Citation: ZHANG Fu-Xing, KUANG Dai-Zhi, FENG Yong-Lan, WANG Jian-Qiu, YU Jiang-Xi, JIANG Wu-Jiu, ZHU Xiao-Ming. Syntheses, Crystal Structures and Properties of the Tetra(o-fluorobenzyl)tin and the Tribenzyltin Ferrocenecarboxylate[J]. Chinese Journal of Inorganic Chemistry, ;2015, (6): 1194-1200. doi: 10.11862/CJIC.2015.157 shu

Syntheses, Crystal Structures and Properties of the Tetra(o-fluorobenzyl)tin and the Tribenzyltin Ferrocenecarboxylate

1.
Department of Chemistry and Material Science, Hengyang Normal University, Key Laboratory of Functional Organometallic Materials of Hengyang Normal University, College of Hunan Province, Hengyang, Hunan 421008, China

Corresponding author: ZHANG Fu-Xing,
Received Date: 11 March 2015
Available Online: 27 March 2015
Fund Project: 湖南省自然科学基金(No.13JJ3112) (No.13JJ3112)湖南省科技计划(No.2013TZ2025) (No.2013TZ2025)湖南省高校创新平台开放基金(No.13K105) (No.13K105)

The tetra(o-fluorobenzyl)tin (1) and the tribenzyltin ferrocenecarboxylate (2) have been synthesized. The crystal structures of the complexes were determined by X-ray diffraction. The crystal 1 belongs to tetragonal space group I4₁/a with a=1.96794(16) nm, b=1.96794(16) nm, c=0.59316(5) nm, V=2.2972(3) nm³, Z=4, D_c= 1.605 g·cm^-3, μ(MoKα)=11.58 cm^-1,F(000)=1112, R₁=0.0208, wR₂=0.0576. The crystal 2 belongs to monoclinic space group P2₁/n with a=1.59354(12) nm, b=1.00723(8) nm, c=1.70026(13) nm, β=91.001(10)°, V=2.7286(4) nm³, Z=4, D_c=1.521 g·cm^-3, μ(MoKα)=14.74 cm^-1, F(000)=1256, R₁=0.0384, wR₂=0.0952. The stabilities, some frontier molecular orbital energies and composition characteristics of some frontier molecular orbital of the complexes have been investigated by quantum chemistry calculation. Further more, thermal stability and anticancer activity of the complexes were tested.
- tetra(o-fluorobenzyl)tin;tribenzyltin ferrocenecarboxylate;synthesis;crystal structure
1. [1]
  [1] Chandrasekhar V, Thirumoorthi R, Metre R K, et al. J. Organomet. Chem., 2011,696:600-606
2. [2]
  [2] Effendy, Marchetti F, Marinelli A, et al. Inorg. Chim. Acta, 2011,366(1):388-393
3. [3]
  [3] Munoz-Flores B M, Santillan R, Farfan N, et al. J. Organomet. Chem., 2014,769:64-71
4. [4]
  [4] Hanif M, Hussain M, Ali S, et al. Polyhedron, 2010,29:613-619
5. [5]
  [5] ZHANG Xiao-Yan(张晓燕), YANG Guang(杨光), ZHANG Jun(张俊), et al. Chem. J. Chinsese Universities(高等学校化学学报), 2010,31(6):1162-1166
6. [6]
  [6] Siddiqi Z A, Shahid M, Kumar S, et al. J. Organomet. Chem., 2009,694:3768-3774
7. [7]
  [7] Mahmudov K T, Guedes da Silva M F C, Kopylovich M N, et al. J. Organomet. Chem., 2014,760:67-73
8. [8]
  [8] Ruan B F, Tian Y U, Zhou H P, et al. Inorg. Chim. Acta, 2011,365:302-308
9. [9]
  [9] YIN Han-Dong(尹汉东), WANG Chuan-Hua(王传华), WANG Yong(王勇), et al. Chinese J. Inorg. Chem.(无机化学学报), 2002,18(2):201-204
10. [10]
  [10] YAN Wen-Hua(闫文华), KANG Wan-Li(康万利), LI Jin-Huan(李金环). Chinese J. Appl. Chem.(应用化学), 2007,24 (6):660-664
11. [11]
  [11] Shujha S, Shah A, Rehman Z U, et al. Eur. J. Med. Chem., 2010,45:2902-2911
12. [12]
  [12] ZHANG Fu-Xing(张复兴), KUANG Dai-Zhi(邝代治), WANG Jian-Qiu(王剑秋), et al. Chinese J. Org. Chem.(有机化学), 2008,28(8):1457-1461
13. [13]
  [13] KUANG Dai-Zhi(邝代治), JIANG Wu-Jiu(蒋伍玖), FENG Yong-Lan(冯泳兰), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012,27(10):1981-1986
14. [14]
  [14] WANG Jian-Qiu(王剑秋), ZHANG Fu-Xing(张复兴), KUANG Dai-Zhi(邝代治), et al. Chinese J. Inorg. Chem.(无机化学学报), 2015,27(31):237-2426
15. [15]
  [15] Sheldrick G M. SHELXL-97, Program for Crystal Structure Refinement, University of Göttingen, Germany, 1997.
16. [16]
  [16] PENG Jun-Mei(彭俊梅), LI Wan(李婉), SHEN Kun(申坤), et al. Chem. J. Chinese Universities(高等学校化学学报), 2013,34(7):1646-1652
17. [17]
  [17] ZHANG Fu-Xing(张复兴), WANG Jian-Qiu(王剑秋), KUANG Dai-Zhi(邝代治), et al. Chinese J. Org. Chem.(有机化学), 2003,23(4):368-371
