Citation: YANG Li, WANG Hua, LI Kong-Zhai, WEI Yong-Gang, ZHU Xing. Microwave-Assisted Synthesis of Ru(Ⅱ) Complex and Self-Assembled Multilayer Film Formed by Alternating Layers of the Ru Complex[J]. Chinese Journal of Inorganic Chemistry, ;2015, (6): 1131-1138. doi: 10.11862/CJIC.2015.151 shu

Microwave-Assisted Synthesis of Ru(Ⅱ) Complex and Self-Assembled Multilayer Film Formed by Alternating Layers of the Ru Complex

YANG Li ^1,2 ,
WANG Hua ^1,2 ,
LI Kong-Zhai ^1,2 ,
WEI Yong-Gang ^1,2 ,
ZHU Xing ^1,2

1.
1 Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China;
2.
2 State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming University of Science and Technology, Kunming 650093, China

Received Date: 12 December 2014
Available Online: 7 February 2015
Fund Project: 国家自然科学基金(No.51174105) (No.51174105)国家自然基金面上项目(No.51374004)资助。 (No.51374004)

Asymmetrical ruthenium complex bearing phosphonic acid was prepared under the microwave irradiation and fully characterized by ¹H NMR, ESI-MS and thermo gravimetric(TG) analysis. For the Ru complex, the phosphonic groups were selectively attached to the ITO through covalent interaction, resulting in the hydrophilic surface due to the appearance of the exposed other phosphonic-acid groups on the top. The Layer by layer(LBL) growth of molecular units was used to fabricate redox-active films of Ru complex, which was followed by the formation of Zr⁴⁺-phosphonate layer. The buildup of the films was followed by monitoring cyclic voltammetry(CV) and ultraviolet-visible absorption spectrometry(UV-Vis) measurements. The results showed the electrode modified by multilayered film displayed reversible redox processes, and the Ru(Ⅱ/Ⅲ) oxidative peak was observed at +0.53 V. The plots of surface coverage versus number of layers show a linear relationship, which means a uniform layer structure is formed during the LBL process. UV-Vis spectra shows the prepared Ru film have strong absorptions between 300 nm and 600 nm. These findings show the Ru complex has good photoelectric properties.
- ruthenium complex;self-assembled;microwave-assisted;photoelectric character
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