Citation: LIU Jing-Liang, ZONG En-Min, CHEN Huan, XU Zhao-Yi. Adsorption of Fluoride Ion by Zirconia Functionalized Activated Carbon Fiber[J]. Chinese Journal of Inorganic Chemistry, ;2015, (6): 1105-1111. doi: 10.11862/CJIC.2015.152 shu

Adsorption of Fluoride Ion by Zirconia Functionalized Activated Carbon Fiber

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1 School of Environmental Science, Nanjing XiaoZhuang University, Nanjing 211171, China;
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2 School of Life Science, Taizhou University, Taizhou, Zhejiang, 317000, China;
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3 School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing 210094, China;
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4 State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Nanjing 210046, China

Corresponding author: LIU Jing-Liang,
Received Date: 19 January 2015
Available Online: 3 April 2015
Fund Project: 国家自然科学基金(No.31471699,21407074,51208257) (No.31471699,21407074,51208257)江苏省生态学“十二五”省重点建设学科项目和南京晓庄学院项目(No.2012NJX103)资助。 (No.2012NJX103)

Zirconia functionalized activated carbon fiber (ACF-Zr) adsorbent was successfully prepared using the post-grafting method and its adsorptions for fluoride ion (F^-) uptake were investigated in details. Characterized results demonstrated that zirconia was highly dispersed on the surface of active carbon fiber. Adsorption experiment indicated ACF-Zr has high removal efficiency of F^-, because of ion exchange andelectrostatic interaction. The adsorption isotherm could be well described by the Langmuir adsorption model and adsorption kinetics on ACF-Zr followed by pseudo-second-order kinetics. The adsorption capacity decreased with the increase of solution pHvalue. Nearly no influence was observed by solution coexisting ions Cl^-, NO₃^- and SO₄^2-.
- active carbon fiber;F^-;adsorption;zirconia
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