1. [1]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
2. [2]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
3. [3]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
4. [4]
  Zhiwen HUANG , Qi LIU , Jianping LANG . W/Cu/S cluster-based supramolecular macrocycles and their third-order nonlinear optical responses. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 79-87. doi: 10.11862/CJIC.20240184
5. [5]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
6. [6]
  Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
7. [7]
  Jiaming Xu , Yu Xiang , Weisheng Lin , Zhiwei Miao . Research Progress in the Synthesis of Cyclic Organic Compounds Using Bimetallic Relay Catalytic Strategies. University Chemistry, 2024, 39(3): 239-257. doi: 10.3866/PKU.DXHX202309093
8. [8]
  Qiuyu Ming , Huijun Jiang , Zhihao Zhang . A Sightseeing Tour of Folic Acid Processing Plant. University Chemistry, 2024, 39(9): 11-15. doi: 10.12461/PKU.DXHX202404092
9. [9]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
10. [10]
  Hong RAO , Yang HU , Yicong MA , Chunxin LÜ , Wei ZHONG , Lihua DU . Synthesis and in vitro anticancer activity of phenanthroline-functionalized nitrogen heterocyclic carbene homo- and heterobimetallic silver/gold complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2429-2437. doi: 10.11862/CJIC.20240275
11. [11]
  Yao HUANG , Yingshu WU , Zhichun BAO , Yue HUANG , Shangfeng TANG , Ruixue LIU , Yancheng LIU , Hong LIANG . Copper complexes of anthrahydrazone bearing pyridyl side chain: Synthesis, crystal structure, anticancer activity, and DNA binding. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 213-224. doi: 10.11862/CJIC.20240359
12. [12]
  Ping Song , Nan Zhang , Jie Wang , Rui Yan , Zhiqiang Wang , Yingxue Jin . Experimental Teaching Design on Synthesis and Antitumor Activity Study of Cu-Pyropheophorbide-a Methyl Ester. University Chemistry, 2024, 39(6): 278-286. doi: 10.3866/PKU.DXHX202310087
13. [13]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
14. [14]
  Maitri Bhattacharjee , Rekha Boruah Smriti , R. N. Dutta Purkayastha , Waldemar Maniukiewicz , Shubhamoy Chowdhury , Debasish Maiti , Tamanna Akhtar . Synthesis, structural characterization, bio-activity, and density functional theory calculation on Cu(Ⅱ) complexes with hydrazone-based Schiff base ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1409-1422. doi: 10.11862/CJIC.20240007
15. [15]
  Xiaofeng Xia , Jielian Zhu . Innovative Comprehensive Experimental Design: Synthesis of 6-Fluoro-N-benzoyl Tetrahydroquinoline. University Chemistry, 2024, 39(10): 344-352. doi: 10.12461/PKU.DXHX202405063
16. [16]
  Ling Liu , Haibin Wang , Genrong Qiang . Curriculum Ideological and Political Design for the Comprehensive Preparation Experiment of Ethyl Benzoate Synthesized from Benzyl Alcohol. University Chemistry, 2024, 39(2): 94-98. doi: 10.3866/PKU.DXHX202304080
17. [17]
  Tingting Yu , Si Chen , Lianglong Sun , Tongtong Shi , Kai Sun , Xin Wang . Comprehensive Experimental Design for the Photochemical Synthesis, Analysis, and Characterization of Difluoropyrroles. University Chemistry, 2024, 39(11): 196-203. doi: 10.3866/PKU.DXHX202401022
18. [18]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
19. [19]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
20. [20]
  Chen LU , Qinlong HONG , Haixia ZHANG , Jian ZHANG . Syntheses, structures, and properties of copper-iodine cluster-based boron imidazolate framework materials. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 149-154. doi: 10.11862/CJIC.20240407

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(399)
HTML views(30)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142