Citation: ZHANG Ming, WANG Shuai-Shuai, ZHU Han, DU Ming-Liang. Preparation and Characterization of Monodispersed and Water-Soluble Gold Nano-Clusters[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(10): 2015-2020. doi: 10.11862/CJIC.2015.222 shu

Preparation and Characterization of Monodispersed and Water-Soluble Gold Nano-Clusters

1.
1 Zhejiang Sci-Tech University, Hangzhou 310018, China;
2.
2 National Engineering Lab for Textile Fiber Materials and Processing Technology, Hangzhou 310018, China

Corresponding author: ZHANG Ming,
Received Date: 10 April 2015
Available Online: 3 June 2015
Fund Project: 浙江省高校重中之重学科开放基金(N0.2013YXQN04)资助项目。 (N0.2013YXQN04)

Monodispersed water-soluble gold nano-clusters were prepared by using sodium borohydride to reduce tetrachloroauric acid in methanol, with water-soluble 2-mercaptosuccinic acid as the protecting agent on gold nano-cluster surface. HRTEM results show that MSA monolayer-protected gold clusters were obtained with size of about 10.2 nm by increasing the proportion of 2-mercaptosuccinic acid and concentration of tetrachloroauric acid with C_Au:C_S=1:30. TG, UV and XPS results show that the possible chemical formula of the synthesized gold nano-clusters is [Au₃₈(MSANa)₂₆] or [Au₃₉(MSANa)₂₇].
- gold nano-clusters;nanoparticles;monodisperse;2-mercaptosuccinic acid
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沈阳化工大学材料科学与工程学院沈阳 110142