多级结构氧化锌的构筑、形貌调控及其光催化活性

引用本文: 全微雷, 张金敏, 沈俊海, 李良超, 李佳佳. 多级结构氧化锌的构筑、形貌调控及其光催化活性[J]. 无机化学学报, 2015, 31(8): 1626-1636. doi: 10.11862/CJIC.2015.212 shu

Citation: QUAN Wei-Lei, ZHANG Jin-Min, SHEN Jun-Hai, LI Liang-Chao, LI Jia-Jia. Hierarchical ZnO: Architecture, Morphological Control and Photocatalytic Activity[J]. Chinese Journal of Inorganic Chemistry, 2015, 31(8): 1626-1636. doi: 10.11862/CJIC.2015.212 shu

多级结构氧化锌的构筑、形貌调控及其光催化活性

1.
浙江师范大学化学与生命科学学院, 金华 321004

通讯作者: 李良超,E-mail:sky52@zjnu.cn

基金项目:
国家自然科学基金(No.21071125) (No.21071125)

浙江省大学生科技创新计划(No.2014R404056)资助项目。 (No.2014R404056)

摘要: 分别以混合常见二锌盐为锌源,以离子液体和柠檬酸钠为表面活性剂,在绿色温和的条件下采用二次沉积法制备出多级结构氧化锌。用XRD、IR、SEM、UV-Vis、PL等表征了样品的组成、结构、形貌、光致发光性能及光催化性能。探讨了表面活性剂、阴离子、温度等因素对氧化锌形貌的影响。结果表明,由不同表面活性剂所得到样品的多级结构有较大的差异。此外,推测了在多级结构氧化锌形成过程中,阴离子和温度对样品形貌的调控作用,并对比了三种典型样品的光催化性能,其中样品-1的光催化性能最好。

关键词:

氧化锌;多级结构;形貌调控;光催化

English

Hierarchical ZnO: Architecture, Morphological Control and Photocatalytic Activity

1.
College of Chemistry and Life Sciences, Zhejiang Normal University, Jinhua, Zhejiang 321004, China

Corresponding author: 李良超,E-mail:sky52@zjnu.cn

Received Date: 21 April 2015
Fund Project:
国家自然科学基金(No.21071125)

浙江省大学生科技创新计划(No.2014R404056)资助项目。

Abstract: Under the green and mild conditions, the hierarchical ZnO was fabricated by the secondary deposition with mixed two zinc salts (zinc source), ionic liquid (surfactant). The composition, structure, morphology, photoluminescence properties and photocatalytic activity of samples were characterized by XRD, IR, SEM, UV-Vis and PL, respectively. The influential factors on sample morphology, such as surfactant, the kind of anion and temperature, were discussed. The results indicate that surfactant has a significant regulation on the morphologies of as-prepared ZnO samples. Furthermore, the anion and temperature also play a critical role in the crystal structure and morphology of ZnO. In addition, all of as-prepared hierarchical ZnO show an excellent photocatalytic activity on methyl orange under UV lamp, where the sample-1 is slightly better than others.

Key words:

ZnO;hierarchical structure;morphological control;photocatalysis

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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

多级结构氧化锌的构筑、形貌调控及其光催化活性

通讯作者: 李良超,E-mail:sky52@zjnu.cn

English

Hierarchical ZnO: Architecture, Morphological Control and Photocatalytic Activity

Corresponding author: 李良超,E-mail:sky52@zjnu.cn

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

多级结构氧化锌的构筑、形貌调控及其光催化活性

通讯作者: 李良超,E-mail:sky52@zjnu.cn

English

Hierarchical ZnO: Architecture, Morphological Control and Photocatalytic Activity

Corresponding author: 李良超,E-mail:sky52@zjnu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

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