complex 2 is a 1D double chain without any solvent, and complexes 3 and 4 are 1D chain structures. Diverse structures differ with respect to molecular conformation, coordination modes of 2-Hnbdc, and weak interactions. In these complexes there are weak bonds, π-π aromatic stacking interactions, Ag…Ag interaction, and hydrogen bonding. The diverse structures are related to the thermal stability, UV absorptions, and fluorescence emissions. CCDC: 945166, 1; 945167, 2; 945168, 3; 945169, 4.
- coordination modes;structure elucidation;silver coordination compound;nitrobenzenedicarboxylate
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