Citation: WU Di, YU Zhu, GAO Da-Zhi, WANG Xin, SHEN Xuan, ZHU Dun-Ru. A Mixed-Bridged Linear Trinuclear Copper(Ⅱ) Complex Containing Both Square Pyramidal and Trigonal Bipyramidal Configuration[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(8): 1619-1625. doi: 10.11862/CJIC.2015.220 shu

A Mixed-Bridged Linear Trinuclear Copper(Ⅱ) Complex Containing Both Square Pyramidal and Trigonal Bipyramidal Configuration

WU Di ¹ ,
YU Zhu ¹ ,
GAO Da-Zhi ¹ ,
WANG Xin ¹ ,
SHEN Xuan ¹ ,
ZHU Dun-Ru ^1,2,,

1.
1. College of Chemical Engineering, State Key Laboratory of Materials-oriented Chemical Engineering, Nanjing Tech University, Nanjing 210009, China;
2.
2. State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China

Corresponding author: ZHU Dun-Ru,
Received Date: 19 April 2015
Available Online: 2 June 2015
Fund Project: 国家自然科学基金资助项目(No.21171093,21476115) (No.21171093,21476115)

A novel trinuclear copper(Ⅱ) complex, [Cu₃L₂(py)](ClO₄)₂·2THF (1) (H₂L=(E)-3-[N,N-di(2-pyridylmethyl)aminomethyl]-2-hydroxyl-5-methylbenzaldehyde oxime, py=pyridine, THF=tetrahydrofuran), has been successfully synthesized and characterized. 1 crystallizes in monoclinic system with space group C2/c, a=2.969 0(7) nm, b=1.302 8(3) nm, c=2.057 4(9) nm, β=132.435(2)°, V=5.873(3) nm³, Z=4 with final R₁=0.047 9. X-ray crystallography analysis reveals that 1 is a mixed-bridged (-N-O-/μ₂-O-) linear tricopper(Ⅱ) complex with all the copper cations being five-coordinated by three N and two O atoms: the central Cu(Ⅱ) in a distorted trigonal bipyramidal configuration, whereas the peripheral Cu(Ⅱ) in a distorted square pyramidal arrangement. Magnetic susceptibility measurement indicates that there is a medium antiferromagnetic exchange coupling between the Cu(Ⅱ) ions with a J value of -33.3(5) cm^-1. CCDC: 916132.
- trinuclear copper;pentacoordinate;crystal structure;mixed-bridged;anti-ferromagnetism
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