Citation: LIANG Li-Li, XU Lei, CHEN Fei-Jian, SI You-Lin, TAO Zhao-Lin, XUE Hong-Bao. Syntheses, Structures and Properties of Two Cadmium Complexes Constructed from a Flexible Tetrahedral Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(10): 1993-2000. doi: 10.11862/CJIC.2015.210 shu

Syntheses, Structures and Properties of Two Cadmium Complexes Constructed from a Flexible Tetrahedral Ligand

LIANG Li-Li ^1,2 ,
XU Lei ¹ ,
CHEN Fei-Jian ^1,2 ,
SI You-Lin ² ,
TAO Zhao-Lin ² ,
XUE Hong-Bao ^2,,

1.
1 State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China;
2.
2 Department of Chemistry, Bengbu Medical College, Bengbu, Anhui 233030, China

Corresponding author: XUE Hong-Bao,
Received Date: 16 March 2015
Available Online: 16 June 2015
Fund Project: 安徽省自然科学基金(No.1308085QB24) (No.1308085QB24)安徽省优秀青年人才基金重点项目(No.2013SQRL051ZD) (No.2013SQRL051ZD)

Two cadmium coordination polymers, [Cd₆L₃(DMA)₃(H₂O)]_n (1) and {[Cd₂L(H₂O)₄]·4H₂O}_n (2) (L=tetrakis[3-(carboxyphenyl)oxamethyl]methane acid) with different structures have been synthesized based on a tetrahedral ligand L. Compound 1 crystallizes in the trigonal space group R3. The tetrahedral ligand connects four Cd₃ clusters through its four carboxylates and the Cd₃ clusters connect six benzoic rings to form a 4,6-connected 3-dimentional framework of the toc topology. Compound 2 crystallizes in the monoclinic C2/c space group. Each ligand connects four cadmium atoms and the cadmium atoms are connected through carboxylates to form a chain along the b axis. The solid-state UV-Vis spectra and photoluminescent properties of 1 and 2 were investigated at room tempreture. CCDC: 1030076, 1; 1046165, 2.
- cadmium complex;tetrakis[3-(carboxyphenyl)oxamethyl]methane acid;crystal structure;luminescent property
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