Citation: LONG Fei, ZHANG Jin, ZHANG Ming-Yue, HE Jin-Yun, WU Xiao-Li, ZOU Zheng-Guang. Ni-Doped FeS₂: Solvothermal Synthesis and the Visible-Light Photocatalytic Properties[J]. Chinese Journal of Inorganic Chemistry, ;2015, (6): 1119-1124. doi: 10.11862/CJIC.2015.179 shu

Ni-Doped FeS₂: Solvothermal Synthesis and the Visible-Light Photocatalytic Properties

LONG Fei ^1,2 ,
ZHANG Jin ² ,
ZHANG Ming-Yue ² ,
HE Jin-Yun ^1,2 ,
WU Xiao-Li ^1,2 ,
ZOU Zheng-Guang ^1,2

1.
1 Key Laboratory of Nonferrous Materials and New Processing Technology of Ministry of Education, Guilin, Guangxi 541004, China;
2.
2 School of Materials Science and Engineering, Guilin University of Technology, Guilin, Guangxi 541004, China

Received Date: 18 November 2014
Available Online: 30 April 2015
Fund Project: 国家自然科学基金(No.51162005) (No.51162005)广西自然科学基金(No.2012GXNSFFA060007)资助项目。 (No.2012GXNSFFA060007)

Ni-doped pyrite FeS₂ were synthesized through a solvothermal method using FeSO₄·7H₂O, Na₂S₂O₃·5H₂O and NiSO₄·6H₂O as raw materials. The products were characterized by X-ray diffraction (XRD), X-ray Photoelectron Spectroscopy (XPS), field emission scanning electron microscope (FE-SEM), UV-Vis diffuse reflectance spectra (DRS) and Raman spectroscopy. The results showed that appropriate amount of Ni doping facilitated the transformation of the marcasite to pyrite. After Ni²⁺ doping, the visible-light-driven photocatalytic performance of the FeS₂ was greatly enhanced. Methylene blue (MB) was decomposed 62.8% within 210 min using Ni_0.125Fe_0.875S₂ as photocatalyst, which was 26.2% higher than that of the pristine FeS₂.
- solvothermal synthesis;FeS₂;Ni doping;photocatalytic activity;methylene blue
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Ni-Doped FeS2: Solvothermal Synthesis and the Visible-Light Photocatalytic Properties

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Ni-Doped FeS₂: Solvothermal Synthesis and the Visible-Light Photocatalytic Properties