Citation: DENG Sheng-Jun, ZHENG Qiang, RAO Fu-Yuan, LIN Ling-Zhi, ZHANG Ning. Diphenylphosphine Functionalized Graphite Oxide Loaded with Platinum Complex: Preparation and Catalytic Performance for the Hydrosilylation of Olefins[J]. Chinese Journal of Inorganic Chemistry, ;2015, (6): 1085-1090. doi: 10.11862/CJIC.2015.178 shu

Diphenylphosphine Functionalized Graphite Oxide Loaded with Platinum Complex: Preparation and Catalytic Performance for the Hydrosilylation of Olefins

1.
College of Chemistry, Nanchang University, Nanchang 330031, China

Corresponding author: DENG Sheng-Jun,
Received Date: 23 December 2014
Available Online: 7 March 2015
Fund Project: 国家自然科学基金(No.21263014) (No.21263014)江西省自然科学基金(No.2011ZBAB203013,20122BAB203010) (No.2011ZBAB203013,20122BAB203010)江西省教育厅基金(No.GJJ12103)资助项目。 (No.GJJ12103)

By supported platinum complex to the graphite oxide carrier modified by diphenylphosphine ligands, a GO-P-Pt catalyst was synthesized. The GO-P-Pt catalyst was characterized by means of elemental analysis, FT-IRand XRD, and tested for the hydrosilylation of olefin with triethoxysilane. The catalytic results shows that GO-P-Pt catalyst possessed a high catalytic activity, and 94.6% conversion of 1-octene and 99.4% selectivity of β-adduct in yield were obtained at 100 ℃ after 180 min. And the selectivity of β-adduct was lower when the aromatic olefins were used as reaction substrates. Additionally, GO-P-Pt catalyst can be recycled four times without significant loss of catalytic activity and selectivity.
- hydrosilylation;graphite oxide;platinum catalyst;olefin
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沈阳化工大学材料科学与工程学院沈阳 110142